Effect of Compression on the Crystallization Behavior and Corrosion Resistance of Al86Ni9La5 Amorphous Alloy

Abstract

Abstract:

The effect of compression on the crystallization behavior and corrosion resistance of Al₈₆Ni₉La₅ amorphous ribbons was investigated by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM) and electrochemistry test. The XRD and TEM results reveal that the compressed Al86Ni9La5 ribbons spun with the circumferential speed (R) of 29.3 m/s are in fully amorphous state; however, the compressed ribbons spun with R=14.7 m/s have crystalline phases embedded in the amorphous matrix. The SEM images indicate that after compression, the toughness of the ribbons increases. Electrochemical results show that the compression decreases the stability of the passive film of the Al₈₆Ni₉La₅ amorphous ribbons, because of the compression-introduced free volume, shear bands and crystalline phases; meanwhile, with R=14.7 m/s, the compression-induced crystalline phases in the Al₈₆Ni₉La₅ ribbons increase the corrosion potential.

Key words: Compression, Crystallization, Corrosion resistance, Quenched-in nuclei

Yan Liu, Weimin Wang, Hongdi Zhang, Haijian Ma, Bang An. Effect of Compression on the Crystallization Behavior and Corrosion Resistance of Al₈₆Ni₉La₅ Amorphous Alloy[J]. J. Mater. Sci. Technol., 2012, 28(12): 1102-1108.

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Effect of Compression on the Crystallization Behavior and Corrosion Resistance of Al₈₆Ni₉La₅ Amorphous Alloy

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