The Kirkendall effect on erosion resistance of chrome-coated 25Cr3Mo2WNiV and 30SiMn2MoV gun barrel steels

doi:10.1016/j.jmst.2023.07.062

J. Mater. Sci. Technol. ›› 2024, Vol. 177: 246-255.DOI: 10.1016/j.jmst.2023.07.062

• Research article • Previous Articles Next Articles

The Kirkendall effect on erosion resistance of chrome-coated 25Cr3Mo2WNiV and 30SiMn2MoV gun barrel steels

C.H. Dou^a, P.F. Jin^a, C.Z. Wang^a, J.J. Li^a, C. Zhang^b, J.F. Huang^a,*, C. Zhang^a,*

^aKey Laboratory for Advanced Materials Processing State, State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China;
^bNational Joint Engineering Research Center for Abrasion Control and Molding of Metal Materials, School of Materials Science and Engineering, Henan University of Science and Technology, Luoyang 471003, China

Received:2023-04-25 Revised:2023-06-13 Accepted:2023-07-04 Published:2024-04-01 Online:2024-03-25
Contact: ^*E-mail addresses: huangjf@ustb.edu.cn (J.F. Huang), zhangcheng@ustb.edu.cn (C. Zhang)

Abstract

Abstract: This study aimed to investigate the erosion behavior and mechanism of a newly developed 25Cr3Mo2WNiV steel with a chrome coating using promoted ignition combustion tests. The erosion threshold pressure and temperature of the chrome-coated 25Cr3Mo2WNiV steel were determined to be 0.2 MPa and 254.3 K higher than those of traditional chrome-coated 30SiMn2MoV steel. Furthermore, Kirkendall voids and inter-diffusion between the Cr coating and matrix were first observed before erosion. The improved erosion resistance of the chrome-coated 25Cr3Mo2WNiV steel was attributed to the suppression of the Kirkendall effect, which minimized heat generation at the Cr/matrix interface by preventing oxygen diffusion and reducing oxygen affinity.

Key words: Erosion resistance, Kirkendall effect, Cr coating, Gun steel

C.H. Dou, P.F. Jin, C.Z. Wang, J.J. Li, C. Zhang, J.F. Huang, C. Zhang. The Kirkendall effect on erosion resistance of chrome-coated 25Cr3Mo2WNiV and 30SiMn2MoV gun barrel steels[J]. J. Mater. Sci. Technol., 2024, 177: 246-255.

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The Kirkendall effect on erosion resistance of chrome-coated 25Cr3Mo2WNiV and 30SiMn2MoV gun barrel steels

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