J. Mater. Sci. Technol. ›› 2021, Vol. 62: 25-33.DOI: 10.1016/j.jmst.2020.04.062
• Research Article • Previous Articles Next Articles
Ruobin Changa,b, Wei Fanga,b,*(
), Jiaohui Yanb, Haoyang Yub, Xi Baib, Jia Lic,**(), Shiying Wangd, Shijian Zhenga,b, Fuxing Yina,b,*()
Received:2020-02-23
Revised:2020-04-12
Accepted:2020-04-29
Published:2021-01-30
Online:2021-02-01
Contact:
Wei Fang,Jia Li,Fuxing Yin
About author:** School of Science, Hebei University of Technology, Tianjin 300132, China. E-mail addresses: jiali@hebut.edu.cn (J. Li).Ruobin Chang, Wei Fang, Jiaohui Yan, Haoyang Yu, Xi Bai, Jia Li, Shiying Wang, Shijian Zheng, Fuxing Yin. Microstructure and mechanical properties of CoCrNi-Mo medium entropy alloys: Experiments and first-principle calculations[J]. J. Mater. Sci. Technol., 2021, 62: 25-33.
Fig. 1. SEM backscatter micrographs of (CoCrNi)100-xMox alloys at different annealing temperatures (700-900 °C): (a1-a4) Mo-0; (b1-b4) Mo-1; (c1-c4) Mo-3; (d1-d4) Mo-5.
Fig. 2. (a) X-ray diffraction patterns of (CoCrNi)100-xMox alloys after annealing at 900 °C and (b) the enlarged area of diffraction peak between 48° and 56°.
Fig. 3. EPMA maps of (a) Mo-3 and (b) Mo-5 alloy after annealing at 900 °C.
Fig. 4. (a) Engineering stress-strain curves of the (CoCrNi)100-xMox alloys after annealing at 900 °C and (b) comparison of mechanical properties of Mo-3 alloy with reported single-phase FCC-HEAs and TRIP-DP-HEAs.
| Alloys | Annealing temperature (°C) | YS (MPa) | UTS (MPa) | EL (%) |
|---|---|---|---|---|
| Mo-0 | 900 | 373 ± 5 | 862 ± 7 | 61 ± 1 |
| Mo-1 | 900 | 412 ± 3 | 914 ± 5 | 63 ± 2 |
| Mo-3 | 900 | 475 ± 5 | 983 ± 6 | 69 ± 2 |
| Mo-5 | 900 | 528 ± 6 | 1026 ± 10 | 47 ± 3 |
Table 1 Yield stress (YS), ultimate tensile strength (UTS), and elongation (EL) of (CoCrNi)100-xMox alloy after annealing at 900 °C.
| Alloys | Annealing temperature (°C) | YS (MPa) | UTS (MPa) | EL (%) |
|---|---|---|---|---|
| Mo-0 | 900 | 373 ± 5 | 862 ± 7 | 61 ± 1 |
| Mo-1 | 900 | 412 ± 3 | 914 ± 5 | 63 ± 2 |
| Mo-3 | 900 | 475 ± 5 | 983 ± 6 | 69 ± 2 |
| Mo-5 | 900 | 528 ± 6 | 1026 ± 10 | 47 ± 3 |
Fig. 5. Typical TEM images of the fractured Mo-0 alloy: (a) bright-field (BF) image of twin bands; (b) dark-field (DF) image and selected area diffraction (SAD) pattern; (c) TEM BF image of dislocations in another grain; (d) representative HRTEM image of twins.
Fig. 6. Typical TEM images of fractured Mo-3 alloy. (a, b) BF images of nano-twin bands and SAD patterns. (c, d) BF images of dislocations and SFs in another grain. (e) HRTEM image of twins and SFs in (b). (f) HRTEM image of SFs in (d).
Fig. 7. Schematics of crystal configurations of (a) Mo-3 and (b) Mo-3 with SF.
Fig. 8. Ab initio calculations for the lattice distortion and stacking fault energy (SFE). (a) Mean square atomic displacement (MSAD) and (b) SFE for various multiple principal element alloys.
Fig. 9. Ab initio calculations of first nearest-neighbor distances of each elemental pairs for Mo-0 and Mo-3 alloys.
| [1] |
B. Cantor, I.T.H. Chang, P. Knight, A.J.B. Vincent, Mater. Sci. Eng A 375-377 (2004) 213-218.
DOI URL |
| [2] |
J.W. Yeh, S.K. Chen, S.J. Lin, J.Y. Gan, T.S. Chin, T.T. Shun, C.H. Tsau, S.Y. Chang, Adv. Eng. Mater. 6 (2004) 299-303.
DOI URL |
| [3] |
D.B. Miracle, Nat. Commun. 10 (2019) 1805.
URL PMID |
| [4] |
Z. Li, S. Zhao, R.O. Ritchie, M.A. Meyers, Prog. Mater. Sci. 102 (2019) 296-345.
DOI URL |
| [5] |
F. Otto, A. Dlouh ý, C. Somsen, H. Bei, G. Eggeler, E.P. George, Acta Mater. 61 (2013) 5743-5755.
DOI URL |
| [6] |
P. Sathiyamoorthi, J. Moon, J.W. Bae, P. Asghari-Rad, H.S. Kim, Scr. Mater. 163 (2019) 152-156.
DOI URL |
| [7] |
Y.L. Zhao, T. Yang, Y. Tong, J. Wang, J.H. Luan, Z.B. Jiao, D. Chen, Y. Yang, A. Hu, C. T. Liu, J.J. Kai, Acta Mater. 138 (2017) 72-82.
DOI URL |
| [8] |
J.Y. He, H. Wang, H.L. Huang, X.D. Xu, M.W. Chen, Y. Wu, X.J. Liu, T.G. Nieh, K. An, Z.P. Lu, Acta Mater. 102 (2016) 187-196.
DOI URL |
| [9] |
T. Yang, Y.L. Zhao, Y. Tong, Z.B. Jiao, J. Wei, J.X. Cai, X.D. Han, D. Chen, A. Hu, J.J. Kai, K. Lu, Y. Liu, C.T. Liu, Science 362 (2018) 933-937.
DOI URL PMID |
| [10] |
S.J. Sun, Y.Z. Tian, H.R. Lin, S. Lu, H.J. Yang, Z.F. Zhang, Scr. Mater. 163 (2019) 111-115.
DOI URL |
| [11] |
J. Gu, S. Ni, Y. Liu, M. Song, Mater. Sci. Eng. A 755 (2019) 289-294.
DOI URL |
| [12] |
Y.Y. Zhao, T.G. Nieh, Intermetallics 86 (2017) 45-50.
DOI URL |
| [13] |
Y. Tong, S. Zhao, K. Jin, H. Bei, J.Y.P. Ko, Y. Zhang, F.X. Zhang, Scr. Mater. 156 (2018) 14-18.
DOI URL |
| [14] |
S. Yoshida, T. Bhattacharjee, Y. Bai, N. Tsuji, Scr. Mater. 134 (2017) 33-36.
DOI URL |
| [15] | S.S. Sohn, A. Kwiatkowski da Silva, Y. Ikeda, F. Kormann, W. Lu, W.S. Choi, B. Gault, D. Ponge, J. Neugebauer, D. Raabe, Adv. Eng. Mater. (2018) e1807142. |
| [16] |
R. Chang, W. Fang, X. Bai, C. Xia, X. Zhang, H. Yu, B. Liu, F. Yin, J. Alloys Compd. 790 (2019) 732-743.
DOI URL |
| [17] |
M.P. Agustianingrum, S. Yoshida, N. Tsuji, N. Park, J. Alloys Compd. 781 (2019) 866-872.
DOI URL |
| [18] |
Z. Li, K.G. Pradeep, Y. Deng, D. Raabe, C.C. Tasan, Nature 534 (2016) 227-230.
DOI URL PMID |
| [19] |
Z. Li, F. Körmann, B. Grabowski, J. Neugebauer, D. Raabe, Acta Mater. 136 (2017) 262-270.
DOI URL |
| [20] |
C.E. Slone, S. Chakraborty, J. Miao, E.P. George, M.J. Mills, S.R. Niezgoda, Acta Mater. 158 (2018) 38-52.
DOI URL |
| [21] |
G. Laplanche, A. Kostka, O.M. Horst, G. Eggeler, E.P. George, Acta Mater. 118 (2016) 152-163.
DOI URL |
| [22] |
G. Laplanche, A. Kostka, C. Reinhart, J. Hunfeld, G. Eggeler, E.P. George, Acta Mater. 128 (2017) 292-303.
DOI URL |
| [23] |
S.F. Liu, Y. Wu, H.T. Wang, J.Y. He, J.B. Liu, C.X. Chen, X.J. Liu, H. Wang, Z.P. Lu, Intermetallics 93 (2018) 269-273.
DOI URL |
| [24] |
S.F. Liu, Y. Wu, H.T. Wang, W.T. Lin, Y.Y. Shang, J.B. Liu, K. An, X.J. Liu, H. Wang, Z.P. Lu, J. Alloys Compd. 792 (2019) 444-455.
DOI URL |
| [25] | D. Wei, X. Li, W. Heng, Y. Koizumi, F. He, W.M. Choi, B.J. Lee, H.S. Kim, H. Kato, A. Chiba, Mater. Lett. 7 (2018) 82-88. |
| [26] |
D. Wei, X. Li, J. Jiang, W. Heng, Y. Koizumi, W.M. Choi, B.J. Lee, H.S. Kim, H. Kato, A. Chiba, Scr. Mater. 165 (2019) 39-43.
DOI URL |
| [27] |
W. Fang, R. Chang, X. Zhang, P. Ji, X. Wang, B. Liu, J. Li, X. He, X. Qu, F. Yin, Mater. Sci. Eng. A 723 (2018) 221-228.
DOI URL |
| [28] |
D. Miracle, O. Senkov, Acta Mater. 122 (2017) 448-511.
DOI URL |
| [29] |
B. Cai, B. Liu, S. Kabra, Y. Wang, K. Yan, P. Lee, Y. Liu, Acta Mater. 127 (2017) 471-480.
DOI URL |
| [30] |
Y. Wang, B. Liu, K. Yan, M. Wang, S. Kabra, Y.L. Chiu, D. Dye, P.D. Lee, Y. Liu, B. Cai, Acta Mater. 154 (2018) 79-89.
DOI URL |
| [31] |
N.L. Okamoto, K. Yuge, K. Tanaka, H. Inui, E.P. George, AIP Adv. 6 (2016) 125008.
DOI URL |
| [32] |
Z. Pei, Mater. Sci. Eng. A 737 (2018) 132-150.
DOI URL |
| [33] |
Y.H. Zhang, Y. Zhuang, A. Hu, J.J. Kai, C.T. Liu, Scr. Mater. 130 (2017) 96-99.
DOI URL |
| [34] |
J. Ding, Q. Yu, M. Asta, R.O. Ritchie, Proc. Natl. Acad. Sci. U. S. A. 115 (2018) 8919-8924.
DOI URL PMID |
| [35] |
G. Kresse, J. Hafner, Phys. Rev. B 47 (1993) 558-561.
DOI URL |
| [36] |
G. Kresse, J. Hafner, Phys. Rev. B 54 (1996) 11169-11186.
DOI URL |
| [37] | G. Kresse, D. Joubert, Phys. B 59 (1999) 1758-1775. |
| [38] |
J.P. Perdew, K. Burke, M. Ernzerhof, Phys. Lett. 77 (1996) 3865-3868.
DOI URL |
| [39] |
G. Qin, R. Chen, H. Zheng, H. Fang, L. Wang, Y. Su, J. Guo, H. Fu, J. Mater. Sci. Technol. 35 (2019) 578-583.
DOI URL |
| [40] |
Q.F. Wu, Z.J. Wang, F. He, J.J. Li, J.C. Wang, J. Phase Equilib. Diffus. 39 (2018) 446-453.
DOI URL |
| [41] |
B. Gludovatz, A. Hohenwarter, D. Catoor, E.H. Chang, E.P. George, R.O. Ritchie, Science 345 (2014) 1153-1158.
DOI URL PMID |
| [42] |
B. Gludovatz, A. Hohenwarter, K.V. Thurston, H. Bei, Z. Wu, E.P. George, R.O. Ritchie, Nat. Commun. 7 (2016) 10602.
DOI URL PMID |
| [43] |
Z. Wu, H. Bei, G.M. Pharr, E.P. George, Acta Mater. 81 (2014) 428-441.
DOI URL |
| [44] |
C.E. Slone, J. Miao, E.P. George, M.J. Mills, Acta Mater. 165 (2019) 496-507.
DOI URL |
| [45] |
Z. Li, C.C. Tasan, K.G. Pradeep, D. Raabe, Acta Mater. 131 (2017) 323-335.
DOI URL |
| [46] |
E.J. Pickering, N.G. Jones, Int. Mater. Rev. 61 (2016) 183-202.
DOI URL |
| [47] |
Y. Tong, K. Jin, H. Bei, J.Y.P. Ko, D.C. Pagan, Y. Zhang, F.X. Zhang, Mater. Des. 155 (2018) 1-7.
DOI URL |
| [48] |
R. Chang, W. Fang, X. Bai, C. Xia, X. Zhang, H. Yu, B. Liu, F. Yin, J. Alloys Compd. 790 (2019) 732-743.
DOI URL |
| [49] |
Y.Z. Tian, Y. Bai, L.J. Zhao, S. Gao, H.K. Yang, A. Shibata, Z.F. Zhang, N. Tsuji, Mater. Charact. 126 (2017) 74-80.
DOI URL |
| [50] |
H. Idrissi, K. Renard, L. Ryelandt, D. Schryvers, P.J. Jacques, Acta Mater. 58 (2010) 2464-2476.
DOI URL |
| [51] |
Q.J. Li, H. Sheng, E. Ma, Nat. Commun. 10 (2019) 3563.
URL PMID |
| [52] |
F. Zhang, Y. Wu, H. Lou, Z. Zeng, V.B. Prakapenka, E. Greenberg, Y. Ren, J. Yan, J.S. Okasinski, X. Liu, Y. Liu, Q. Zeng, Z. Lu, Nat. Commun. 8 (2017) 15687.
DOI URL PMID |
| [53] |
S. Zhao, G.M. Stocks, Y. Zhang, Acta Mater. 134 (2017) 334-345.
DOI URL |
| [54] |
S. Huang, H. Huang, W. Li, D. Kim, S. Lu, X. Li, E. Holmstrom, S.K. Kwon, L. Vitos, Nat. Commun. 9 (2018) 2381.
DOI URL PMID |
| [55] | B. Gwalani, R. Salloom, T. Alam, S.G. Valentin, X. Zhou, G. Thompson, S.G. Srinivasan, R. Banerjee, Mater. Lett. 7 (2019) 267-274. |
| [56] | Z. Lei, X. Liu, Y. Wu, H. Wang, S. Jiang, S. Wang, X. Hui, Y. Wu, B. Gault, P. Kontis, D. Raabe, L. Gu, Q. Zhang, H. Chen, H. Wang, J. Liu, K. An, Q. Zeng, T.G. Nieh, Z. Lu, Nature 563 (2018) 546. |
| [57] |
F.X. Zhang, S. Zhao, K. Jin, H. Xue, G. Velisa, H. Bei, R. Huang, J.Y.P. Ko, D.C. Pagan, J.C. Neuefeind, W.J. Weber, Y. Zhang, Phys. Rev. Lett. 118 (2017) 205501.
DOI URL PMID |
| [58] |
L. Li, Z. Li, A. Kwiatkowski da Silva, Z. Peng, H. Zhao, B. Gault, D. Raabe, Acta Mater. 178 (2019) 1-9.
DOI URL |
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