Suppressing the anomalous rapid oxidation of Ti3AlC2 by incorporating TiB2

doi:10.1016/j.jmst.2018.08.002

Abstract

Abstract:

The oxidation behavior of Ti₃AlC₂-20TiB₂ composite was studied at 500?°C-900?°C in air. The composite showed a very low oxidation rate and followed a logarithmic oxidation law. The in-situ incorporation of TiB₂ suppressed the anomalous rapid oxidation of the substrate Ti₃AlC₂ occurred near 600?°C by forming a protective B₂O₃ glass layer, and also improved the oxidation resistance of the MAX phase at intermediate-temperature.

Key words: MAX phase, Ti₃AlC₂-TiB₂ composite, Oxidation

Chao Li, Yuhai Qian, Chunlei Ma, Shumin Wang, Meishuan Li. Suppressing the anomalous rapid oxidation of Ti₃AlC₂ by incorporating TiB₂[J]. J. Mater. Sci. Technol., 2019, 35(3): 432-439.

Figures/Tables 8

Fig. 1. Oxidation kinetics of Ti3AlC2-20TiB2 composite at 500?°C-900?°C in air.

Fig. 2. Natural logarithm relationships of mass gains with time for Ti3AlC2-20TiB2 composite at 500?°C-900?°C in air for 20?h.

Fig. 3. Oxidation kinetics of Ti3AlC2 at 500?°C-900?°C in air.

Fig. 4. (a) XRD patterns of Ti3AlC2-20TiB2 composite oxidized at 500-900?°C in air for 20?h, (b) XRD analysis for the main characteristic peak positions of Ti3AlC2-20TiB2 composites before&after oxidation and pure Ti3AlC2.

Fig. 5. XPS analyses of the surface of Ti3AlC2-20TiB2 oxidized at 500?°C (A-D) and 900?°C (a-d) in air for 20?h (scatter circle plots: raw data, solid lines: Gaussian-Lorentzian fitted data, dotted lines: background fitted data).

Fig. 6. Surface morphologies of Ti3AlC2-20TiB2 composite oxidized for 20?h in air at 600?°C, (b) 700?°C, (c) 800?°C and (d) 900?°C.

Fig. 7. Backscattered electron images of cross sections of Ti3AlC2-20TiB2 oxidized at (a) 700?°C, (b) 800?°C and (c) 900?°C, and (a′) elemental line profiles along the white line in (a).

Fig. 8. Surface morphology (a) and cross section (b) of monolithic Ti3AlC2 oxidized at 600?°C in air for 20?h.

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Suppressing the anomalous rapid oxidation of Ti₃AlC₂ by incorporating TiB₂

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