J. Mater. Sci. Technol. ›› 2023, Vol. 138: 93-107.DOI: 10.1016/j.jmst.2022.08.014

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Magnetic field intensity dependent microstructure evolution and recrystallization behavior in a Co-B eutectic alloy

Fan Bua,b, Yiyuan Zhanga,b, Haoxiang Liua,b, Jun Wanga,b, Eric Beaugnone, Jinshan Lia, Yixuan Hea,b,c,d,*   

  1. aState Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an 710072, China;
    bCenter of Advanced Lubrication and Seal Materials, Northwestern Polytechnical University, Xi’an 710072, China;
    cCollaborative Innovation Center of NPU, Shanghai 201108, China;
    dInstitute of Superconducting Materials and Applied Technology, Northwestern Polytechnical University, Xi’an 710072, China;
    eUniv. Grenoble Alpes, INSA Toulouse, University Toulouse Paul Sabatier, EMFL, CNRS, LNCMI, Grenoble 38000, France
  • Received:2022-07-11 Revised:2022-08-04 Accepted:2022-08-07 Published:2023-03-01 Online:2023-03-03
  • Contact: * State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an 710072, China. E-mail address:. yixuanhenwpu@126.com (Y. He)

Abstract: Systematic understanding on the magnetic field intensity dependent microstructure evolution and recrystallization behavior in a Co-B eutectic alloy under a constant undercooling (∆T≈100 K) were carried out. Absent of the magnetic field, the comparable size of divorced FCC-Co and Co3B eutectic ellipsoidal grains coexist with a few regular lamellas. When the magnetic field is less than 15 T, the elongated primary FCC-Co dendrites parallel to the magnetic field with the dispersed FCC-Co nano-particles embedded within the Co3B matrix occupy the inter-dendrite regions. Once the magnetic field increases to 20 T, the FCC-Co/Co2B anomalous eutectic colonies dominate. The formation mechanism of Co2B phase is discussed from several aspects of the competitive nucleation, the chemical redistribution induced by the thermomagnetic-induced convection and magnetic dipole interaction, and the strain-induced transformation. Furthermore, the application of magnetic field is found to promote recrystallization, proved by the lower density of misorientation, the appearance of FCC-Co annealed twins and more Co3B sub-grains. This work could further enrich our knowledge about the magnetic-dependent microstructure evolution and recrystallization process in the undercooled Co-B system and provide guidance for controlling the microstructures and properties under extreme conditions.

Key words: Magnetic field, Undercooled solidification, Microstructure evolution, Recrystallization, Co-B alloy