One-step fabrication of two-dimensional hierarchical Mn2O3@graphene composite as high-performance anode materials for lithium ion batteries

doi:10.1016/j.jmst.2020.12.006

Abstract

Abstract:

Two-dimensional (2D) hierarchical Mn₂O₃@graphene composite is synthesized by a one-step solid-phase reaction. The nanosheets of Mn₂O₃ are vertically grown on few-layered graphene, constructing a unique 2D hierarchical structure. As an anode material for lithium-ion batteries (LIBs), this hierarchical composite displays excellent electrochemical performances, showing an extraordinary reversible discharge capacity of 2125.9 mA h g^-1. Moreover, a record high reversible capacity of 1746.8 mA h g^-1 is maintained after 100 cycles at a current density of 100 mA g^-1, which retains 82.2 % of the initial capacity. Such an outstanding performance could be attributed to its novel structure and the synergistic effects between the Mn₂O₃ and graphene.

Key words: Mn₂O₃, Graphene, Anode material, 2D hierarchical structure, Lithium ion battery

Zhou Zhou, Chaoying Ding, Wenchao Peng, Yang Li, Fengbao Zhang, Xiaobin Fan. One-step fabrication of two-dimensional hierarchical Mn₂O₃@graphene composite as high-performance anode materials for lithium ion batteries[J]. J. Mater. Sci. Technol., 2021, 80: 13-19.

Figures/Tables 7

Scheme 1. Schematic illustration of the formation process of Mn2O3@graphene. The dashed boxes in Scheme 1 indicate the lithium ions intercalation electrode material and electron transfer during discharge-charge cycling.

Fig. 1. (a) XRD patterns of Mn2O3@graphene composite. (b) TGA curves of Mn2O3@graphene and NaMnxOy sample at a heating rate of 10 °C min -1 under air flux. (c) Raman spectrum.

Fig. 2. (a, b, c, d) SEM images of Mn2O3@graphene composite. (e, f) HRTEM image and (g) elemental mapping of the Mn2O3@graphene composite.

Fig. 3. (a) XPS survey scan spectrum. (b) high-resolution XPS spectra of the Mn2O3@graphene composite and NaMnxOy. (c) XPS spectrum of Mn 2p.

Fig. 4. Electrochemical performance of Mn2O3@graphene composite: (a) CV curves at a scan rate of 0.1 mV s-1, (b) cycling performances between the Mn2O3@g - 10, Mn2O3@g-20, Mn2O3@g-50, Mn2O3@g - 100, Mn2O3@g-200, graphene and NaMnxOy at the current of 100 mA g-1, (c) cycling performances of the Mn2O3@G-20 at the current of 500 mA g-1, (d) rate capabilities.

Fig. 5. (a) Selected discharge voltage profiles. (b) The difference of the capacities between the 100th and the 10th cycle and their differential vs. voltage. (c) XRD pattern of Mn2O3@graphene composite electrode after discharging to 2.35 V (I), 0.46 V (II), 0.43 V (III), 0.18 V (IV) and 0.03 V (V).

Fig. 6. EIS spectrum of Mn2O3@graphene composite and NaMnxOy electrodes.

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One-step fabrication of two-dimensional hierarchical Mn₂O₃@graphene composite as high-performance anode materials for lithium ion batteries

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