J. Mater. Sci. Technol. ›› 2020, Vol. 49: 144-156.DOI: 10.1016/j.jmst.2020.02.025
• Research Article • Previous Articles Next Articles
Zhiliang Jina,b,c,*(), Lijun Zhanga,b,c,*()
Received:
2019-11-16
Revised:
2019-12-13
Accepted:
2019-12-17
Published:
2020-07-15
Online:
2020-07-17
Contact:
Zhiliang Jin,Lijun Zhang
Zhiliang Jin, Lijun Zhang. Performance of Ni-Cu bimetallic co-catalyst g-C3N4 nanosheets for improving hydrogen evolution[J]. J. Mater. Sci. Technol., 2020, 49: 144-156.
Fig. 3. XPS analysis of CNNC-15 composite: (a) XPS survey spectrum of CNNC-15 and pure g-C3N4; High-resolution XPS spectrum of C 1s (b), N 1s (c), O 1s (d), Ni 2p (e) and Cu 2p (f) that belongs to CNNC-15 and pure g-C3N4, respectively.
Samples | SBET (m2/g) | Pore volume (cm3/g) | Average pore size (nm) |
---|---|---|---|
g-C3N4 | 5 | 0.025 | 21 |
CNC | 40 | 0.002 | 18 |
CNN-15 | 42 | 0.219 | 19 |
CNNC-15 | 51 | 0.233 | 19 |
Table 1 SBET, pore volume and average pore size comparisons results for different catalysts.
Samples | SBET (m2/g) | Pore volume (cm3/g) | Average pore size (nm) |
---|---|---|---|
g-C3N4 | 5 | 0.025 | 21 |
CNC | 40 | 0.002 | 18 |
CNN-15 | 42 | 0.219 | 19 |
CNNC-15 | 51 | 0.233 | 19 |
Fig. 6. N2 adsorption-desorption isotherms and corresponding pore-size distribution curves (inset) of the CN (a), CNC (b), CNN-15 (c) and CNNC-15 (d) samples.
Fig. 8. Comparison of different catalyst H2 production activity of CN, CNC, CNN-15, and CNNC-15 (a). Comparison of hydrogen production performance of composite with different nickel content (b) and copper content (c). Effect of different pH triethanolamine aqueous to the photocatalytic property of CNNC-15 (d). Stability testing of CNNC-15 composite in this system (e). Apparent quantum efficiency (QE) of the CNNC-15 (f).
Photocatalyst | Co-catalyst | Light source | Sacrificial reagent | Activity (μmol/ (h g)) | Ref. |
---|---|---|---|---|---|
g-C3N4 | Ni-Cu | 5 W LED (≥ 420 nm) | 15 vol.% TEOA | 2088.28 | This work |
g-C3N4 | S-Ni | 300 W Xe-lamp (> 420 nm) | 20 vol.% TEOA | 2021.3 | [ |
g-C3N4 | Pt-Pd | 300 W Xe-lamp (≥ 400 nm) | 10 vol.% TEOA | 1600.8 | [ |
g-C3N4 | NiS | 350 W Xe-lamp, (≥ 420 nm) | 15 vol.% TEOA | 593.6 | [ |
g-C3N4 | Pt-C | 350 W Xe-lamp, (≥ 420 nm) | 15 vol.% TEOA | 212.8 | [ |
g-C3N4 | C | Xe-lamp, (> 420 nm) | 15 vol.% TEOA | 410.1 | [ |
g-C3N4 | MoP | 300 W Xe-lamp (> 400 nm) | 10 vol.% TEOA | 327.5 | [ |
Table 2 Comparison of photocatalytic activity.
Photocatalyst | Co-catalyst | Light source | Sacrificial reagent | Activity (μmol/ (h g)) | Ref. |
---|---|---|---|---|---|
g-C3N4 | Ni-Cu | 5 W LED (≥ 420 nm) | 15 vol.% TEOA | 2088.28 | This work |
g-C3N4 | S-Ni | 300 W Xe-lamp (> 420 nm) | 20 vol.% TEOA | 2021.3 | [ |
g-C3N4 | Pt-Pd | 300 W Xe-lamp (≥ 400 nm) | 10 vol.% TEOA | 1600.8 | [ |
g-C3N4 | NiS | 350 W Xe-lamp, (≥ 420 nm) | 15 vol.% TEOA | 593.6 | [ |
g-C3N4 | Pt-C | 350 W Xe-lamp, (≥ 420 nm) | 15 vol.% TEOA | 212.8 | [ |
g-C3N4 | C | Xe-lamp, (> 420 nm) | 15 vol.% TEOA | 410.1 | [ |
g-C3N4 | MoP | 300 W Xe-lamp (> 400 nm) | 10 vol.% TEOA | 327.5 | [ |
Samples | Pre-exponential factors, A | Lifetime, <τ> (ns) | Average lifetime, <τ> (ns) | ket (s-1) | χ2 |
---|---|---|---|---|---|
EY | A = 100 | τ=0.1979 | 0.1979 | --- | 1.07 |
EY-CN | A1 = 36.61 A2 = 33.00 A3 = 30.39 | τ1=8.357 τ2 = 1.660 τ3=96.99 | 4.0702 | 5.920 × 108 | 1.02 |
EY-CNC | A1 = 35.79 A2 = 31.39 A3 = 32.39 | τ1=8.274 τ2 = 99.52 τ3 = 1.498 | 3.7674 | 6.575 × 108 | 1.09 |
EY-CNN-15 | A1 = 36.20 A2 = 26.43 A3 = 37.37 | τ1=8.469 τ2 = 91.23 τ3 = 1.664 | 3.7009 | 5.900 × 108 | 1.08 |
EY-CNNC-15 | A1 = 41.98 A2 = 26.68 A3 = 31.35 | τ1=5.519 τ2 = 1.061 τ3=48.44 | 2.9948 | 9.218 × 108 | 1.09 |
Table 3 Attenuation parameters o photocatalyst.
Samples | Pre-exponential factors, A | Lifetime, <τ> (ns) | Average lifetime, <τ> (ns) | ket (s-1) | χ2 |
---|---|---|---|---|---|
EY | A = 100 | τ=0.1979 | 0.1979 | --- | 1.07 |
EY-CN | A1 = 36.61 A2 = 33.00 A3 = 30.39 | τ1=8.357 τ2 = 1.660 τ3=96.99 | 4.0702 | 5.920 × 108 | 1.02 |
EY-CNC | A1 = 35.79 A2 = 31.39 A3 = 32.39 | τ1=8.274 τ2 = 99.52 τ3 = 1.498 | 3.7674 | 6.575 × 108 | 1.09 |
EY-CNN-15 | A1 = 36.20 A2 = 26.43 A3 = 37.37 | τ1=8.469 τ2 = 91.23 τ3 = 1.664 | 3.7009 | 5.900 × 108 | 1.08 |
EY-CNNC-15 | A1 = 41.98 A2 = 26.68 A3 = 31.35 | τ1=5.519 τ2 = 1.061 τ3=48.44 | 2.9948 | 9.218 × 108 | 1.09 |
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