J. Mater. Sci. Technol. ›› 2021, Vol. 61: 138-146.DOI: 10.1016/j.jmst.2020.05.063
• Research Article • Previous Articles Next Articles
Xianlong Wang, Jinchuan Jie*(), Shichao Liu, Zhuangzhuang Dong, Guomao Yin, Tingju Li
Received:
2020-04-15
Revised:
2020-04-29
Accepted:
2020-05-02
Published:
2021-01-20
Online:
2021-01-20
Contact:
Jinchuan Jie
Xianlong Wang, Jinchuan Jie, Shichao Liu, Zhuangzhuang Dong, Guomao Yin, Tingju Li. Growth mechanism of primary Ti5Si3 phases in special brasses and their effect on wear resistance[J]. J. Mater. Sci. Technol., 2021, 61: 138-146.
Nominal composition | Measured chemical compositions (wt.%) | ||||
---|---|---|---|---|---|
Ti | Si | Zn | Al | Cu | |
1#, Cu-35Zn-3Al-0.71Ti-0.25Si | 0.69 | 0.24 | 32.71 | 2.97 | Bal. |
2#, Cu-35Zn-3Al-1.43Ti-0.5Si | 1.33 | 0.49 | 32.36 | 2.88 | Bal. |
3#, Cu-35Zn-3Al-2.86Ti-1Si | 2.72 | 0.94 | 31.66 | 3.01 | Bal. |
4#, Cu-35Zn-3Al-4.28Ti-1.5Si | 4.10 | 1.42 | 31.27 | 2.87 | Bal. |
Table 1 Chemical composition of as-prepared special brasses.
Nominal composition | Measured chemical compositions (wt.%) | ||||
---|---|---|---|---|---|
Ti | Si | Zn | Al | Cu | |
1#, Cu-35Zn-3Al-0.71Ti-0.25Si | 0.69 | 0.24 | 32.71 | 2.97 | Bal. |
2#, Cu-35Zn-3Al-1.43Ti-0.5Si | 1.33 | 0.49 | 32.36 | 2.88 | Bal. |
3#, Cu-35Zn-3Al-2.86Ti-1Si | 2.72 | 0.94 | 31.66 | 3.01 | Bal. |
4#, Cu-35Zn-3Al-4.28Ti-1.5Si | 4.10 | 1.42 | 31.27 | 2.87 | Bal. |
Fig. 1. XRD patterns of (a-d) the as-prepared 1#-4# special brasses, (e-h) the extracted powders from the prepared 1#-4# special brasses, respectively.
Fig. 2. Microstructures of the as-cast special brasses: (a) 1# brass with 0.96 wt.% Ti5Si3; (b) 2# brass with 1.93 wt.% Ti5Si3; (c) 3# brass with 3.86 wt.% Ti5Si3; (d) 4# brass with 5.78 wt.% Ti5Si3; (e) corresponding EDS results of the points 1-4.
Fig. 3. TEM analysis of the 1# special brass: (a) TEM image of primary Ti5Si3; (b) SAED pattern along the [110] zone axis of Ti5Si3; (c) HRTEM image of Ti5Si3.
Fig. 4. 3D morphologies of the deeply etching samples and extracted powders of the 1#-4# special brasses: (a) 1# brass with 0.96 wt.% Ti5Si3; (b) 2# brass with 1.93 wt.% Ti5Si3; (c) 3# brass with 3.86 wt.% Ti5Si3; (d) 4# brass with 5.78 wt.% Ti5Si3.
Fig. 5. (a) Volume fraction of the primary Ti5Si3 phase in the 1#-4# special brasses and (b) average diameter and aspect ratio of the primary Ti5Si3 phase in the 1#-4# special brasses.
Fig. 7. (a) $\bar{\mu }$ curves of 1#-4# special brasses and (b) variation of wear rate and friction coefficient of 1#-4# special brasses under 216 N contact pressures.
Parameter | Ti3Si | TiSi2 | TiSi | Ti5Si4 | Ti5Si3 | Type |
---|---|---|---|---|---|---|
Eform (kJ/mol) | -47. 1 | -49.9 | -72.2 | -74.6 | -72.7 | Ab-initio, T = 0 K |
-49 | -55 | -72.6 | -73.8 | -78.5 | Experimental, T = 298 K | |
Melting point (K) | 1443 | 1773 | 1843 | 2193 | 2401 | - |
Table 2 The formation enthalpy of the TixSiy compounds.
Parameter | Ti3Si | TiSi2 | TiSi | Ti5Si4 | Ti5Si3 | Type |
---|---|---|---|---|---|---|
Eform (kJ/mol) | -47. 1 | -49.9 | -72.2 | -74.6 | -72.7 | Ab-initio, T = 0 K |
-49 | -55 | -72.6 | -73.8 | -78.5 | Experimental, T = 298 K | |
Melting point (K) | 1443 | 1773 | 1843 | 2193 | 2401 | - |
Fig. 9. Worn surface topographies of (a-d) 1#-4# special brasses by confocal laser microscopy, (e) the cross-sectional view of 1#-4# brass worn surfaces in the x-z plane, and (f) λ value of 1#-4# special brasses as a function of the primary Ti5Si3 volume fraction.
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