Effects of Pulsed Magnetic Field on Microsegregation of Solute Elements in a Ni-Based Single Crystal Superalloy

doi:10.1016/j.jmst.2015.12.021

Abstract

Abstract:

The effects of a pulsed magnetic field (PMF) on the microsegregation of solute elements during directional solidification of a Ni-based single crystal superalloy were experimentally investigated, and the results show that the PMF significantly affects the microsegregation of Al, Ti, Co, Mo and W elements in the alloy. However, the distribution behavior differs for both positive and negative segregation elements. With the PMF, the microsegregation of negative segregation elements, Co and W, was restrained effectively, while that of positive segregation elements, Al, Ti and Mo, was aggravated. A segregation model was established to reveal the distribution mechanism of the elements with PMF. It is considered that, under the action of PMF, the jumping of solute atoms from the liquid phase to solid phase is hindered, but the jumping of solute atoms from the solid phase into liquid phase is promoted during solidification. As a result, the effective distribution coefficient of the solute atoms is reduced, which leads to the reduction of microsegregation of negative segregation elements and aggravation of microsegregation of positive segregation elements.

Key words: Pulsed magnetic field, Segregation, Superalloy, Distribution coefficient

Li Yingju,Teng Yuefei,Feng Xiaohui,Yang Yuansheng. Effects of Pulsed Magnetic Field on Microsegregation of Solute Elements in a Ni-Based Single Crystal Superalloy[J]. J. Mater. Sci. Technol., 2017, 33(1): 105-110.

Figures/Tables 9

Fig.1 Schematic illustration of the directional solidification apparatus with a PMF

Fig.2 Distributions of element Co in the alloy with different PMF: (a) 0V, (b) 50V, (c) 100V, and (d) 200V

Fig.3 Distributions of element Ti in the alloy with different PMF: (a) 0V, (b) 50V, (c) 100V, and (d) 200V

Fig.4 Effect of PMF on the microsegregation of negative segregation elements Co and W

Fig.5 Effect of PMF on the microsegregation of positive segregation elements Al, Ti and Mo

Fig.6 Effect of PMF on the distribution of γ/γ′ eutectics in the alloys: (a) 0V, (b) 50V, (c) 100V, and (d) 200V

Fig.7 Effect of PMF on the distribution of γ/γ′ eutectics

Fig.8 Schematic illustration of the solute atoms migration at the solid-liquid interface of dendritic crystal with PMF

Fig.9 Chemical potentials of the atoms at the liquid-solid interface

References

[1]	P. Caron, T. Khan, Aerosp. Sci. Technol. 3(1999) 513-523.
[2]	G.J.S.Higginbotham, Mater. Sci. Technol. 2(1986) 442-460.
[3]	G.E. Fuchs, B.A. Boutwell,Mater. Sci. Eng. A 333 (2002) 72-79.
[4]	R.M. Kearsey, J.C. Beddoesa, P. Jonesb, P. Auc,Intermetallics 12 (2004) 903-910.
[5]	A. Heckl, R. Rettig, R.F. Singer,Metall. Mater. Trans. A 41 (2010) 202-211.
[6]	A.F. Giamei, J.G. Tschinkel,Metall. Mater. Trans. A 7 (1976) 1427-1434.
[7]	C.B. Liu, J. Shen, J. Zhang, L.H. Lou, J. Mater. Sci.Technol. 26(2010) 306-310.
[8]	C.L. Brundidge, J.D. Miller, T.M. Pollock,Metall. Mater. Trans. A 43 (2012) 965-976.
[9]	H.P. Utech, M.C. Flemings, J. Appl. Phys. 37(1966) 2021-2024.
[10]	T. Zhang,W.L. Ren, J.W. Dong, X. Li, Z.M. Ren, G.H. Cao, Y.B. Zhong, K. Deng, Z.S. Lei, J.T. Guo, J. Alloy. Compd. 487(2009) 612-617.
[11]	W.L. Ren, L. Lu, G.Z. Yuan, W.D. Xuan, Y.B. Zhong, J.B. Yu, Z.M. Ren, Mater. Lett. 100(2013) 223-226.
[12]	X.P. Ma, Y.J. Li, Y.S. Yang, J. Mater. Res. 24(2009) 2670-2676.
[13]	Y.J. Li, X.P. Ma, Y.S. Yang,Trans. Nonferrous Met. Soc. China 21 (2011) 1277-1282.
[14]	B.T. Zi, Q.X. Ba, J.Z. Cui, G.M. Xu, Scr. Mater. 43(2000) 377-380.
[15]	Y.J. Li,W.Z. Tao, Y.S. Yang, J. Mater. Process.Technol. 212(2012) 903-909.
[16]	Y.L. Gao, Q.S. Li, Y.Y. Gong, Q.J. Zhai, Mater. Lett. 61(2007) 4011-4014.
[17]	Y.J. Li, Y.F. Teng, Y.S. Yang, Met. Mater. Int. 20(2014) 527-530.
[18]	M. Tani, K. Tanaka, S. Fukunaga, T. Toh, K. Tsunenari, K. Umetsu, K. Hayashi, M. Zeze, K. Isogami, Sendai, 2006, pp. 63-67.
[19]	A. Kolesnichenko, V. Buryak, Sendai, 2006, pp. 57-62.
[20]	Z.L. Zhao, R. Zhang, L. Liu, A.P. Zeng, Chin. J. Mater. Res. 19(2005) 207-212 (in Chinese).
[21]	C.J. Song, Q.S. Li, H.B. Li, Q.J. Zhai,Mater. Sci. Eng. A 485 (2008) 403-408.
[22]	Y.L. Zhang, J.G. Li, Mater. Trans. 53(2012) 1910-1914.
[23]	Z. Qgumi, Electrochemistry, Science Press, Beijing, 2002.
[24]	X.Q. Cha, Electrode Kinetics, Beijing Science and Technology Press, Beijing, 2002.
[25]	M.J. Aziz, J. Appl. Phys. 53(1982) 1158-1168.