J. Mater. Sci. Technol. ›› 2020, Vol. 51: 119-129.DOI: 10.1016/j.jmst.2020.02.041
• Research Article • Previous Articles Next Articles
Angga Hermawana, Yusuke Asakuraa, Miki Inadab, Shu Yina,*()
Received:
2019-11-24
Revised:
2020-02-12
Accepted:
2020-02-16
Published:
2020-08-15
Online:
2020-08-11
Contact:
Shu Yin
Angga Hermawan, Yusuke Asakura, Miki Inada, Shu Yin. A facile method for preparation of uniformly decorated-spherical SnO2 by CuO nanoparticles for highly responsive toluene detection at high temperature[J]. J. Mater. Sci. Technol., 2020, 51: 119-129.
Fig. 2. TEM images (inset is ED pattern) and the corresponding HRTEM image of (a, b) CuO nanoparticle (c, d) spherical SnO2 (e, f) SnO2@CuO. (g) Dark-field image and elemental mapping of (h) Sn (i) Cu (j) O and (k) EDX profile of SnO2@CuO.
Fig. 5. (a) The gas sensing response of all samples at different working temperature and response/recovery time of (b) CuO, (c) SnO2 and (d) SnO2@CuO at 400 °C.
Fig. 6. (a) A transient sensing response of SnO2@CuO to different concentrations of toluene gas (b) exponential fitting vs. toluene concentration; y and x-axis represents sensing response and toluene concentration, respectively and R shows quality of fitting, (c) selectivity of SnO2@CuO.
Material | T (oC) | Conc. (ppm) | Response (Ra/Rg or Rg/Ra) | Selectivity Rtoluene/Rothergas | Response/ recovery times (s) | Refs. |
---|---|---|---|---|---|---|
SnO2-decorated NiO nanostructure | 250 | 100 | 60 | 2 | N/A | [ |
NiO -SnO2 composite nanofiber | 330 | 50 | 11 | 3.8 | 11.2 /4 s | [ |
SnO2-Fe2O3 Interconnected Nanotubes | 260 | 50 | 25.3 | 7 | 6/10 | [ |
Pd-loaded flower-like SnO2 microspheres | 250 | 10 | 17.4 | 1.7 | N/A | [ |
Pd- loaded SnO2 cubic nanocages | 230 | 20 | 41.4 | 4.1 | 0.4/16.5 | [ |
SnO2-ZnO core-shell nanowires | 300 | 1 | 73 | 2.8 | N/A | [ |
CuO-decorated spherical SnO2 | 400 | 75 | 540 | 5 | 100/36 | This work |
Table 1 Comparison of SnO2-based toluene gas sensing performance.
Material | T (oC) | Conc. (ppm) | Response (Ra/Rg or Rg/Ra) | Selectivity Rtoluene/Rothergas | Response/ recovery times (s) | Refs. |
---|---|---|---|---|---|---|
SnO2-decorated NiO nanostructure | 250 | 100 | 60 | 2 | N/A | [ |
NiO -SnO2 composite nanofiber | 330 | 50 | 11 | 3.8 | 11.2 /4 s | [ |
SnO2-Fe2O3 Interconnected Nanotubes | 260 | 50 | 25.3 | 7 | 6/10 | [ |
Pd-loaded flower-like SnO2 microspheres | 250 | 10 | 17.4 | 1.7 | N/A | [ |
Pd- loaded SnO2 cubic nanocages | 230 | 20 | 41.4 | 4.1 | 0.4/16.5 | [ |
SnO2-ZnO core-shell nanowires | 300 | 1 | 73 | 2.8 | N/A | [ |
CuO-decorated spherical SnO2 | 400 | 75 | 540 | 5 | 100/36 | This work |
Fig. 7. (a) Gas sensing response as a function of toluene concentration and (b) relationship between sensor base resistance and toluene sensing response of SnO2@CuO based-sensor with different amount of decorating material.
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