J. Mater. Sci. Technol. ›› 2014, Vol. 30 ›› Issue (8): 765-769.DOI: 10.1016/j.jmst.2014.03.010

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Photoelectrochemical Performance of Nb-doped TiO2 Nanoparticles Fabricated by Hydrothermal Treatment of Titanate Nanotubes in Niobium Oxalate Aqueous Solution

Lizhen Long1, 2, Liangpeng Wu1, Xu Yang1, Xinjun Li1, *   

  1. 1 Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion,Chinese Academy of Sciences, Guangzhou 510640, China; 2 University of Chinese Academy of Sciences, Beijing 100049, China
  • Received:2013-05-21 Online:2014-05-20 Published:2014-09-30
  • Contact: * Corresponding author. Prof.; Tel.: t86 20 87057781; Fax: t86 2087057677; E-mail address: lixj@ms.giec.ac.cn (X. Li).

Abstract: Nb-doped TiO2 nanoparticles were prepared by hydrothermal treatment of titanate nanotubes in niobium oxalate aqueous solution. The effect of Nb doping and rutile content on the photoelectrochemical performance based on TiO2 powder electrodes was investigated. The results show that Nb-doped TiO2 with a small amount of rutile exhibits the enhanced photoelectric conversion efficiency for dye-sensitized solar cell. The highest photoelectric conversion efficiency of 8.53% is obtained for 1% Nb-TiO2 containing a small amount of rutile. When a small amount of rutile contained in 2% Nb-TiO2, a higher photoelectric conversion efficiency of 8.77% is achieved.

Key words: Titanate nanotube, Hydrothermal, Nb-doped, TiO, Dye-sensitized solar cell