J. Mater. Sci. Technol. ›› 2013, Vol. 29 ›› Issue (1): 39-43.DOI: 10.1016/j.jmst.2012.11.005

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Characterization of Ga-doped ZnO Nanorods Synthesized via Microemulsion Method

Sang Kyoo Lim1), Seong Hui Hong1), Sung-Ho Hwang1), Soonhyun Kim1), Hyunwoong Park2)   

  1. 1) Division of Nano & Bio Technology, Daegu Gyeongbuk Institute of Science and Technology (DGIST), Daegu 711-873, Republic of Korea
    2) School of Energy Engineering, Kyungpook National University, Daegu 702-701, Republic of Korea
  • Received:2012-03-06 Revised:2012-05-12 Online:2013-01-30 Published:2013-02-04
  • Contact: Sang Kyoo Lim
  • Supported by:

    Fundamental R&D Program for Core Technology of Materials funded by the Ministry of Knowledge Economy, also supported by the DGIST R&D Program of the Ministry of Education, Science and Technology of Korea (11-NB-03).

Abstract:

Gallium-doped ZnO (GZO) nanorods were synthesized by microemulsion method with different types of surfactants. The phase and morphology of the above nanorods were investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD), high resolution transmission electron microscopy (HR-TEM) and X-ray photoelectron spectroscopy (XPS). SEM observations show that the ZnO nanorods have diameters around 70–200 nm and lengths up to several micrometers. The room temperature photoluminescence (PL) spectrum of GZO nanorods exhibited a sharp and strong ultraviolet bandgap at 383 nm and a relatively weaker emission associated with the defect level. Resistivity of GZO nanorods synthesized with sodium lauryl sulfate (SLS) and sodium benzene sulfonate (SBS) surfactants showed 2.84 Ω m and 14.2 Ω m, respectively.

 

Key words: Zinc oxide, Nanorod, Microemulsion, Gallium, Surfactants