J. Mater. Sci. Technol. ›› 2021, Vol. 83: 123-130.DOI: 10.1016/j.jmst.2020.10.088
• Research Article • Previous Articles Next Articles
Xiaoyang Yia, Kuishan Sunb, Jingjing Liub, Xiaohang Zhengb, Xianglong Mengb,*(), Zhiyong Gaob, Wei Caib
Received:
2020-09-25
Revised:
2020-10-22
Accepted:
2020-10-31
Published:
2021-02-01
Online:
2021-02-01
Contact:
Xianglong Meng
About author:
* E-mail address: xlmeng@hit.edu.cn (X. Meng).Xiaoyang Yi, Kuishan Sun, Jingjing Liu, Xiaohang Zheng, Xianglong Meng, Zhiyong Gao, Wei Cai. Tailoring the microstructure, martensitic transformation and strain recovery characteristics of Ti-Ta shape memory alloys by changing Hf content[J]. J. Mater. Sci. Technol., 2021, 83: 123-130.
x | a(Å) | b (Å) | c (Å) | V (Å3) |
---|---|---|---|---|
2 | 3.1176 | 4.8189 | 4.6375 | 69.9472 |
4 | 3.1654 | 4.8268 | 4.6381 | 71.7925 |
6 | 3.1812 | 4.8380 | 4.6770 | 72.1985 |
8 | 3.2018 | 4.8560 | 4.6864 | 72.4257 |
Table 1 Lattice parameters of solution-treated (Ti70Ta30)100-xHfx shape memory alloys.
x | a(Å) | b (Å) | c (Å) | V (Å3) |
---|---|---|---|---|
2 | 3.1176 | 4.8189 | 4.6375 | 69.9472 |
4 | 3.1654 | 4.8268 | 4.6381 | 71.7925 |
6 | 3.1812 | 4.8380 | 4.6770 | 72.1985 |
8 | 3.2018 | 4.8560 | 4.6864 | 72.4257 |
x (at.%) | Ms (℃) | Mp (℃) | Mf (℃) | As (℃) | Ap (℃) | Af (℃) |
---|---|---|---|---|---|---|
2 | - | - | - | 306.1 | 354.8 | 388.8 |
4 | 307.3 | 279.5 | 224.1 | 261.15 | 314.7 | 347.4 |
6 | 262.2 | 229.5 | 187.5 | 221.4 | 267.3 | 291.3 |
8 | 108.5 | 71.7 | 12.9 | 180.1 | 196.1 | 215.2 |
Table 2 Martensitic transformation temperatures of solution-treated (Ti70Ta30)100-xHfx shape memory alloys.
x (at.%) | Ms (℃) | Mp (℃) | Mf (℃) | As (℃) | Ap (℃) | Af (℃) |
---|---|---|---|---|---|---|
2 | - | - | - | 306.1 | 354.8 | 388.8 |
4 | 307.3 | 279.5 | 224.1 | 261.15 | 314.7 | 347.4 |
6 | 262.2 | 229.5 | 187.5 | 221.4 | 267.3 | 291.3 |
8 | 108.5 | 71.7 | 12.9 | 180.1 | 196.1 | 215.2 |
Fig. 6. Dependence of reverse martensitic transformation temperature on thermal cycling number for solution treated (Ti70Ta30)94Hf6 and (Ti70Ta30)92Hf8 alloys.
Fig. 7. (a) Room temperature tensile stress-strain curves of solution treated (Ti70Ta30)100-xHfx shape memory alloys. (b) A comparison of strength in Ti-Ta based shape memory alloys.
x (at.%) | Elastic modulus (GPa) | Yield stress (MPa) | Fracture stress (MPa) | Fracture strain (%) |
---|---|---|---|---|
2 | 76.1 | 358 | 678 | 19.3 |
4 | 76.5 | 337 | 686 | 14.9 |
6 | 77.5 | 291 | 719 | 10.9 |
8 | 79.5 | 401 | 1262 | 9.8 |
Table 3 The mechanical properties of solution-treated (Ti70Ta30)100-xHfx shape memory alloys.
x (at.%) | Elastic modulus (GPa) | Yield stress (MPa) | Fracture stress (MPa) | Fracture strain (%) |
---|---|---|---|---|
2 | 76.1 | 358 | 678 | 19.3 |
4 | 76.5 | 337 | 686 | 14.9 |
6 | 77.5 | 291 | 719 | 10.9 |
8 | 79.5 | 401 | 1262 | 9.8 |
Fig. 10. Stress-strain curves obtained from cyclic loading-unloading tensile tests for solution-treated (Ti70Ta30)100-xHfx shape memory alloys (a) x = 2; (b) x = 4; (c) x = 6; (d) x = 8.
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