J Mater Sci Technol ›› 2012, Vol. 28 ›› Issue (3): 280-284.

• Regular Papers • Previous Articles     Next Articles

Microstructures and Dielectric Properties of Ba1-xSrxTiO3 Ceramics Doped with B2O3-Li2O Glasses for LTCC Technology Applications

Xiujian Chou1), Zhenyu Zhao1), Miaoxuan Du1), Jun Liu1), Jiwei Zhai2)   

  1. 1) Key Laboratory of Instrumentation Science & Dynamic Measurement, Ministry of Education, National Key Laboratory of Science and Technology on Electronic Test and Measurement (North University of China), Taiyuan 030051, China
    2) Functional Materials Research Laboratory, Tongji University, Shanghai 200092, China
  • Received:2010-12-27 Revised:2011-04-18 Online:2012-03-31 Published:2012-03-31
  • Contact: Xiu-Jian CHOU
  • Supported by:

    Functional Materials Research Laboratory, Tongji University, China. This work was funded as part of the Ministry of Sciences and Technology of China through 973-project under Grant No.2009CB623302, the National Natural Science Foundation of China under Grant No. 51175483 and Program for the Outstanding Innovative Teams of High Learning Institutions of Shanxi.

Abstract: Ba1-xSrxTiO3 ceramics, doped with B2O3-Li2O glasses have been fabricated via a traditional ceramic process at a low sintering temperature of 900 °C using liquid-phase sintering aids. The microstructures and dielectric properties of B2O3-Li2O glasses doped Ba1-xSrxTiO3 ceramics have been investigated systematically. The temperature dependence dielectric constant and loss reveals that B2O3-Li2O glasses doped Ba1-xSrxTiO3 ceramics have diffusion phase transformation characteristics. For 5 wt% B2O3-Li2O glasses doped Ba0:55Sr0:45TiO3 composites, the tunability is 15.4% under a dcpplied electric field of 30 kV/cm at 10 kHz; the dielectric loss can be controlled about 0.0025; and the Q value is 286. These composite ceramics sintered at low temperature with suitable dielectric constant, low dielectric loss, relatively high tunability and high Q value are promising candidates for multilayer low-temperature co-fired ceramics (LTCC) and potential microwave tunable devices applications.

Key words: Sintering, Ferroelectricity, Dielectric properties, Microstructure