Fe-Based Metal-Organic Framework and Its Derivatives for Reversible Lithium Storage

doi:10.1016/j.jmst.2016.11.021

Abstract

Abstract:

The use of a Fe-based metal organic framework (MOF), namely MIL-88B(Fe), as active material for lithium ion batteries (LIBs) is reported for the first time in the present work. Fe-based MOF demonstrated high capacity, excellent cycling stability and rate performance when used as anode. A highly reversible capacity of ~680 mA h g^-1 after 500 cycles at a current density of 200 mA g^-1 was obtained. In addition, Fe₂O₃ and Fe₃O₄/C composites were obtained from Fe-based MOFs through thermal treatment. Both Fe₂O₃ and Fe₃O₄/C composites demonstrated high capacity and excellent cycling stability.

Key words: Lithium ion battery, Anode, Metal organic framework, Metal oxide

Jin Yan, Zhao Chongchong, Lin Yichao, Wang Deyu, Chen Liang, Shen Cai. Fe-Based Metal-Organic Framework and Its Derivatives for Reversible Lithium Storage[J]. J. Mater. Sci. Technol., 2017, 33(8): 768-774.

Figures/Tables 10

Scheme 1 Schematic illustration of the preparation process of MIL-88B(Fe), Fe2O3 and Fe3O4/C composites.

Fig.1. (a) XRD patterns; (b) SEM images; (c) TG profile; and (d) N2 adsorption-desorption isotherm of MIL-88B(Fe).

Fig.2. Electrochemical performance of MIL-88B(Fe): (a) cyclic voltammograms at a scanning rate of 0.05 mVs-1; (b) galvanostatic discharge-charge profiles; (c) cycling performance at a current density of 200 mA g-1; (d) rate performance at various current densities from 0.2-2.0 Ag-1.

Fig.3. EIS spectra of the MIL-88B(Fe) electrodes after 1, 100 and 200 discharge-charge cycles at a current density of 200 mA g-1.

Fig.4. SEM images of (a) the original MIL-88B(Fe) electrode and (b) MIL-88B(Fe) electrode after 200 cycles at a current density of 200 mA g-1.

Fig.5. (a) XRD patterns (The JCPDS number is No. 33-0664) and (b) SEM images of Fe2O3 nanoparticles.

Fig.6. Electrochemical performance of the Fe2O3 electrode: (a) cycling performance at a current density of 0.5 C; (b) rate performance at various current densities from 0.2 C to 5 C (1 C = 1007 mA g-1)

Fig.7. (a) XRD patterns (The JCPDS number is No. 19-0629) and (b) Raman spectroscopy of Fe3O4/C composite.

Fig.8. SEM images of Fe3O4/C composite (a, b); elemental mapping of the Fe3O4/C composite(c-e); TEM image (f); HRTEM and SAED pattern of Fe3O4/C composite (g).

Fig.9. Electrochemical performance of Fe3O4/C composite: (a) galvanostatic discharge-charge profiles; (b) cyclic voltammograms of Fe3O4/C composite at scanning rate of 0.05 mVs-1; (c) cycling performance at a current density of 0.5 C; (d) rate performance at different current densities from 0.2 C-5 C.

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