Effects of thiosulfate and dissolved oxygen on crevice corrosion of Alloy 690 in high-temperature chloride solution

doi:10.1016/j.jmst.2020.05.074

Abstract

Abstract:

The crevice corrosion behavior of Alloy 690 was investigated in high-temperature chloride solution containing different concentrations of thiosulfate (S₂O₃^2-) and dissolved oxygen (DO). The S₂O₃^2- inhibited corrosion of Alloy 690 through consuming oxygen in aerated chloride solution. In deaerated chloride solution, the S₂O₃^2- was reduced to S° and S^2- and subsequently incorporated into the oxide films, which promoted the pitting corrosion at locations of both TiN inclusions and matrix inside the crevice during the crevice corrosion as well as influenced the composition and thickness of the oxide films. The effect mechanisms of S₂O₃^2- and DO on crevice corrosion in high-temperature chloride solution are discussed.

Key words: Alloy, Crevice corrosion, Pitting corrosion, High-temperature corrosion, Thiosulfate, Oxidation

Fangqiang Ning, Jibo Tan, Ziyu Zhang, Xinqiang Wu, Xiang Wang, En-Hou Han, Wei Ke. Effects of thiosulfate and dissolved oxygen on crevice corrosion of Alloy 690 in high-temperature chloride solution[J]. J. Mater. Sci. Technol., 2021, 66: 163-176.

Figures/Tables 21

References 70

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Test ID	Chemical composition (mol/L)		Dissolved oxygen
Test ID	NaCl	Na₂S₂O₃	Dissolved oxygen
NC1	0.01	0	Aerated
NC2	0.01	10^-4	Aerated
NC3	0.01	0	Deaerated
NC4	0.01	10^-4	Deaerated

Test ID	Chemical composition (mol/L)		Dissolved oxygen
Test ID	NaCl	Na₂S₂O₃	Dissolved oxygen
NC1	0.01	0	Aerated
NC2	0.01	10^-4	Aerated
NC3	0.01	0	Deaerated
NC4	0.01	10^-4	Deaerated

Element	Species	Binding energy (eV)	References
S	SO₄^2- (2p)	168.1-169.4	[36,37]
	SO₃^2- (2p)	166.0-167.0	[38,39]
	S^2- (2p)	162.5, 163.7	[18,40]
O	O^2- (1 s)	530.3	[3]
	OH^-(1 s)	531.7	[3]
Ni	Ni⁰ (2p3/2)	852.7	[[3], [4], [5], [6], [7], [8], [9], [10], [11], [12], [13], [14], [15], [16], [17], [18], [19], [20], [21], [22], [23], [24], [25], [26], [27], [28], [29], [30], [31], [32], [33], [34], [35], [36], [37], [38], [39], [40], [41], [42], [43], [44], [45]]
	Ni⁰ _sat (2p3/2)	858.5	[[3], [4], [5], [6], [7], [8], [9], [10], [11], [12], [13], [14], [15], [16], [17], [18], [19], [20], [21], [22], [23], [24], [25], [26], [27], [28], [29], [30], [31], [32], [33], [34], [35], [36], [37], [38], [39], [40], [41], [42], [43], [44], [45]]
	Ni²⁺_OX (2p3/2)	854.4	[[3], [4], [5], [6], [7], [8], [9], [10], [11], [12], [13], [14], [15], [16], [17], [18], [19], [20], [21], [22], [23], [24], [25], [26], [27], [28], [29], [30], [31], [32], [33], [34], [35], [36], [37], [38], [39], [40], [41], [42], [43], [44], [45]]
	Ni²⁺_OH (2p3/2)	856.5	[[3], [4], [5], [6], [7], [8], [9], [10], [11], [12], [13], [14], [15], [16], [17], [18], [19], [20], [21], [22], [23], [24], [25], [26], [27], [28], [29], [30], [31], [32], [33], [34], [35], [36], [37], [38], [39], [40], [41], [42], [43], [44], [45]]
	Ni²⁺_sat (2p3/2)	861.7	[[3], [4], [5], [6], [7], [8], [9], [10], [11], [12], [13], [14], [15], [16], [17], [18], [19], [20], [21], [22], [23], [24], [25], [26], [27], [28], [29], [30], [31], [32], [33], [34], [35], [36], [37], [38], [39], [40], [41], [42], [43], [44], [45]]
Cr	Cr⁰ (2p3/2)	574.3	[[3], [4], [5], [6], [7], [8], [9], [10], [11], [12], [13], [14], [15], [16], [17], [18], [19], [20], [21], [22], [23], [24], [25], [26], [27], [28], [29], [30], [31], [32], [33], [34], [35], [36], [37], [38], [39], [40], [41], [42], [43], [44], [45]]
	Cr³⁺_OX (2p3/2)	576.1	[[3], [4], [5], [6], [7], [8], [9], [10], [11], [12], [13], [14], [15], [16], [17], [18], [19], [20], [21], [22], [23], [24], [25], [26], [27], [28], [29], [30], [31], [32], [33], [34], [35], [36], [37], [38], [39], [40], [41], [42], [43], [44], [45]]
	Cr³⁺_OH (2p3/2)	577.6	[[3], [4], [5], [6], [7], [8], [9], [10], [11], [12], [13], [14], [15], [16], [17], [18], [19], [20], [21], [22], [23], [24], [25], [26], [27], [28], [29], [30], [31], [32], [33], [34], [35], [36], [37], [38], [39], [40], [41], [42], [43], [44], [45]]
Fe	Fe⁰ (2p3/2)	707.2	[[3], [4], [5], [6], [7], [8], [9], [10], [11], [12], [13], [14], [15], [16], [17], [18], [19], [20], [21], [22], [23], [24], [25], [26], [27], [28], [29], [30], [31], [32], [33], [34], [35], [36], [37], [38], [39], [40], [41], [42], [43], [44], [45]]
	Fe²⁺ (2p3/2)	709.0	[[3], [4], [5], [6], [7], [8], [9], [10], [11], [12], [13], [14], [15], [16], [17], [18], [19], [20], [21], [22], [23], [24], [25], [26], [27], [28], [29], [30], [31], [32], [33], [34], [35], [36], [37], [38], [39], [40], [41], [42], [43], [44], [45]]
	Fe³⁺ (2p3/2)	711.3	[[3], [4], [5], [6], [7], [8], [9], [10], [11], [12], [13], [14], [15], [16], [17], [18], [19], [20], [21], [22], [23], [24], [25], [26], [27], [28], [29], [30], [31], [32], [33], [34], [35], [36], [37], [38], [39], [40], [41], [42], [43], [44], [45]]

Element	Species	Binding energy (eV)	References
S	SO₄^2- (2p)	168.1-169.4	[36,37]
	SO₃^2- (2p)	166.0-167.0	[38,39]
	S^2- (2p)	162.5, 163.7	[18,40]
O	O^2- (1 s)	530.3	[3]
	OH^-(1 s)	531.7	[3]
Ni	Ni⁰ (2p3/2)	852.7	[[3], [4], [5], [6], [7], [8], [9], [10], [11], [12], [13], [14], [15], [16], [17], [18], [19], [20], [21], [22], [23], [24], [25], [26], [27], [28], [29], [30], [31], [32], [33], [34], [35], [36], [37], [38], [39], [40], [41], [42], [43], [44], [45]]
	Ni⁰ _sat (2p3/2)	858.5	[[3], [4], [5], [6], [7], [8], [9], [10], [11], [12], [13], [14], [15], [16], [17], [18], [19], [20], [21], [22], [23], [24], [25], [26], [27], [28], [29], [30], [31], [32], [33], [34], [35], [36], [37], [38], [39], [40], [41], [42], [43], [44], [45]]
	Ni²⁺_OX (2p3/2)	854.4	[[3], [4], [5], [6], [7], [8], [9], [10], [11], [12], [13], [14], [15], [16], [17], [18], [19], [20], [21], [22], [23], [24], [25], [26], [27], [28], [29], [30], [31], [32], [33], [34], [35], [36], [37], [38], [39], [40], [41], [42], [43], [44], [45]]
	Ni²⁺_OH (2p3/2)	856.5	[[3], [4], [5], [6], [7], [8], [9], [10], [11], [12], [13], [14], [15], [16], [17], [18], [19], [20], [21], [22], [23], [24], [25], [26], [27], [28], [29], [30], [31], [32], [33], [34], [35], [36], [37], [38], [39], [40], [41], [42], [43], [44], [45]]
	Ni²⁺_sat (2p3/2)	861.7	[[3], [4], [5], [6], [7], [8], [9], [10], [11], [12], [13], [14], [15], [16], [17], [18], [19], [20], [21], [22], [23], [24], [25], [26], [27], [28], [29], [30], [31], [32], [33], [34], [35], [36], [37], [38], [39], [40], [41], [42], [43], [44], [45]]
Cr	Cr⁰ (2p3/2)	574.3	[[3], [4], [5], [6], [7], [8], [9], [10], [11], [12], [13], [14], [15], [16], [17], [18], [19], [20], [21], [22], [23], [24], [25], [26], [27], [28], [29], [30], [31], [32], [33], [34], [35], [36], [37], [38], [39], [40], [41], [42], [43], [44], [45]]
	Cr³⁺_OX (2p3/2)	576.1	[[3], [4], [5], [6], [7], [8], [9], [10], [11], [12], [13], [14], [15], [16], [17], [18], [19], [20], [21], [22], [23], [24], [25], [26], [27], [28], [29], [30], [31], [32], [33], [34], [35], [36], [37], [38], [39], [40], [41], [42], [43], [44], [45]]
	Cr³⁺_OH (2p3/2)	577.6	[[3], [4], [5], [6], [7], [8], [9], [10], [11], [12], [13], [14], [15], [16], [17], [18], [19], [20], [21], [22], [23], [24], [25], [26], [27], [28], [29], [30], [31], [32], [33], [34], [35], [36], [37], [38], [39], [40], [41], [42], [43], [44], [45]]
Fe	Fe⁰ (2p3/2)	707.2	[[3], [4], [5], [6], [7], [8], [9], [10], [11], [12], [13], [14], [15], [16], [17], [18], [19], [20], [21], [22], [23], [24], [25], [26], [27], [28], [29], [30], [31], [32], [33], [34], [35], [36], [37], [38], [39], [40], [41], [42], [43], [44], [45]]
	Fe²⁺ (2p3/2)	709.0	[[3], [4], [5], [6], [7], [8], [9], [10], [11], [12], [13], [14], [15], [16], [17], [18], [19], [20], [21], [22], [23], [24], [25], [26], [27], [28], [29], [30], [31], [32], [33], [34], [35], [36], [37], [38], [39], [40], [41], [42], [43], [44], [45]]
	Fe³⁺ (2p3/2)	711.3	[[3], [4], [5], [6], [7], [8], [9], [10], [11], [12], [13], [14], [15], [16], [17], [18], [19], [20], [21], [22], [23], [24], [25], [26], [27], [28], [29], [30], [31], [32], [33], [34], [35], [36], [37], [38], [39], [40], [41], [42], [43], [44], [45]]