J. Mater. Sci. Technol. ›› 2023, Vol. 150: 11-26.DOI: 10.1016/j.jmst.2022.10.092

• Review Article • Previous Articles     Next Articles

Recent advances in metal-free CDs/g-C3N4 photocatalysts: Synthetic strategies, mechanism insight, and applications

Xingxing Yanga, Lina Shenga, Yongli Yea, Jiadi Suna, Zaijun Lic, Xiao Ninga,d, Jin Caod, Xiulan Suna,b,*   

  1. aState Key Laboratory of Food Science and Technology, School of Food Science and Technology, Collaborative Innovation Center of Food Safety and Quality Control, Jiangnan University, Wuxi 214122, China;
    bYixing Institute of Food and Biotechnology Co., Ltd, Yixing 214200, China;
    cSchool of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China;
    dNational Institutes for Food and Drug Control, Beijing 100050, China
  • Received:2022-09-12 Revised:2022-10-20 Accepted:2022-10-21 Published:2023-07-01 Online:2023-01-16
  • Contact: * E-mail address: tsxlzyz@jiangnan.edu.cn (X. Sun).

Abstract: Carbon dots/graphite carbon nitride (CDs/g-C3N4), a novel composite photocatalyst, has shown great potential for applications in energy regeneration and environmental remediation owing to its following advantages: metal-free, low cost, easily tunable, and excellent photocatalytic performance. Hence, we reviewed the development of synthetic strategies, photocatalytic enhancement mechanisms, and photocatalytic applications of CDs/g-C3N4 in this study. First, the three composite strategies of CDs and g-C3N4-self-assembly, solvothermal, and calcination polymerization are outlined, and their advantages and disadvantages are described in detail. Moreover, the photocatalytic enhancement mechanism of the composite strategies was elucidated according to the variation trends of CDs/g-C3N4 band structure, electronic properties, light absorption range, and interfacial charge transfer. Then, the applications of CDs/g-C3N4 in hydrogen evolution, pollutant degradation, CO2 reduction, and bacterial disinfection in recent years are reviewed systematically. Finally, the current obstacles and future research directions of CDs/g-C3N4 are discussed from the perspective of preparation technology and practical applications, respectively.

Key words: Photocatalysis, Graphite carbon nitride, Carbon dots, Synthetic strategy, Photocatalytic application