Screen printing fabricating patterned and customized full paper-based energy storage devices with excellent photothermal, self-healing, high energy density and good electromagnetic shielding performances

doi:10.1016/j.jmst.2021.04.054

Abstract

Abstract:

Supercapacitors are favored by researchers because of their high power density, especially with the acceleration of people's life rhythm. However, their energy density, especially from the point of view of the whole energy storage device, is far lower than that of commercial batteries. In this work, a kind of customizable full paper-based supercapacitor device with excellent self-healing ability is fabricated by simple and low-cost screen printing, electropolymerization and dip coating methods. The resultant separator-free supercapacitor device exhibits both ultrahigh gravimetric and areal specific energy (power) densities of 39 Wh kg^-1 (69 kW kg^-1) and 692 μWh cm ^-2 (236 mW cm^-2), achieving excellent supercapacitor performance. Notably, the addition of vitrimers endows the whole device with outstanding self-healing properties, which is helpful for enhancing the adaptability of the device to the environment. In addition, this kind of paper-based device also displays good photothermal and electromagnetic shielding performances. These striking features make paper matrix composites attractive in the fields of supercapacitors, medical photothermal treatment and electromagnetic shielding.

Key words: Customizable full paper-based supercapacitors, Energy density, Self-healing, Photothermal, Electromagnetic shielding

Chuanyin Xiong, Mengrui Li, Qing Han, Wei Zhao, Lei Dai, Yonghao Ni. Screen printing fabricating patterned and customized full paper-based energy storage devices with excellent photothermal, self-healing, high energy density and good electromagnetic shielding performances[J]. J. Mater. Sci. Technol., 2022, 97: 190-200.

Figures/Tables 8

Fig. 1. (A) Synthesis route of the vitrimer. (B) Schematic diagram of the self-healing mechanism of the paper-based energy storage device.

Fig. 2. Fabrication procedure of the IP@PN-V hybrid.

Fig. 3. Photographs and SEM images of OP ((a) and (b) front images, (c) cross-section images); IP ((d) and (e) front images, (f) cross-section images) IP@PN ((g) and (h) front images, (i) cross-section images); IP@PN-V ((j) and (k) front images, (l) cross-section images); (m) micro flexible energy storage devices constructed with different shapes.

Fig. 4. Comparison of (a) XRD patterns, (b) Raman spectra, and (c) FT-IR spectra of OP, IP, IP@PN and IP@PN-V, (d) high-resolution of N 1s spectra of the IP@PN-V samples.

Fig. 5. Photothermal conversion characteristics of (A) OP, (B) IP5, and (C) IP5@PN. (D) Comparison of temperature rise curves of three corresponding samples irradiated by an 808 nm laser for 60 s.

Fig. 6. Digital photographs of IP5@PN (1) original state, (2) various damage conditions, and (3) after self-healing.

Fig. 7. Comparison of (a-c) CV curves and (d) GCD curves of IP1, IP5, IP10, IP@PN1, IP@PN5, IP@PN10, IP@PN1-V, IP@PN5-V and IP@PN10-V hybrids at different scan rates and current densities, respectively. (e) Comparison of EIS measurements of IP@PN1, IP@PN5, IP@PN10, IP@PN1-V, IP@PN5-V and IP@PN10-V. Comparison of capacitance retention of IP@PN5 and IP@PN5-V hybrid (f) at various current densities and (g) after experiencing 5000 cycles respectively. (h) Comparison of energy efficiency of IP@PN5 and IP@PN5-V hybrids at different current densities, respectively. (i) Comparison of energy and power densities of the IP@PN5-V paper-based supercapacitor device with those of commercial supercapacitor energy storage devices. The inset is reprinted with permission from Ref. [35].

Fig. 8. (a) SEA of OP, IP, IP@PN, and IP@PN-V. (b) SER of OP, IP, IP@PN, and IP@PN-V. (c) EMI shielding effectiveness of OP, IP, IP@PN, and IP@PN-V. (d) Screen printing the IP@PN-V hybrid onto a plastic lunch box and using it as the back cover of the mobile phone.

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