Reactive MnO2 template-assisted synthesis of double-shelled PPy hollow nanotubes to boost microwave absorption

doi:10.1016/j.jmst.2022.11.010

Abstract

Abstract: Microwave absorbing materials (MAMs) with wide effective absorption bandwidth (EAB) and low filling ratio are highly desirable for practical applications. Rational design in components and structures is one of the effective strategies to achieve MAMs with high performance. Herein, double-shelled hollow (DSH) polypyrrole (PPy) nanotubes were synthesized with hydrochloric acid (HCl) and sodium p-styrene sulfonate (SS) co-doping polymerization process using manganese dioxide (MnO₂) nanorods as a self-sacrifice template. With the increase of HCl concentration, the 1D MnO₂ core diminishes gradually to form the MnO₂@PPy coaxial nanostructures and finally the DSH PPy nanotube, which tunes the microwave absorption performance. Importantly, the DSH PPy nanotubes exhibit excellent microwave absorption of an optimal reflection loss of -50.4 dB and a wide EAB of 7.7 GHz with a low filling ratio of 5 wt% in a paraffin wax matrix. The excellent microwave absorption is believed to be mainly attributed to the enhanced synergistic effects of interfacial polarization and conduction loss arising from the unique DSH structure and the co-doping polymerization.

Key words: PPy nanotube, MnO₂ template, Double-shelled hollow structure, Microwave absorption

Huiling Gu, Ji Huang, Na Li, Hua Yang, Gang Chen, Chengjun Dong, Chunhong Gong, Hongtao Guan. Reactive MnO₂ template-assisted synthesis of double-shelled PPy hollow nanotubes to boost microwave absorption[J]. J. Mater. Sci. Technol., 2023, 146: 145-153.

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Reactive MnO₂ template-assisted synthesis of double-shelled PPy hollow nanotubes to boost microwave absorption

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