J. Mater. Sci. Technol. ›› 2016, Vol. 32 ›› Issue (8): 705-709.DOI: 10.1016/j.jmst.2016.06.017

• Orginal Article • Previous Articles     Next Articles

Superelasticity and Tunable Thermal Expansion across a Wide Temperature Range

Hao Y.L.1,*(),Wang H.L.1,Li T.2,3,Cairney J.M.2,3,Ceguerra A.V.2,3,Wang Y.D.4,Wang Y.5,6,Wang D.5,Obbard E.G.7,Li S.J.1,Yang R.1   

  1. 1 Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
    2 School of Aerospace, Mechanical & Mechatronic Engineering, University of Sydney, Sydney, NSW 2006, Australia
    3 Australian Centre for Microscopy and Microanalysis, University of Sydney, Sydney, NSW 2006, Australia
    4 State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China
    5 State Key Laboratory for Mechanical Behavior of Materials and Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an 710049, China
    6 Department of Materials Science and Engineering, Ohio State University, Columbus, OH 43210, USA
    7 Department of Electrical Engineering and Telecommunications, University of New South Wales, Sydney, NSW 2052, Australia
  • Received:2016-04-22 Accepted:2016-05-30 Online:2016-08-10 Published:2016-10-10
  • Contact: Hao Y.L.

Abstract:

Materials that undergo a reversible change of crystal structure through martensitic transformation (MT) possess unusual functionalities including shape memory, superelasticity, and low/negative thermal expansion. These properties have many advanced applications, such as actuators, sensors, and energy conversion, but are limited typically in a narrow temperature range of tens of Kelvin. Here we report that, by creating a nano-scale concentration modulation via phase separation, the MT can be rendered continuous by an in-situ elastic confinement mechanism. Through a model titanium alloy, we demonstrate that the elastically confined continuous MT has unprecedented properties, such as superelasticity from below 4.2?K to 500?K, fully tunable and stable thermal expansion, from positive, through zero, to negative, from below 4.2?K to 573?K, and high strength-to-modulus ratio across a wide temperature range. The elastic tuning on the MT, together with a significant extension of the crystal stability limit, provides new opportunities to explore advanced materials.

Key words: Ti alloy, Superelasticity, Thermal expansion behavior, Temperature characteristic