Role of Heavy Metal Ions in the Formation of Oxyfluoride Glasses and Glass Ceramics

doi:10.1016/j.jmst.2014.02.003

Abstract

Abstract: In order to investigate the influence of different heavy metal ions on the formation of the oxyfluoride glasses and glass ceramics, samples with different PbF₂/CdF₂ ratios have been prepared by the melting quenching and thermal treatment method. The different effects of Pb²⁺ and Cd²⁺ on the glass network structure are investigated by FTIR and Raman spectra. During the formation of glass network structure, Pb²⁺ prefers to break the Si-O-Si bond and subsequently bond to F^- for charge compensation, and Cd²⁺ prefers to break the Si-O-Al bond and is surrounded by O^2-. Pb²⁺ and F^- gather together and form the fluoride nanocrystals, while Cd²⁺ remains in oxide matrix after thermal treatment. Introduction of proper CdF₂ is important to adjust and control the glass network structure and crystallization process in the fabrication of the transparent glass ceramics.

Key words: Pb, Cd, Glass network, Oxyfluoride glass ceramics

Min Liu, Lijuan Zhao, Yan Liu, Zijian Lan, Lifen Chang, Yiming Li, Hua Yu. Role of Heavy Metal Ions in the Formation of Oxyfluoride Glasses and Glass Ceramics[J]. J. Mater. Sci. Technol., 2014, 30(12): 1213-1216.

References

[1] Y. Wang, J. Ohwaki, Appl. Phys. Lett. 63 (1993) 3268e3270.
[2] P.A. Tick, N.F. Borrelli, L.K. Cornelius, M.A. Newhouse, J. Appl. Phys. 78 (1995) 6367e6374.
[3] H. Guo, H. Yu, X.X. Zhang, L.F. Chang, Z.J. Lan, Y.M. Li, L.J. Zhao, Opt. Express 21 (2013) 24742e24745.
[4] K. Driesen, V.K. Tikhomirov, C. Görller-Walrand, V.D. Rodriguez, A.B. Seddon, Appl. Phys. Lett. 88 (2006) 073111.
[5] V.K. Tikhomirov, M. Mortier, P. Gredin, G. Patriarche, C. Görller-Walrand, V.V. Moshchalkov, Opt. Express 16 (2008) 14544e 14549.
[6] F. Lahoz, N. Capuj, P. Haro-González, I.R. Martín, C. Pérez- Rodríguez, J.M. Cáceres, J. Appl. Phys. 109 (2011) 043102.
[7] L.L. Kukkonen, I.M. Reaney, D. Furniss, M.G. Pellatt, A.B. Seddon, J. Non-Cryst. Solids 290 (2001) 25e31.
[8] V.K. Tikhomirov, D. Furniss, A.B. Seddon, I.M. Reaney, M. Beggiora, M. Ferrari, M. Montagna, R. Rolli, Appl. Phys. Lett. 81 (2002) 1937e1939.
[9] M. Mortier, P. Goldner, C. Chateau, M. Genotelle, J. Alloy. Compd. 323e324 (2001) 245e249.
[10] S. Haas, A. Hoell, Phys. Rev. B 81 (2010) 184207.
[11] N. Hu, H. Yu, M. Zhang, P. Zhang, Y.Z. Wang, L.J. Zhao, Phys. Chem. Chem. Phys. 13 (2011) 1499e1505.
[12] H. Yu, L.J. Zhao, J. Meng, Q. Liang, X.Y. Yu, B.Q. Tang, J.J. Xu, Chin. Opt. Lett. 3 (2005) 469e471.
[13] Z.C. Duan, J.J. Zhang, D.B. He, H.T. Sun, L.L. Hu, Mater. Chem. Phys. 100 (2006) 400e403.
[14] A.A. Bahgat, M.G. Moustafa, E.E. Shaisha, J. Mater. Sci. Technol.
29 (2013) 1166e1176.
[15] M.S. Al-Assiri, M.M. El-Desoky, A. Al-Hajry, A. Al-Shahrani, A. M. Al-Mogeeth, A.A. Bahgat, Physica B 404 (2009) 1437e1445.
[16] B.O. Mysen, D. Vigo, C.M. Scarfe, Am. Mineral. 65 (1980) 690e 710.
[17] M. Liu, H. Yu, P. Zhang, M. Zhang, Y. Liu, L.J. Zhao, Acta Phys. Sin. 61 (2012) 118102 (in Chinese).
[18] C.J. Merzbacher, W.B. White, J. Non-Cryst. Solids 130 (1991) 18e 34.
[19] J.P. Hamilton, S.L. Brantley, C.G. Puntano, L.J. Criscenti, J.D. Kubicki, Geochim. Cosmochim. Acta 65 (2001) 3683e3702.
[20] R.G. Duan, K.M. Liang, S.R. Gu, J. Inorg. Mater. 13 (1998) 593e 598.
[21] B.N. Roy, J. Am. Ceram. Soc. 73 (1990) 846e855.
[22] M. _Sroda, C. Paluszkiewicz, Vib. Spectrosc. 48 (2008) 246e250.
[23] C. Huang, E.C. Behrman, J. Non-Cryst. Solids 128 (1991) 310e 321.
[24] C.M. Baldwin, J.D. Mackenzie, J. Am. Ceram. Soc. 62 (1979) 532e538.
[25] M.A.P. Silva, V. Briois, M. Poulain, Y. Messaddeq, S.J.L. Ribeiro, J. Phys. Chem. Solids 64 (2003) 95e105.
[26] M.A.P. Silva, Y. Messaddeq, V. Briois, M. Poulain, S.J.L. Ribeiro, J. Braz. Chem. Soc. 13 (2002) 200e206.
[27] J.S. Cheng, H. Li, L.Y. Tang, F. He, Glass Ceramics, ChemicalIndustry Press, Beijing, 2006, pp. 102e105 (in Chinese).