Carbon nanofilm stabilized twisty V2O3 nanorods with enhanced multiple polarization behavior for electromagnetic wave absorption application

doi:10.1016/j.jmst.2021.12.034

Abstract

Abstract:

Vanadium (V) oxides exhibit low electrical conductivity and poor polarization properties, especially in that V₂O₃ has low stability and is easily oxidized to higher valence V oxides. To solve this problem, we herein provide a two-step strategy for the synthesis of carbon nanofilm stabilized twisty V₂O₃ nanorods (V₂O₃@C), including a hydrothermal reaction and a controlled pyrolysis process. Conductivity tests and electron-spin resonance (ESR) spectra indicate that the coating of carbon nanofilm not only enhances the electrical conductivity but also generates abundant defects. The electromagnetic waves absorption (EMA) results suggest that V₂O₃@C exhibits excellent EMA performance at ultra-low thickness, where the effective absorption bandwidth gets to 7.21 GHz at 1.7 mm and the maximal absorption reaches -56 dB. Enhanced conductivity loss and improved multiple polarization relaxation were used to illustrate the absorbing mechanism of V₂O₃@C. This work provides new insights into the design of advanced nanocomposites for EMA applications.

Key words: Vanadium oxides, V₂O₃@C nanorod, Core-shell nanostructure, Electromagnetic wave absorption, Interfacial polarization

Siyao Cheng, Cheng Zhang, Hao Wang, Jinrui Ye, Yan Li, Qiu Zhuang, Wei Dong, Aming Xie. Carbon nanofilm stabilized twisty V₂O₃ nanorods with enhanced multiple polarization behavior for electromagnetic wave absorption application[J]. J. Mater. Sci. Technol., 2022, 119: 37-44.

Figures/Tables 7

Fig. 1. Schematic illustration of the synthesis process of V2O3@C.

Fig. 2. SEM images of V2O5 (a), VO2@PPy (c) and V2O3@C (e); TEM images of V2O5 (b), VO2@PPy (d) and V2O3@C (f-j), elemental mapping of C, N, O, V (k) and overlay for V2O3@C composites (l).

Fig. 3. XRD pattern (a); FI-IR spectroscopy of V2O5, VO2@PPy, and V2O3@C (b); TG curve of VO2@Ppy (c); Raman spectroscopy of VO2@PPy, V2O3@C, and C (d); XRS spectra for V 2p (e), C 1 s (f), and N 1 s (g); EPR spectra of VO2@PPy and V2O3@C (h).

Fig. 4. The 3D-RL plots of VO2@PPy (a), V2O3@C (b), V2O3 (c) and C (d); RL curves of V2O3@C (e) and V2O3 (f); efficient bandwidth comparison (g) of V2O3@C and V2O3; comparison of the EMA performance between our work and the relevant absorbers (h).

Fig. 5. The relative complex permittivity ε′ (a) and ε″ (b), impedance matching |Z| (c) and attenuation constant α (d), the relative complex permeability μ′ and μ″ of V2O3@C (e) and dielectric loss tan δε (f).

Fig. 6. The electrical conductivity (a); zeta potential (b); Cole-Cole curves (c) of VO2@PPy, V2O3@C, V2O3, and C.

Fig. 7. Schematic diagram of the EMA mechanism for V2O3@C.

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Carbon nanofilm stabilized twisty V₂O₃ nanorods with enhanced multiple polarization behavior for electromagnetic wave absorption application

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