J. Mater. Sci. Technol. ›› 2021, Vol. 69: 7-14.DOI: 10.1016/j.jmst.2020.03.092
• Research Article • Previous Articles Next Articles
Pengfei Ji, Bohan Chen, Bo Li, Yihao Tang, Guofeng Zhang, Xinyu Zhang, Mingzhen Ma, Riping Liu*()
Received:
2020-03-07
Revised:
2020-03-29
Accepted:
2020-03-31
Published:
2021-04-10
Online:
2021-05-15
Contact:
Riping Liu
About author:
*E-mail address: riping@ysu.edu.cn (R. Liu).Pengfei Ji, Bohan Chen, Bo Li, Yihao Tang, Guofeng Zhang, Xinyu Zhang, Mingzhen Ma, Riping Liu. Influence of Nb addition on microstructural evolution and compression mechanical properties of Ti-Zr alloys[J]. J. Mater. Sci. Technol., 2021, 69: 7-14.
Alloys | Ti (at %) | Zr (at %) | Nb (at %) | Bo- | Md- |
---|---|---|---|---|---|
TZ0N | 50 | 50 | - | 2.938 | 2.691 |
TZ5N | 47.5 | 47.5 | 5 | 2.946 | 2.677 |
TZ10N | 45 | 45 | 10 | 2.954 | 2.664 |
TZ20N | 40 | 40 | 20 | 2.970 | 2.637 |
TZN | 33.33 | 33.33 | 33.33 | 2.962 | 2.576 |
Table 1 The components, names and calculated values of $\overline {Bo}$ and $\overline { Md }$ of the studied alloys.
Alloys | Ti (at %) | Zr (at %) | Nb (at %) | Bo- | Md- |
---|---|---|---|---|---|
TZ0N | 50 | 50 | - | 2.938 | 2.691 |
TZ5N | 47.5 | 47.5 | 5 | 2.946 | 2.677 |
TZ10N | 45 | 45 | 10 | 2.954 | 2.664 |
TZ20N | 40 | 40 | 20 | 2.970 | 2.637 |
TZN | 33.33 | 33.33 | 33.33 | 2.962 | 2.576 |
Fig. 1. (a) XRD patterns of the studied alloys with different Nb contents, (b) (211) peak in TZ0N, TZ20N and TZN alloys, and (c) the variation of $\overline {Bo}$, $\overline {Md}$ and phase composition with respect to Nb content.
Fig. 4. The microstructure and corresponding SAED patterns of (a) TZ10 N, (b) TZ20 N and (c) TZN alloy, and (d) the grain size of α, α″ and β phases with respect to Nb content.
Alloys | Zeff | Bond energy |
---|---|---|
TZ0N | 3.41 | 1.384 |
TZ5N | 3.42 | 1.406 |
TZ10N | 3.43 | 1.428 |
TZ20N | 3.45 | 1.473 |
TZN | 3.476 | 1.552 |
Table 2 The $\overline {Z_{eff}}$ and bonding force values of the TZ0N, TZ5N, TZ10 N, TZ20 N and TZN alloys.
Alloys | Zeff | Bond energy |
---|---|---|
TZ0N | 3.41 | 1.384 |
TZ5N | 3.42 | 1.406 |
TZ10N | 3.43 | 1.428 |
TZ20N | 3.45 | 1.473 |
TZN | 3.476 | 1.552 |
Fig. 5. (a) The room-temperature engineering compression stress-strain curves of the studied alloys and (b) the elastic deformation and compressive yield strength stages from the given curves.
Alloys | Elastic modulus (GPa) | Yield strength (MPa) | Compressive strength (MPa) | Compressive elongation (%) |
---|---|---|---|---|
TZ0N | 44 | 967 | 1870.2 | 28.21 |
TZ5N | 40 | 914 | 2043.2 | 32.51 |
TZ10N | 35 | 649 | > 2096.7 | > 54 % |
TZ20N | 42 | 873 | > 2413.6 | > 54 % |
TZN | 49 | 1137 | > 2914.7 | > 54 % |
Table 3 The mechanical properties of TZ0N, TZ5N, TZ10 N, TZ20 N and TZN alloys.
Alloys | Elastic modulus (GPa) | Yield strength (MPa) | Compressive strength (MPa) | Compressive elongation (%) |
---|---|---|---|---|
TZ0N | 44 | 967 | 1870.2 | 28.21 |
TZ5N | 40 | 914 | 2043.2 | 32.51 |
TZ10N | 35 | 649 | > 2096.7 | > 54 % |
TZ20N | 42 | 873 | > 2413.6 | > 54 % |
TZN | 49 | 1137 | > 2914.7 | > 54 % |
Fig. 6. (a) The compressive strain-hardening rate (Θ= dσ/dε) vs. the logarithmic strain of the studied alloys and (b) the detail of compressive strain-hardening rate (Θ= dσ/dε) vs. the logarithmic strain of β-alloys.
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