J. Mater. Sci. Technol. ›› 2022, Vol. 105: 142-152.DOI: 10.1016/j.jmst.2021.06.076
• Research Article • Previous Articles Next Articles
Xuan Konga, Yang Liub, Minghui Chena,*(), Tao Zhanga, Qunchang Wanga, Fuhui Wanga
Received:
2021-03-11
Revised:
2021-06-27
Accepted:
2021-06-29
Published:
2021-09-20
Online:
2021-09-20
Contact:
Minghui Chen
About author:
*E-mail address: mhchen@mail.neu.edu.cn (M. Chen).Xuan Kong, Yang Liu, Minghui Chen, Tao Zhang, Qunchang Wang, Fuhui Wang. Heterostructured NiCr matrix composites with high strength and wear resistance[J]. J. Mater. Sci. Technol., 2022, 105: 142-152.
Elements | Ni | Cr | O | C | S | Fe | Ti | Ca | W | Si |
---|---|---|---|---|---|---|---|---|---|---|
Ni20Cr | 79.2 | 20.47 | 0.05 | - | - | 0.28 | - | - | - | - |
Ti | 0.002 | - | - | 0.002 | 0.002 | 0.002 | 99.988 | 0.002 | - | 0.002 |
WS2 | 0.002 | - | 0.02 | - | 25.85 | 0.002 | 0.002 | 0.002 | 74.12 | 0.002 |
Table 1. Chemical compositions of powders (wt.%).
Elements | Ni | Cr | O | C | S | Fe | Ti | Ca | W | Si |
---|---|---|---|---|---|---|---|---|---|---|
Ni20Cr | 79.2 | 20.47 | 0.05 | - | - | 0.28 | - | - | - | - |
Ti | 0.002 | - | - | 0.002 | 0.002 | 0.002 | 99.988 | 0.002 | - | 0.002 |
WS2 | 0.002 | - | 0.02 | - | 25.85 | 0.002 | 0.002 | 0.002 | 74.12 | 0.002 |
Samples | Composition (wt.%) |
---|---|
N | Ni20Cr |
NW | Ni20Cr + 15% WS2 |
NW5T | Ni20Cr + 15% WS2 + 5% Ti |
NW10T | Ni20Cr + 15% WS2 + 10% Ti |
NW15T | Ni20Cr + 15% WS2 + 15% Ti |
Table 2. Composition of the mixed powders or composites.
Samples | Composition (wt.%) |
---|---|
N | Ni20Cr |
NW | Ni20Cr + 15% WS2 |
NW5T | Ni20Cr + 15% WS2 + 5% Ti |
NW10T | Ni20Cr + 15% WS2 + 10% Ti |
NW15T | Ni20Cr + 15% WS2 + 15% Ti |
Fig. 1. XRD patterns of the composites NW, NW5T, NW10T and NW15T: (a) general view from 10° to 90°, (b) an enlarged view of the dotted box area in (a).
Spots | Ni | Cr | W | Ti | S |
---|---|---|---|---|---|
1 | 23.6 | 37.1 | 1.4 | 0 | 37.9 |
2 | 29.7 | 27.4 | 35.4 | 0 | 7.5 |
3 | 79.9 | 15.6 | 4.3 | / | 0.2 |
4 | 2.2 | 18.0 | 0.2 | 48.0 | 31.6 |
5 | 71.5 | 21.5 | 0.9 | 6.1 | 0 |
6 | 19.7 | 5.1 | 2.6 | 39.4 | 33.2 |
7 | 55.4 | 7.3 | 2.8 | 33.8 | 0.7 |
Table 3. EDS analysis at spots denoted in Fig. 2 (at.%).
Spots | Ni | Cr | W | Ti | S |
---|---|---|---|---|---|
1 | 23.6 | 37.1 | 1.4 | 0 | 37.9 |
2 | 29.7 | 27.4 | 35.4 | 0 | 7.5 |
3 | 79.9 | 15.6 | 4.3 | / | 0.2 |
4 | 2.2 | 18.0 | 0.2 | 48.0 | 31.6 |
5 | 71.5 | 21.5 | 0.9 | 6.1 | 0 |
6 | 19.7 | 5.1 | 2.6 | 39.4 | 33.2 |
7 | 55.4 | 7.3 | 2.8 | 33.8 | 0.7 |
Materials | Hardness (HV) | Yield strength (MPa) | Compressive strength (MPa) | Ultimate plasticity strain (%) |
---|---|---|---|---|
N | 198±11 | 396±12 | unbroken | unbroken |
NW | 286±16 | 658±38 | 1485±20 | 21±1.7 |
NW5T | 441±30 | 961±38 | 1438±35 | 11.9 ± 1.0 |
NW10T | 521±65 | 1010±14 | 1550±15 | 11.2 ± 0.8 |
NW15T | 720±48 | 1645±28 | 1906±19 | 5.2 ± 0.3 |
Table 4. Mechanical properties of the NiCr alloy and the self-lubricating composites.
Materials | Hardness (HV) | Yield strength (MPa) | Compressive strength (MPa) | Ultimate plasticity strain (%) |
---|---|---|---|---|
N | 198±11 | 396±12 | unbroken | unbroken |
NW | 286±16 | 658±38 | 1485±20 | 21±1.7 |
NW5T | 441±30 | 961±38 | 1438±35 | 11.9 ± 1.0 |
NW10T | 521±65 | 1010±14 | 1550±15 | 11.2 ± 0.8 |
NW15T | 720±48 | 1645±28 | 1906±19 | 5.2 ± 0.3 |
Fig. 5. Tribological properties of the NiCr alloy (N) and the composites from NW to NW15T: (a) friction coefficient curves, (b) average friction coefficients, (c) wear scar profiles, (d) wear rates..
Spots | Ni | Cr | W | Ti | S | O | Si |
---|---|---|---|---|---|---|---|
1 | 26.5 | 26.6 | 9.6 | 0 | 30.6 | 5.9 | 0.8 |
2 | 14.0 | 4.0 | 11.7 | 29.6 | 27.9 | 12.8 | 0 |
3 | 47.5 | 13.4 | 2.7 | 35.6 | 0.8 | 0 | 0 |
4 | 54.3 | 14.9 | 2.7 | 25.7 | 2.4 | 0 | 0 |
5 | 9.2 | 4.8 | 0.5 | 54.3 | 31.2 | 0 | 0 |
Table 5. EDS analysis at spots denoted in Figs. 6 and 7 (at.%).
Spots | Ni | Cr | W | Ti | S | O | Si |
---|---|---|---|---|---|---|---|
1 | 26.5 | 26.6 | 9.6 | 0 | 30.6 | 5.9 | 0.8 |
2 | 14.0 | 4.0 | 11.7 | 29.6 | 27.9 | 12.8 | 0 |
3 | 47.5 | 13.4 | 2.7 | 35.6 | 0.8 | 0 | 0 |
4 | 54.3 | 14.9 | 2.7 | 25.7 | 2.4 | 0 | 0 |
5 | 9.2 | 4.8 | 0.5 | 54.3 | 31.2 | 0 | 0 |
Fig. 10. Schematic diagram showing (a) mechanical response of hetero structure to load, stress distribution analyzed by finite element in composites (b) NW and (c) NW15T.
Fig. 11. Comparison of the yield strength and friction coefficient of NW15T with other self-lubricating composites [9], [25], [35], [36], [37], [38], [39], [40], [41], [42].
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