J. Mater. Sci. Technol. ›› 2020, Vol. 53: 32-36.DOI: 10.1016/j.jmst.2020.01.070
• Letter • Previous Articles Next Articles
Peng Jiaa,b,*(
), Ruiwen Huanga,b, Suode Zhangc, Engang Wanga,b, Jiahao Yaoc,**()
Received:2019-12-11
Published:2020-09-15
Online:2020-09-21
Contact:
Peng Jia,Jiahao Yao
Peng Jia, Ruiwen Huang, Suode Zhang, Engang Wang, Jiahao Yao. Synthesis of Ag-Cr thin film metallic glasses with enhanced sulfide-resistance[J]. J. Mater. Sci. Technol., 2020, 53: 32-36.
Fig. 1. (a) Appearance of the Ag-Cr combinatorial sputtered film library deposited on a Si wafer with 50 mm diameter as well as the configuration of the targets, the compositions of the patches at the center line are marked and measured by EDS analysis. (b) XRD patterns of the Ag-Cr compositional library as marked in (a).
Fig. 2. (a) XRD patterns of the compositional uniform Ag-Cr as-deposited thin films with different composition, inset the XRD spectrum of as-deposited nanocrystalline pure Ag film; (b) High-resolution TEM image and the inset selected-area electron diffraction (SAED) pattern for the Ag50Cr50 TFMG sample of ~1 μm thickness.
Fig. 3. Polarization curves for the Ag-Cr alloy films with various Cr content, as well as the nanocrystalline pure Ag film and corresponding bulk silver sample in (a) 0.01 M K2S solution and (b) 0.1 M NaCl solution.
| Composition | Ecorr (VSCE) | icorr (A/cm2) |
|---|---|---|
| Ag90Cr10 | -0.67 ± 0.06 | (6.57 ± 0.63) × 10-6 |
| Ag80Cr20 | -0.47 ± 0.04 | (1.88 ± 0.23) × 10-6 |
| Ag70Cr30 | -0.33 ± 0.03 | (1.67 ± 0.19) × 10-7 |
| Ag60Cr40 | -0.39 ± 0.04 | (3.67 ± 0.35) × 10-7 |
| Ag50Cr50 | -0.16 ± 0.02 | (9.64 ± 0.83) × 10-8 |
| Pure Ag film | -0.70 ± 0.06 | (2.10 ± 0.22) × 10-5 |
| Bulk silver | -0.62 ± 0.05 | (2.49 ± 0.30) × 10-5 |
Table 1 Characteristic electrochemical parameters of Ag-Cr alloy films, pure Ag film and bulk silver sample in 0.01 M K2S solution.
| Composition | Ecorr (VSCE) | icorr (A/cm2) |
|---|---|---|
| Ag90Cr10 | -0.67 ± 0.06 | (6.57 ± 0.63) × 10-6 |
| Ag80Cr20 | -0.47 ± 0.04 | (1.88 ± 0.23) × 10-6 |
| Ag70Cr30 | -0.33 ± 0.03 | (1.67 ± 0.19) × 10-7 |
| Ag60Cr40 | -0.39 ± 0.04 | (3.67 ± 0.35) × 10-7 |
| Ag50Cr50 | -0.16 ± 0.02 | (9.64 ± 0.83) × 10-8 |
| Pure Ag film | -0.70 ± 0.06 | (2.10 ± 0.22) × 10-5 |
| Bulk silver | -0.62 ± 0.05 | (2.49 ± 0.30) × 10-5 |
| Composition | Ecorr (VSCE) | Epit (VSCE) | icorr (A/cm2) | ipass (A/cm2) |
|---|---|---|---|---|
| Ag90Cr10 | -0.14 ± 0.03 | 0.07 ± 0.02 | (4.32 ± 0.25) × 10-7 | (2.69 ± 0.18) × 10-6 |
| Ag80Cr20 | -0.26 ± 0.05 | — | (4.91 ± 0.28) × 10-7 | — |
| Ag70Cr30 | -0.30 ± 0.06 | — | (5.07 ± 0.32) × 10-7 | — |
| Ag60Cr40 | -0.13 ± 0.03 | 0.07 ± 0.02 | (3.67 ± 0.25) × 10-7 | (1.17 ± 0.16) × 10-6 |
| Ag50Cr50 | -0.14 ± 0.03 | 0.07 ± 0.02 | (4.68 ± 0.34) × 10-7 | (3.28 ± 0.33) × 10-6 |
| Pure Ag film | -0.07 ± 0.01 | 0.07 ± 0.02 | (3.15 ± 0.43) × 10-7 | (1.19 ± 0.17) × 10-6 |
| Bulk silver | -0.11 ± 0.01 | 0.08 ± 0.01 | (1.26 ± 0.23) × 10-6 | (8.16 ± 0.43) × 10-6 |
Table 2 Characteristic electrochemical parameters of Ag-Cr alloy films, pure Ag film and bulk silver sample in 0.1 M NaCl solution.
| Composition | Ecorr (VSCE) | Epit (VSCE) | icorr (A/cm2) | ipass (A/cm2) |
|---|---|---|---|---|
| Ag90Cr10 | -0.14 ± 0.03 | 0.07 ± 0.02 | (4.32 ± 0.25) × 10-7 | (2.69 ± 0.18) × 10-6 |
| Ag80Cr20 | -0.26 ± 0.05 | — | (4.91 ± 0.28) × 10-7 | — |
| Ag70Cr30 | -0.30 ± 0.06 | — | (5.07 ± 0.32) × 10-7 | — |
| Ag60Cr40 | -0.13 ± 0.03 | 0.07 ± 0.02 | (3.67 ± 0.25) × 10-7 | (1.17 ± 0.16) × 10-6 |
| Ag50Cr50 | -0.14 ± 0.03 | 0.07 ± 0.02 | (4.68 ± 0.34) × 10-7 | (3.28 ± 0.33) × 10-6 |
| Pure Ag film | -0.07 ± 0.01 | 0.07 ± 0.02 | (3.15 ± 0.43) × 10-7 | (1.19 ± 0.17) × 10-6 |
| Bulk silver | -0.11 ± 0.01 | 0.08 ± 0.01 | (1.26 ± 0.23) × 10-6 | (8.16 ± 0.43) × 10-6 |
Fig. 4. Electrochemical impedance spectroscopy (EIS) complex plane impedance plots for the Ag-Cr alloy films with various Cr content, as well as the nanocrystalline pure Ag film and corresponding bulk silver sample in (a) 0.01 M K2S solution and (b) 0.1 M NaCl solution.
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