Synthesis, Al3+/Mg2+ Intercalation and Structure Study of Graphite-like Carbon Nitride

Abstract

Abstract: Graphite-like carbon nitride (g-C₃N₄) was synthesized in large quantities at 300ºC under nitrogen by a solidstate reaction route. Furthermore, Al³⁺ and Mg²⁺ intercalation of g-C₃N₄ was performed by an electrochemical method. The starting C₃N₄ materials and intercalation compounds were characterized by X-ray powder diffraction, Fourier transform infrared spectra, thermogravimetry, transmission electron microscopy, and X-ray photoelectron spectroscopy. The possible structure model of intercalation compounds was proposed. The cation-¼ interactions and electrostatic interactions were used to explain the changes of microstructure and chemical bonds before and after intercalation.

Key words: Carbon nitride materials, Solid state reactions, Intercalation, Microstructure

Xifeng Lu, Hongjun Wang, Yi Yang, Tao Liu. Synthesis, Al³⁺/Mg²⁺ Intercalation and Structure Study of Graphite-like Carbon Nitride[J]. J Mater Sci Technol, 2011, 27(3): 245-251.

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Synthesis, Al³⁺/Mg²⁺ Intercalation and Structure Study of Graphite-like Carbon Nitride

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