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J Mater Sci Technol  1999, Vol. 15 Issue (06): 551-554    DOI:
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Valence Distribution in ATxV6-xO11 Compounds
Hongchao LIU, Changlin KUO
Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
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Abstract  The distribution of trivalent and tetravalent cations in several ATxV6-xO11 compounds was quantitatively studied by the bond valence method. In SrV6O11, the M(3) sites were mainly occupied by trivalent cations; while M(1) and M(2) sites were shared by trivalent and tetravalent cations, the relative content of tetravalent at M(1) sites was higher than at M(2) sites. During substitution process, the trivalent cations preferred to occupy M(3) sites, tetravalent ones preferred to occupy M(2) sites. The occupancy of trivalent and tetravalent cations at M sites would change with the substitution.
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Received:  05 October 1998     
Corresponding Authors:  Changlin KUO     E-mail:

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Hongchao LIU, Changlin KUO. Valence Distribution in ATxV6-xO11 Compounds. J Mater Sci Technol, 1999, 15(06): 551-554.

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