J. Mater. Sci. Technol. ›› 2019, Vol. 35 ›› Issue (7): 1309-1314.DOI: 10.1016/j.jmst.2019.03.004

• Orginal Article • Previous Articles     Next Articles

Probing the degenerate pattern growth of {100}<011> orientation in a directionally solidified Al-4.5 wt% Cu alloy

Yumin Wanga, Shuangming Lia*(), Zhenpeng Liua, Hong Zhonga, Lei Xub, Hui Xingac   

  1. aState Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an, 710072, China;
    bCollege of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao, 266000, China
    cMOE Key Laboratory of Material Physics and Chemistry under Extraordinary, Shaanxi Key Laboratory of Condensed Matter Structure and Properties, Northwestern Polytechnical University, Xi'an, 710129, China
  • Received:2019-01-04 Revised:2019-01-18 Accepted:2019-01-27 Online:2019-07-20 Published:2019-06-20
  • Contact: Li Shuangming
  • About author:

    1These authors contributed equally.

Abstract:

Degenerate pattern is a seemingly disordered morphology but it exhibits the inherently ordered crystal connected with tip-splitting and limited stability which makes it difficult to observe in the metallic system. Here we employ (100)[011] orientated planar-front seeds using directional solidification and reveal the fundamental origins of the degenerate pattern growth in an Al-4.5 wt% Cu alloy. We find that the spacing of the tip-splitting (λ) in the degenerate of the alloys followed a power law, λV-0.5, and the frequency (f) of the splitting was related to the growth velocity (V) by f∝V1.5. The dimensionless growth direction (θ/θ0) increased monotonously and approached 0.6 with faster velocity, attributed to its anisotropy in the interface kinetics. Once growth velocity exceeded a threshold, two types of pattern transitions from degenerate to regular dendrites were proposed. One of them exhibited a random and chaotic mode and the other underwent a rotation in growth direction.

Key words: Al-Cu alloy, Anisotropy, Direction solidification, Degenerate pattern