J. Mater. Sci. Technol. ›› 2021, Vol. 60: 35-43.DOI: 10.1016/j.jmst.2020.03.078
• Research Article • Previous Articles Next Articles
Zijuan Xua, Zhongtao Lia, Yang Tongc, Weidong Zhanga,*(), Zhenggang Wua,b,*()
Received:
2020-02-08
Revised:
2020-03-07
Accepted:
2020-03-26
Published:
2021-01-10
Online:
2021-01-22
Contact:
Weidong Zhang,Zhenggang Wu
Zijuan Xu, Zhongtao Li, Yang Tong, Weidong Zhang, Zhenggang Wu. Microstructural and mechanical behavior of a CoCrFeNiCu4 non-equiatomic high entropy alloy[J]. J. Mater. Sci. Technol., 2021, 60: 35-43.
Fig. 3. In-situ XRD patterns of the CoCrFeNiCu4 high entropy alloy recorded at 25 °C and those at 300, 500, 700, 900, and 1000 °C during heating (a) and cooling (b) with a heating/cooling rate of 10 °C/min.
Fig. 4. The lattice constant difference, which was qualitatively determined solely from the first FCC peaks, between the Cu-rich phase and CoCrFeNi-rich phase as a function of temperature during heating and cooling.
Fig. 5. (a) DSC curves of the CoCrFeNiCu4 high entropy alloy during heating to melting and subsequent cooling with a heating/cooling rate of 10 °C/min; (b, c) enlarged views of the regions indicated by the arrows.
Fig. 8. BSE images of the as-rolled CoCrFeNiCu4 high entropy alloy annealed at 300 °C (a) and 700 °C (b) for 1 hour, showing the preference of Cu-rich particles precipitation inside the CoCrFeNi-rich phase.
Fig. 9. Inverse pole figure maps projected on rolling direction (horizontal) and the kernel average misorientation maps showing the degree of orientation gradients between the current pixel orientation and its six first-nearest neighbors of the CoCrFeNiCu4 high entropy alloy annealed at 500 °C (a, e), 700 °C (b, f), 900 °C (c, g), and 1000 °C (d, h) following rolling.
Fig. 10. (a) Representative engineering stress-strain curves of the CoCrFeNiCu4 high entropy alloy after cold-rolling and subsequent 1 hour annealing at 300, 500, 700, 900, and 1000 °C; (b) strain hardening rate vs. true strain curves of the 700 °C-, 900 °C-, and 1000 °C-annealed specimens.
Fig. 11. Engineering stress-strain curves of the CoCrFeNiCu4 high entropy alloy obtained through the interrupted tensile tests showing the existence of the yield-drop of the 1000 °C-annealed specimen and the disappearance of it after re-loading following interruption at 4% engineering strain.
[1] |
J.W. Yeh, S.K. Chen, S.J. Lin, J.Y. Gan, T.S. Chin, T.T. Shun, C.T. Tsau, S.Y. Chang, Adv. Eng. Mater. 6(2004) 299-303.
DOI URL |
[2] | B. Cantor, I.T.H. Chang, P. Knight, A.J.B. Vincent, Mater. Sci. Eng. A 375 (2014) 213-218. |
[3] |
F. Alijani, M. Reihanian, K. Gheisari, J. Alloys Compd. 773(2019) 623-630.
DOI URL |
[4] | Y.F. Ye, Q. Wang, J. Lu, C.T. Liu, Y. Yang, Mater. Today 19 (2016) 349-362. |
[5] | X. Yang, Y. Zhang, Mater. Chem. Phys. 132(2012) 233-238. |
[6] | Z. Wu, H. Bei, F. Otto, G.M. Pharr, E.P. George, Intermetallics 46 (2014) 131-140. |
[7] | J.W. Yeh, Ann. Chim. Sci. Mat. 31(2016) 633-648. |
[8] | S. Guo, C. Ng, J. Lu, C.T. Liu, J. Appl. Phys. 109(2011) 1-5. |
[9] |
Z.J. Wang, Y.H. Huang, Y. Yang, J.C. Wang, C.T. Liu, Scr. Mater. 94(2015) 28-31.
DOI URL |
[10] |
F. Otto, A. Dlouhy, Ch. Somsen, H. Bei, G. Eggeler, E.P. George, Acta Mater. 61(2013) 5743-5755.
DOI URL |
[11] |
Z. Wu, H. Bei, G.M. Pharr, E.P. George, Acta Mater. 81(2014) 428-441.
DOI URL |
[12] | C.W. Tsai, C. Lee, P.T. Lin, X. Xie, S.Y. Chen, R. Carroll, M. LeBlanc, B.A.W. Brinkman, P.K. Liaw, K.A. Dahmen, J.W. Yeh, Int. J. Plast. 122(2019) 212-224. |
[13] | Z. Wu, Y.F. Gao, H. Bei, Acta Mater. 120(2016) 108-119. |
[14] | Y. Zhang, T.T. Zuo, Z. Tang, M.C. Gao, K.A. Dahmen, P.K. Liaw, Z.P. Lu, Prog. Mater. Sci. 61(2014) 1-93. |
[15] | Z. Wu, Y.F. Gao, H. Bei, Scr. Mater. 109(2015) 108-112. |
[16] | N. Jia, Y. Li, X. Liu, Y. Zheng, B.P. Wang, J.S. Wang, Y.F. Xue, K. Jin, JOM 71 (2019) 3490-3498. |
[17] | Y.Q. Wang, B. Liu, K. Yan, Acta Mater. 154(2018) 79-89. |
[18] | Q.Q. Ding, X.Q. Fu, D.K. Chen, Mater. Today 25 (2019) 21-27. |
[19] | J.P. Couzinie, L. Lilensten, Y. Champion, G. Dirras, L. Perriere, I. Guillot, Mater. Sci. Eng. A 645 (2015) 255-265. |
[20] | S. Wang, J. Xu, J. Mater. Sci. Technol. 35(2019) 812-816. |
[21] | Z. Wu, M.C. Troparevsky, Y.F. Gao, J.R. Morris, G.M. Stocks, H. Bei, Curr. Opin. Solid State Mater.Sci. 21(2017) 267-284. |
[22] | Z.Q. Xu, Z.L. Ma, M. Wang, Y.W. Chen, Y.D. Chen, X.W. Cheng, Mater. Sci. Eng. A 755 (2019) 318-322. |
[23] | Y.K. Lv, R.Y. Hu, Z.H. Yao, J. Chen, D.P. Xu, Y. Liu, X.H. Fan, Mater. Des. 132(2017) 392-399. |
[24] | A. Verma, P. Tarate, A.C. Abhyankar, Scr. Mater. 161(2019) 28-31. |
[25] |
W.H. Liu, Z.P. Lu, J.Y. He, Z.J. Wang, B. Liu, Yong Liu, M.W. Chen, C.T. Liu, Acta Mater. 116(2016) 332-342.
DOI URL |
[26] |
Y. Tong, D. Chen, B. Han, J. Wang, R. Feng, T. Yang, C. Zhao, W. Guo, Y. Shimizu, C. T. Liu, P.K. Liaw, K. Inoue, Y. Nagai, A. Hu, J.J. Kai, Acta Mater. 165(2019) 228-240.
DOI URL |
[27] |
G.A. Salishchev, M.A. Tikhonovsky, D.G. Shaysultanov, A.V. Kuznetsov, I.V. Kolodiy, A.S. Tortika, O.N. Senkov, J. Alloys Compd. 591(2014) 11-21.
DOI URL |
[28] | H. Jiang, K.M. Han, D.X. Qiao, Y.P. Liu, Z.Q. Cao, T.J. Li, Mater. Chem. Phys. 210(2018) 43-48. |
[29] | L.J. Zhang, M.D. Zhang, Z. Zhou, J.F. Fan, P. Cui, P.F. Yu, Q. Jing, M.Z. Ma, P.K. Liaw, G. Li, R.P. Liu, Mater. Sci. Eng. A 725 (2018) 437-446. |
[30] |
Z.M. Li, K.G. Pradeep, Y. Deng, D. Raabe, C.C. Tasan, Nature 534 (2016) 227-230.
DOI URL PMID |
[31] | W.J. Lu, C.H. Liebscher, D. Gerhard, D. Raabe, Z.M. Li, Adv. Mater. 30(2018), 1804727. |
[32] | X.Z. Gao, Y.P. Lu, B. Zhang, N.N. Liang, G.Z. Wu, G. Sha, J.Z. Liu, Y.H. Zhao, Acta Mater. 141(2017) 59-66. |
[33] | Y.L. Zhao, J.G. Li, X.G. Wang, Y.P. Lu, Y.Z. Zhou, X.F. Sun, J. Mater, Sci. Technol. 35(2019) 902-906. |
[34] |
Y.P. Lu, Y. Dong, S. Guo, L. Jiang, H.J. Kang, T.M. Wang, B. Wen, Z.J. Wang, J.C. Jie, Z.Q. Cao, H.H. Ruan, T.J. Li, Sci. Rep. 4(2015) 6200.
DOI URL PMID |
[35] |
Y.P. Lu, X.Z. Gao, L. Jiang, Z.N. Chen, T.M. Wang, J.C. Jie, H.J. Kang, Y.B. Zhang, S. Guo, H.H. Ruan, Acta Mater. 124(2017) 143-150.
DOI URL |
[36] | Y. Tong, Y.L. Zhao, J.H. Luan, J. Wei, J.J. Kai, C.T. Liu, Scr. Mater. 164(2019) 30-35. |
[37] | X. Yan, Y. Zhang, Scr. Mater. 178(2020) 329-333. |
[38] | Z.Y. Huang, Y.Q. Dai, Z. Li, J.Q. Zhang, C.T. Zhang, J. Ma, Mater. Des. 186(2020), 108367. |
[39] | T. Nagase, A. Shibata, M. Matsumuro, M. Takemuraet, S. Semboshi, Mater. Des. 181(2019), 107900. |
[40] |
M. Dias, F. Antao, N. Catarino, A. Galatanub, M. Galatanub, P. Ferreirac, J.B. Correiad, R.C. da Silvaa, A.P. Gonç alvese, E. Alves, Fusion Eng. Des. 146(2019) 1824-1828.
DOI URL |
[41] | B. Wu, Z.Y. Xie, J.C. Huang, J.W. Lin, Y.X. Yang, L.Q. Jiang, J.L. Huang, G.X. Ye, C. F. Zhao, S.J. Yang, B.S. Sa, Intermetallics 93 (2018) 40-46. |
[42] | G. Qing, R.R. Chen, P.K. Liaw, Y.F. Gao, X.Q. Li, H.T. Zheng, L. Wang, Y.Q. Su, J.J. Guo, H.Z. Fu, Scr. Mater. 172(2019) 51-55. |
[43] | Y.J. Hsu, W.C. Chiang, J.K. Wu, Mater. Chem. Phys. 92(2005) 112-117. |
[44] | K.Y. Tsai, M.H. Tsai, J.W. Yew, Acta Mater. 61(2013) 4887-4897. |
[45] | J. Dabrowa, M. Zajusz, W. Kucza, G. Cieslak, K. Berent, T. Czeppe, T. Kulik, M. Danielewski, J. Alloys. Compd. 783(2019) 193-207. |
[46] | J. Kottke, M. Laurent-Brocq, A. Fareed, D. Gaertner, L. Perrière, Ł. Rogal, S.V. Divinski, G. Wilde, Scr. Mater. 159(2019) 94-98. |
[47] | X. Xian, L.J. Lin, Z.H. Zhong, C. Zhang, C. Chen, K.J. Song, J.G. Cheng, Y.C. Wu, Mater. Sci. Eng. A 713 (2018) 134-140. |
[48] | K.Y. Tsai, M.H. Tsai, J.W. Yeh, Acta Mater. 61(2013) 4887-4897. |
[49] | M. Vaidya, K.G. Pradeep, B.S. Murty, G. Wilde, S.V. Divinski, Acta Mater. 46(2018) 211-224. |
[50] | K. Jin, C. Zhang, F. Zhang, H.B. Bei, Mater. Res. Lett. 6(2018) 293-299. |
[51] | F.J. Humphreys, M. Hatherly, Recrystallization and Related Phenomena. Pergamon Press, Oxford, 2004. |
[52] | P.S. Kotval, O.H. Nostor, TMSAIME 245 (1969) 1275-1278. |
[53] | G.P.C. Jallagher, Metall. Trans. 1(1970) 2429-2461. |
[54] | H. Zheng, R. Chen, G. Qin, X.Z. Li, Y.Q. Su, H.S. Ding, J.J. Guo, H.Z. Fu, J. Mater. Sci. Technol. 38(2020) 19-27. |
[55] |
Z. Wu, C.M. Parish, H. Bei, J. Alloys Compd. 647(2015) 815-822.
DOI URL |
[56] | Y.Z. Tian, S. Gao, L.J. Zhao, R. Pippan, Z.F. Zhang, N. Tsuji, Scr. Mater. 142(2018) 88-91. |
[57] |
X. Huang, N. Hansen, N. Tsuji, Science 312 (2016) 249-251.
DOI URL PMID |
[58] |
J. Gu, M. Song, Scr. Mater. 162(2019) 345-349.
DOI URL |
[59] | S.H. Avner, Introduction to Physical Metallurgy, McGraw Hill Publishing, New York, 1964. |
[60] | Q.M. Luan, H. Xing, J. Zhang, J. Jiang, Acta Mater. 183(2020) 78-92. |
[61] | Z.J. Zhang, Q.Q. Duan, X.H. An, S.D. Wu, G. Yang, Z.F. Zhang, Mater. Sci. Eng. A 528 (2011) 4259-4267. |
[62] |
D. Maisonnette, M. Suery, D. Nelias, P. Chaudet, T. Epicier, Mater. Sci. Eng. A 528 (2011) 2718-2724.
DOI URL |
[63] | R.M. Brick, J.R. Low Jr, C.H. Lorig, Behavior of Metals at Low Temperatures, ASM, Philadelphia, 1953. |
[64] |
A.S. Tetelman, A.J. McEvily, Fracture of Structural Materials, Wiley, New York, 1966.
DOI URL PMID |
[65] | A. Liu, Mechanics and Mechanisms of Fracture, ASM International, Materials Park, OH, 2005. |
[66] | J. Garstone, R.W.K Honeycombe, Dislocations and Mechanical Properties of Crystals, Wiley, New York, 1957. |
[67] | J.Y. He, H. Wang, H.L. Huang, M.W. Chen, Y. Wu, X.J. Liu, T.G. Nieh, K. An, Z.P. Lu, Acta Mater. 102(2016) 187-196. |
[68] | F. He, D. Chen, B. Han, Q.F. Wu, Z.J. Wang, S.L. Wei, D.X. Wei, J.C. Wang, C.T. Liu, J.J. Kai, Acta Mater. 167(2019) 275-286. |
[69] | G. Qin, R. Chen, P.K. Liaw, Y.F. Ga, X.Q. Li, H.T. Zheng, L. Wang, Y.Q. Su, J.J. Guo, H.Z. Fu, Scr. Mater. 172(2019) 51-55. |
[70] | G.E. Dieter, Mechanical Metallurgy, McGraw-Hill Higher Education, Berlin, 1986. |
[71] | E.O. Hall, Yield Point Phenomena in Metals and Alloys, Plenum Press, New York, 1970. |
[72] | A.H. Cottrell, M.A. Jaswon, J. Math. Phys. 199(1949) 104-114. |
[73] |
A.W. Sleeswyk, Acta Mater. 6(1958) 598-603.
DOI URL |
[74] |
R.A. Mulford, U.F. Kocks, Acta Mater. 27(1979) 1125-1134.
DOI URL |
[75] |
S.G. Hong, S. Lee, J. Nucl. Mater. 340(2005) 307-314.
DOI URL |
[76] | A.H. Cottrell, Philos. Mag. Lett. 44(1953) 829-832. |
[1] | Xiong-jie Gu, Wei-li Cheng, Shi-ming Cheng, Yan-hui Liu, Zhi-feng Wang, Hui Yu, Ze-qin Cui, Li-fei Wang, Hong-xia Wang. Tailoring the microstructure and improving the discharge properties of dilute Mg-Sn-Mn-Ca alloy as anode for Mg-air battery through homogenization prior to extrusion [J]. J. Mater. Sci. Technol., 2021, 60(0): 77-89. |
[2] | Lin Yuan, Jiangtao Xiong, Yajie Du, Jin Ren, Junmiao Shi, Jinglong Li. Microstructure and mechanical properties in the TLP joint of FeCoNiTiAl and Inconel 718 alloys using BNi2 filler [J]. J. Mater. Sci. Technol., 2021, 61(0): 176-185. |
[3] | Bin Zhang, Yuping Duan, Haifeng Zhang, Shuo Huang, Guojia Ma, Tongmin Wang, Xinglong Dong, . Magnetic transformation of Mn from anti-ferromagnetism to ferromagnetism in FeCoNiZMnx (Z = Si, Al, Sn, Ge) high entropy alloys [J]. J. Mater. Sci. Technol., 2021, 68(0): 124-131. |
[4] | Huajing Xiong, Jianan Fu, Jinyao Li, Rashad Ali, Hong Wang, Yifan Liu, Hua Su, Yuanxun Li, Woon-Ming Lau, Nasir Mahmood, Chunhong Mu, Xian Jian. Strain-regulated sensing properties of α-Fe2O3 nano-cylinders with atomic carbon layers for ethanol detection [J]. J. Mater. Sci. Technol., 2021, 68(0): 132-139. |
[5] | Xiaoyang Yi, Kuishan Sun, Jingjing Liu, Xiaohang Zheng, Xianglong Meng, Zhiyong Gao, Wei Cai. Tailoring the microstructure, martensitic transformation and strain recovery characteristics of Ti-Ta shape memory alloys by changing Hf content [J]. J. Mater. Sci. Technol., 2021, 83(0): 123-130. |
[6] | Yang Bao, Lujun Huang, Shan Jiang, Rui Zhang, Qi An, Caiwei Zhang, Lin Geng, Xinxin Ma. A novel Ti cored wire developed for wire-feed arc deposition of TiB/Ti composite coating [J]. J. Mater. Sci. Technol., 2021, 83(0): 145-160. |
[7] | Y.M. Ren, X. Lin, H.O. Yang, H. Tan, J. Chen, Z.Y. Jian, J.Q. Li, W.D. Huang. Microstructural features of Ti-6Al-4V manufactured via high power laser directed energy deposition under low-cycle fatigue [J]. J. Mater. Sci. Technol., 2021, 83(0): 18-33. |
[8] | Jingfeng Zou, Lifeng Ma, Weitao Jia, Qichi Le, Gaowu Qin, Yuan Yuan. Microstructural and mechanical response of ZK60 magnesium alloy subjected to radial forging [J]. J. Mater. Sci. Technol., 2021, 83(0): 228-238. |
[9] | Guoqiang Ma, Darcy A. Hughes, Andrew W. Godfrey, Qiang Chen, Niels Hansen, Guilin Wu. Microstructure and strength of a tantalum-tungsten alloy after cold rolling from small to large strains [J]. J. Mater. Sci. Technol., 2021, 83(0): 34-48. |
[10] | Shuting Cao, Yaqian Yang, Bo Chen, Kui Liu, Yingche Ma, Leilei Ding, Junjie Shi. Influence of yttrium on purification and carbide precipitation of superalloy K4169 [J]. J. Mater. Sci. Technol., 2021, 86(0): 260-270. |
[11] | Dan Liu, Daoxin Liu, Junfeng Cui, Xingchen Xu, Kaifa Fan, Amin Ma, Yuting He, Sara Bagherifard. Deformation mechanism and in-situ TEM compression behavior of TB8 β titanium alloy with gradient structure [J]. J. Mater. Sci. Technol., 2021, 84(0): 105-115. |
[12] | Baolei Wang, Qian Wu, Yonggang Fu, Tong Liu. A review on carbon/magnetic metal composites for microwave absorption [J]. J. Mater. Sci. Technol., 2021, 86(0): 91-109. |
[13] | Z.W. Yang, J.M. Lin, J.F. Zhang, Q.W. Qiu, Y. Wang, D.P. Wang, J. Song. An effective approach for bonding of TZM and Nb-Zr system: Microstructure evolution, mechanical properties, and bonding mechanism [J]. J. Mater. Sci. Technol., 2021, 84(0): 16-26. |
[14] | Jing Chen, Liang Wu, Xingxing Ding, Qiang Liu, Xu Dai, Jiangfeng Song, Bin Jiang, Andrej Atrens, Fusheng Pan. Effects of deformation processes on morphology, microstructure and corrosion resistance of LDHs films on magnesium alloy AZ31 [J]. J. Mater. Sci. Technol., 2021, 64(0): 10-20. |
[15] | Yong Li, Zhiyong Liu, Endian Fan, Yunhua Huang, Yi Fan, Bojie Zhao. Effect of cathodic potential on stress corrosion cracking behavior of different heat-affected zone microstructures of E690 steel in artificial seawater [J]. J. Mater. Sci. Technol., 2021, 64(0): 141-152. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||