Microstructure optimization of core@shell structured MSe2/FeSe2@MoSe2 (M = Co, Ni) flower-like multicomponent nanocomposites towards high-efficiency microwave absorption

doi:10.1016/j.jmst.2022.04.017

Abstract

Abstract:

In this work, we put forward a scheme to exquisitely design and selectively synthesize the core@shell structured MSe₂/FeSe₂@MoSe₂ (M = Co, Ni) flower-like multicomponent nanocomposites (MCNCs) through a simple two-step hydrothermal reaction on the surfaces of MFe₂O₄ nanospheres with the certain amounts of Mo and Se sources. With increasing the amounts of Mo and Se sources, the obtained core@shell structured MSe₂/FeSe₂@MoSe₂ (M = Co, Ni) MCNCs with the enhanced content of MoSe₂ and improved flower-like geometry morphology could be produced on a large scale. The obtained results revealed that the as-prepared samples displayed improved comprehensive microwave absorption properties (CMAPs) with the increased amounts of Mo and Se sources. The as-prepared CoSe₂/FeSe₂@MoSe₂ and NiSe₂/FeSe₂@MoSe₂ MCNCs with the well-defined flower-like morphology could simultaneously present the outstanding CMAPs in terms of strong absorption capability, wide absorption bandwidth, and thin matching thicknesses, which mainly originated from the conduction loss and flower-like geometry morphology. Therefore, the findings not only develop the very desirable candidates for high-performance microwave absorption materials but also pave a new way for optimizing the CMAPs through tailoring morphology engineering.

Key words: Core@shell structure, MSe₂/FeSe₂@MoSe₂ (M=Co, Ni), multicomponent nanocomposites, Flower-like geometry morphology, Broad frequency bandwidth, Microwave absorption

Zhang Jingjing, Qi Xiaosi, Gong Xiu, Peng Qiong, Chen Yanli, Xie Ren, Zhong Wei. Microstructure optimization of core@shell structured MSe₂/FeSe₂@MoSe₂ (M = Co, Ni) flower-like multicomponent nanocomposites towards high-efficiency microwave absorption[J]. J. Mater. Sci. Technol., 2022, 128: 59-70.

Figures/Tables 13

Fig. 1. Schematic diagram for the production of (a) CoFe2O4 and NiFe2O4 precursors, and (b) core@shell structured CoSe2/FeSe2@MoSe2 and NiSe2/FeSe2@MoSe2flower-like MCNCs.

Table 1. Summarized sheets of designed experimental parameters and prepared samples.

Experiment	Category of precursor	Amount of Mo source (mmol)	Amount of Se source (mmol)	Name of samples
i	CoFe₂O₄	1.5	3.0	C1
		3.0	6.0	C2
		4.5	9.0	C3
ii	NiFe₂O₄	1.5	3.0	N1
		3.0	6.0	N2
		4.5	9.0	N3
iii	-	4.5	9.0	Bare MoSe₂

Fig. 2. XRD patterns of (a) CoFe2O4; (b) C1, C2, C3, and bare MoSe2, respectively.

Fig. 3. Typical TEM images of (a, b) C1, (c, d) C2, and (e, f) C3, respectively.

Fig. 4. (a, b) HAADF-STEM; element mapping images of (c) Mo, (d) Se, (e) Co, and (f) Fe for C1.

Fig. 5. High-resolution XPS spectra taken from C3 for (a) Co 2p, (b) Fe 2p, (c) Mo 3d, and (d) Se 3d, respectively.

Fig. 6. (a-c) 3D color RL maps; (d-f) typical two-dimensional RL curves in the different frequency bands; (g-i) RL and EAB values of C1, C2, and C3.

Table 2. Contrastive table of MAPs between the representative MCNCs reported elsewhere and our designed MCNCs.

Materials	RL_min (dB)	Thickness (mm)	EAB (GHz)	Thickness (mm)	Refs.
MoSe₂	-57.20	2.70	4.00	2.70	[19]
CoS₂@MoS₂/rGO	-58.00	2.40	6.24	2.40	[43]
MoS₂/CNF	-54.55	3.80	5.84	2.50	[44]
CoS₂@rGO	-56.90	2.20	4.10	2.20	[45]
WS₂/NiO	-53.30	4.30	4.88	2.20	[46]
CoS₂/Cu₂S	-51.68	4.50	3.84	2.00	[47]
CuFe₂O₄/MoS₂	-49.43	2.70	8.16	2.30	[48]
MgFe₂O₄/MgO/C@MoS₂	-56.94	3.50	3.90	2.70	[49]
ZnFe₂O₄@C@MoS₂/FeS₂	-52.50	2.50	4.98	2.23	[50]
Fe₃O₄/Fe@C@MoS₂	-53.79	2.24	4.40	2.24	[51]
NiS/Ni₃S₄@PPy@MoS₂	-51.29	2.29	3.24	2.29	[52]
ZnFe₂O₄@MoS₂	-61.80	3.00	5.80	2.00	[53]
MoS₂@PPy@Fe₃O₄	-32.00	2.00	4.30	2.00	[54]
CoSe₂/FeSe₂@MoSe₂	-62.08	1.97	4.60	1.72	This work
NiSe₂/FeSe₂@MoSe₂	-50.82	2.01	4.60	1.77	This work

Fig. 7. (a-c) Complex permittivity; (d-f) impedance matching characteristics of as-prepared C1, C2, and C3.

Fig. 8. (a, b) XRD patterns of NiFe2O4, N1, N2, and N3; (c, d) high-resolution XPS spectra for Mo 3d and Se 3d, respectively.

Fig. 9. (a, b) TEM images of N2; (c, d) TEM images of N3; (e) high-angle annular dark-field scanning TEM; element mapping images of (f) Mo, (g) Se, (h) Fe, and (i) Ni for N3.

Fig. 10. (a-c) Two-dimensional color RL maps; (d-f) RL and dm values; (g-i) EAB and dm for the as-prepared N1, N2, and N3 in the frequency range of S, C, X, and Ku-bands, respectively.

Fig. 11. (a-c) Cole-Cole plots and (d-f) typical curves of impedance matching ratio versus frequency for the as-prepared NiSe2/FeSe2@MoSe2 samples.

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Microstructure optimization of core@shell structured MSe₂/FeSe₂@MoSe₂ (M = Co, Ni) flower-like multicomponent nanocomposites towards high-efficiency microwave absorption

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