J. Mater. Sci. Technol. ›› 2025, Vol. 216: 38-51.DOI: 10.1016/j.jmst.2024.07.052

• Research Article • Previous Articles     Next Articles

Enhancing strength and irradiation tolerance of Mg alloy via co-addition of Mn and Ca elements

Wei Zhanga,b, Zhipeng Shena, Hucheng Pana,∗, Tao Wanga, Tong Fub, Dongsheng Xiea,b,∗, Aitao Tangc, Changqing Tengb, Lu Wub,∗, Gaowu Qina   

  1. aKey Laboratory for Anisotropy and Texture of Materials (Ministry of Education), College of Materials Science and Engineering, Northeastern University, Shenyang 110819, China;
    bThe First Sub-institute, Nuclear Power Institute of China, Chengdu 610041, China;
    cCollege of Materials Science and Engineering, Chongqing University, Chongqing 40044, China
  • Received:2024-05-09 Revised:2024-07-02 Accepted:2024-07-02 Published:2025-05-01 Online:2024-09-12
  • Contact: *E-mail addresses: panhc@atm.neu.edu.cn (H. Pan), 819299974@qq.com (D. Xie), wulu1002@qq.com (L. Wu)

Abstract: The Mg alloys with combination of high strength and excellent irradiation resistance are currently required for research reactors. In this work, the novel Mg-3Mn-0.5Ca alloy with a high strength of over 300 MPa has been fabricated via co-addition of Mn and Ca elements. Moreover, the Xe ion implantation (300 °C/4.5 × 1015 ions/cm2) is conducted for pure Mg, Mg-3Mn and Mg-3Mn-0.5Ca alloys. Microstructure characterization shows that the number density of dislocation loops is comparable between Mg-3Mn and pure Mg, while the phase boundary of nano-Mn particles could act as the sink to absorb more Xe atoms, resulting in the abundant formation of Xe bubbles in the matrix of irradiated Mg-3Mn alloy. With further minor addition of Ca element, the formation of Xe bubbles and dislocation loops in Mg-3Mn-0.5Ca alloy has been obviously suppressed, and the abundant grain boundaries (GBs) due to grain refinement then act as the sink region for Xe precipitation. The limited number density of Xe bubbles leads to the extremely low swelling ratio in Mg-3Mn-0.5Ca alloy, ∼0.08 %. The result above suggests that the Mn and Ca co-addition could enhance the mechanical properties and irradiation tolerance of Mg alloys, simultaneously. The present low-alloying strategy would provide a new design reference for novel nuclear materials.

Key words: Magnesium alloy, Mechanical property, Xe bubble, Irradiation hardening