Construction of SnS2/SnO2 heterostructures with enhanced potassium storage performance

doi:10.1016/j.jmst.2019.05.074

Abstract

Abstract:

Increasing attention has been focused on potassium ion batteries (KIBs) as promising energy-storage system (ESS) owing to the abundance and low-cost of potassium resources. Here, SnS₂/SnO₂ heterostructures were successfully fixed onto stainless steel mesh (SnS₂/SnO₂/SSM) through a facile two-step hydrothermal method and used as anodes for KIBs. Due to the advantages of SnS₂/SnO₂ heterostructures and good conductivity of SSM substrate, the SnS₂/SnO₂/SSM anodes display enhanced electrochemical performance. The SnS₂/SnO₂/SSM anodes deliver specific capacity of 394 mA h g^-1 at 50 mA g^-1 over 100 cycles, better than SnO₂/SSM. Even at 500 mA g^-1 after 250 cycles, high capacity of 155 mA h g^-1 can still be obtained.

Key words: SnS₂/SnO₂, Heterostructures, Potassium-ion batteries, Anode

Guoquan Suo, Dan Li, Lei Feng, Xiaojiang Hou, Xiaohui Ye, Li Zhang, Qiyao Yu, Yanling Yang, Wei (Alex) Wang. Construction of SnS₂/SnO₂ heterostructures with enhanced potassium storage performance[J]. J. Mater. Sci. Technol., 2020, 55: 167-172.

Figures/Tables 5

Fig. 1. Schematic illustration for the formation of SnS2/SnO2/SSM through two steps. (I) The growth of SnO2 nanoshees onto the surface of SSM; (II) The formation of SnS2/SnO2/SSM though partially vulcanization of SnO2/SSM.

Fig. 2. SEM images of (a, c) SnO2/SSM and (b, d) SnS2/SnO2/SSM.

Fig. 3. (a) TEM image and (b) the corresponding EDS elemental mappings of S, Sn, O of SnS2/SnO2 heterostructures. (c) HRTEM image and (d) the corresponding interlayer spacings.

Fig. 4. (a) XRD patterns of SnS2/SnO2/SSM and SnO2/SSM products. High resolution XPS spectra for SnS2/SnO2/SSM: (b) Sn 3d, (c) O 1s and (d) S 2s.

Fig. 5. (a) CV curves for the SnS2/SnO2/SSM electrode in the initial three cycles at a scan rate of 0.1 mV s-1. (b) Discharge-charge voltage profile at the 50 mA g-1 for 1 st, 2nd, 5th, 20th and 50th cycle. (c) Cycling performances of the SnS2/SnO2/SSM and SnO2/SSM electrodes at 50 mA g-1. (d) Rate capabilities of SnS2/SnO2/SSM and SnO2/SSM electrodes under various current densities from 50 to 1000 mA g-1. (e) The cycling performance and Coulombic efficiency of the SnS2/SnO2/SSM electrode for 250 cycles at 500 mA g-1.

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Construction of SnS₂/SnO₂ heterostructures with enhanced potassium storage performance

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