J. Mater. Sci. Technol. ›› 2024, Vol. 174: 145-156.DOI: 10.1016/j.jmst.2023.03.048

• Research Article • Previous Articles     Next Articles

Phase evolution and mechanical properties of low-activation refractory high-entropy alloy Ti1.5ZrV0.5Ta0.5

Yuxiang Chena, Ningyu Lia, Yijie Wanga, Kang Liua, Yongqin Changa,*, Mingyang Lib,*   

  1. aSchool of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China;
    bXi'an Rare Metal Materials Institute Co. Ltd, Xi'an 710016, China
  • Received:2023-01-05 Revised:2023-03-28 Accepted:2023-03-29 Published:2024-03-01 Online:2023-05-20
  • Contact: *E-mail addresses: chang@ustb.edu.cn (Y. Chang), myli.ustb@gmail.com (M. Li)

Abstract: A novel low-activation Ti1.5ZrV0.5Ta0.5 refractory high-entropy alloy (RHEA) was designed as a potential candidate for nuclear reactor application. At room temperature, it had an elongation of 8.4% and a yield strength of 1096 MPa. The phase evolution of this alloy and its effect on properties was investigated. At 400 °C, the solid solution bcc1 transformed into the fcc phase and bcc2 phase, and the ω phase and α phase also appeared. At 600 °C, the ω phase and α phase disappeared, and the microstructure of the alloy was composed of the fcc phase and bcc2 phase. When the temperature was up to 1200 °C, the fcc phase and bcc2 phase re-transformed into solid solution bcc1 phase. The precipitation of ω phase and α phase caused a sharp increase in strength and a decrease in plasticity. Meanwhile, the appearance of the fcc phase led to a simultaneous decrease in strength and ductility, due to larger stress concentrations at the fcc/bcc interface. Besides, the formation mechanism of each phase in the alloy was discussed in detail.

Key words: Low-activation, Refractory high-entropy alloy, Phase evolution, Phase formation mechanism, Strengthening mechanism