NiCoLDH nanosheets grown on MOF-derived Co3O4 triangle nanosheet arrays for high-performance supercapacitor

doi:10.1016/j.jmst.2020.05.066

Abstract

Abstract:

Hierarchical Co₃O₄@NiCoLDH nanosheets (NSs) were prepared on carbon cloth through a multistep method, containing Metal-organic frameworks (MOF)-templated thermal annealing and electrodeposition. The triangle-shaped Co₃O_4NSs were firstly obtained by thermal treatment of MOF templates in air. Then, ultrathin NiCoLDH_NSs were in-situ electrodeposited on the surface of Co₃O_4NSs, constructing a core-shell structure. Benefiting the unique hierarchical structure, high conductivity of Co₃O_4NSs core and large surface area of NiCoLDH_NSs shell, the Co₃O₄@NiCoLDH_NSs array served as supercapacitor electrode exhibits excellent electrochemical properties, such as high specific capacitance of 1708 F g^-1 (850 C g^-1) at a current density of 1 A g^-1, good rate capability, and excellent cycling stability. Further, the asymmetric supercapacitor assembled by Co₃O₄@NiCoLDH_NSs and activated carbon, also displays superior electrochemical performance with high energy density and power density. Remarkably, the strategy of constructing core-shell structure based on MOF templates could be extended to other electrochemical fields.

Key words: NiCoLDH, Co₃O₄, Core-shell, Supercapacitor, MOF

Xuemin Yin, Hejun Li, Ruimei Yuan, Jinhua Lu. NiCoLDH nanosheets grown on MOF-derived Co₃O₄ triangle nanosheet arrays for high-performance supercapacitor[J]. J. Mater. Sci. Technol., 2021, 62: 60-69.

Figures/Tables 8

Fig. 1. Schematic illustration of the preparation of Co3O4@NiCoLDHNSs/CC.

Fig. 2. SEM images of different samples: (a) Co-MOFNSs/CC; (b), (c) Co3O4NSs/CC; (d)-(f) Co3O4@NiCoLDHNSs/CC. (g) EDX mapping images of Co3O4@NiCoLDHNSs/CC.

Fig. 3. (a, b, d, e) TEM and (c, f) HRTEM images of different samples: (a-c) Co3O4 and (d-f) Co3O4@NiCoLDHNSs, insert (f) is the enlarged HRTEM image.

Fig. 4. (a) XRD patterns of different samples. XPS spectrum of Co3O4@NiCoLDHNSs: (b) Survey spectrum, high-resolution spectrum of (c) Ni 2p and (d) Co 2p.

Fig. 5. (a) CV curves, (b) GCD curves, (e) Rate performance and (f) Nyquist plots of different samples. (c) CV and (d) GCD curves of Co3O4@NiCoLDHNSs/CC electrode.

Fig. 6. (a) Cycle performance of different samples at a current density of 10 A g-1 for 4000 cycles; (b) CV curves of Co3O4@NiCoLDHNSs-20 before and after cycles at 20 mV s-1.

Fig. 7. (a) CV curves of Co3O4@NiCoLDHNSs/CC and AC/CC electrodes at a scan rate of 20 mV s-1; (b) CV curves in different potential ranges at 50 mVs-1, (c) GCD curves in different potential ranges at 5 A g-1, (d) CV curves at different scan rates, (e) GCD curves at different current densities, and (f) Specific capacitances at different current densities of Co3O4@NiCoLDHNSs//AC ASC.

Fig. 8. (a) Ragone plots and (b) Cycling performance of Co3O4@NiCoLDHNSs//AC ASC. Insert (b) is the digital photos of a red LED powered by two devices in series.

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NiCoLDH nanosheets grown on MOF-derived Co₃O₄ triangle nanosheet arrays for high-performance supercapacitor

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