High Temperature Thermoelectric Properties of Dy-doped CaMnO3 Ceramics

Abstract

Abstract: Dy-doped CaMnO₃ ceramics have been synthesized by co-precipitation method combined with the solid-state reaction. Phase composition and microstructure analysis indicate that high density and pure CaMnO₃ phase can be achieved. The electric conductivity can be enhanced by Dy doping, and result in a slight increase of the thermal conductivity. The highest dimensionless figure of merit ZT of 0.15 has been obtained at 973 K for x=0.02 sample, which is about 4 times larger than that of the pure CaMnO₃, which indicate that CaMnO₃ can be a promising candidate for n-type thermoelectric material at high temperature.

Key words: CaMnO3, Thermoelectric properties, Thermal conductivity

Bin Zhan, Jinle Lan, Yaochun Liu, Yuanhua Lin, Yang Shen, Cewen Nan. High Temperature Thermoelectric Properties of Dy-doped CaMnO₃ Ceramics[J]. J. Mater. Sci. Technol., 2014, 30(8): 821-825.

References

[1] R. Venkatasubramanian, E. Siivola, T. Colpitts; B. O'Quinn Nature, 413 (2001), pp. 597-602
[2] A.J. Minnich, M.S. Dresselhaus, Z.F. Ren, G. Chen; Energy Environ. Sci., 2 (2009), pp. 466-479
[3] J.W. Fergus J. Eur; Ceram. Soc., 32 (2012), pp. 525-540
[4] J.R. Sootsman, D.Y. Chung, M.G. Kanatzidis; Angew. Chem. Int. Edit., 48 (2009), pp. 8616-8639
[5] B. Poudel, Q. Hao, Y. Ma, Y.C. Lan, A. Minnich, B. Yu, X. Yan, D.Z. Wang, A. Muto, D. Vashaee, X.Y. Chen, J.M. Liu, M.S. Dresselhaus, G. Chen, Z.F. Ren; Science, 320 (2008), pp. 634-638
[6] J.P. Heremans, V. Jovovic, E.S. Toberer, A. Saramat, K. Kurosaki, A. Charoenphakdee, S. Yamanaka, G.J. Snyder; Science, 321 (2008), pp. 554-557
[7] X.W. Wang, H. Lee, Y.C. Lan, G.H. Zhu, G. Joshi, D.Z. Wang, J. Yang, A.J. Muto, M.Y. Tang, J. Klatsky, S. Song, M.S. Dresselhaus, G. Chen, Z.F. Ren; Appl. Phys. Lett., 93 (2008), p. 193121
[8] Y. Wang, Y. Shi, J.G. Cheng, X.J. Wang, W.H. Su; J. Alloy. Compd., 477 (2009), pp. 817-821
[9] Y.H. Lin, J. Lan, Z.J. Shen, Y.H. Liu, C.W. Nan, J.F. Li; Appl. Phys. Lett., 94 (2009), p. 072107
[10] A. Kikuchi, N. Okinaka, T. Akiyama; Scripta Mater., 63 (2010), pp. 407-410
[11] M. Ohtaki, K. Araki, K. Yamamoto; J. Electron. Mater., 38 (2009), pp. 1234-1238
[12] J. Li, J.H. Sui, Y.L. Pei, C. Barreteau, D. Berardan, N. Dragoe, W. Cai, J.Q. He, L.D. Zhao; Energy Environ. Sci., 5 (2012), pp. 8543-8547
[13] Y. Liu, L.D. Zhao, Y.C. Liu, J.L. Lan, W. Xu, F. Li, B.P. Zhang, D. Berardan, N. Dragoe, Y.H. Lin, C.W. Nan, J.F. Li, H.M. Zhu; J. Am. Chem. Soc., 133 (2011), pp. 20112-20115
[14] J.L. Lan, Y.H. Lin, A. Mei, C.W. Nan, Y. Liu, B.P. Zhang, J.F. Li; J. Mater. Sci. Technol., 25 (2009), pp. 535-538
[15] S. Populoh, M. Trottmann, M.H. Aguire, A. Weidenkaff; J. Mater. Res., 26 (2011), pp. 1947-1952
[16] L. Bocher, M.H. Aguirre, D. Logvinovich, A. Shkabko, R. Robert, M. Trottmann, A. Weidenkaff; Inorg. Chem., 47 (2008), pp. 8077-8085
[17] C.L. Wang, L. Shi, X.M. Xu, S.M. Zhou, J.Y. Zhao, Y.Q. Guo, H.F. Liu, L.F. He, X. Cai, G.J. Xu; Appl. Phys. A, 112 (2013), pp. 1003-1009
[18] A. Bhaskar, C.J. Liu, J.J. Yuan, C.L. Chang; J. Alloy. Compd., 552 (2013), pp. 236-239
[19] J.L. Lan, Y.H. Lin, H. Fang, A. Mei, C.W. Nan, Y. Liu, S.L. Xu, M. Peters; J. Am. Ceram. Soc., 93 (2010), pp. 2121-2124
[20] Y. Wang, Y. Sui, W. Su; J. Appl. Phys., 104 (2008), p. 093703
[21] H. Muguerra, B. Rivas-Murias, M. Traianidis, C. Marchal, Ph. Vanderbemden, B. Vertruyen, C. Henrist, R. Cloots; J. Alloy. Compd., 509 (2011), pp. 7710-7716
[22] R.D. Shannon Acta; Crystallogr. A, 32 (1976), pp. 751-767
[23] A.J. Bosmana, H.J. van; Daala Adv. Phys., 19 (1970), pp. 1-117
[24] A. Bhaskar, J.J. Yuan, C.J. Liu; J. Electroceram., 31 (2013), pp. 124-128

High Temperature Thermoelectric Properties of Dy-doped CaMnO₃ Ceramics

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