Multistage microcellular waterborne polyurethane composite with optionally low-reflection behavior for ultra-efficient electromagnetic interference shielding

doi:10.1016/j.jmst.2024.04.061

Abstract

Abstract: Electromagnetic interference (EMI) shielding materials with superior shielding efficiency and low-reflection properties hold promising potential for utilization across electronic components, precision instruments, and fifth-generation communication equipment. In this study, multistage microcellular waterborne polyurethane (WPU) composites were constructed via gradient induction, layer-by-layer casting, and supercritical carbon dioxide foaming. The gradient-structured WPU/iron-cobalt loaded reduced graphene oxide (FeCo@rGO) foam serves as an impedance-matched absorption layer, while the highly conductive WPU/silver loaded glass microspheres (Ag@GM) layer is employed as a reflection layer. Thanks to the incorporation of an asymmetric structure, as well as the introduction of gradient and porous configurations, the composite foam demonstrates excellent conductivity, outstanding EMI SE (74.9 dB), and minimal reflection characteristics (35.28 %) in 8.2-12.4 GHz, implying that more than 99.99999 % of electromagnetic (EM) waves were blocked and only 35.28 % were reflected to the external environment. Interestingly, the reflectivity of the composite foam is reduced to 0.41 % at 10.88 GHz due to the resonance for incident and reflected EM waves. Beyond that, the composite foam is characterized by low density (0.47 g/cm³) and great stability of EMI shielding properties. This work offers a viable approach for crafting lightweight, highly shielding, and minimally reflective EMI shielding composites.

Key words: Electromagnetic interference shielding, Supercritical carbon dioxide (ScCO₂) foaming, Low reflectivity, Multilayered structure, Microcellular

Jianming Yang, Hu Wang, Hexin Zhang, Peng Lin, Hong Gao, Youyi Xia, Xia Liao. Multistage microcellular waterborne polyurethane composite with optionally low-reflection behavior for ultra-efficient electromagnetic interference shielding[J]. J. Mater. Sci. Technol., 2025, 208: 132-140.

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