Oxygen Permeation and Stability of Ce0.8Gd0.2O2-δ-PrBaCo2-xFexO5+δ Dual-phase Composite Membranes

doi:10.1016/j.jmst.2014.09.001

Abstract

Abstract: Dual-phase membranes of 60 wt% Ce_0.8Gd_0.2O_2-δ-40 wt% PrBaCo₂-xFexO_3-δ (0 ≤ x ≤ 2) were prepared by combined citrate and ethylene diamine tetraacetic acid (EDTA) complexing method. X-ray diffraction (XRD) results revealed the good chemical compatibility between ion-conducting phase CGO and electron-conducting phases PBC₂-xFxO after sintering in air. The Fe ionic dopant had a significant effect on the phase structure stability and oxygen permeability under CO₂ atmosphere, which was confirmed by XRD, thermogravimetry-differential scanning calorimetry (TG-DSC), scanning electron microscopy (SEM) and oxygen permeation experiments. CGO-PBC_0.5F_1.5O dual-phase membrane demonstrated a stable oxygen permeation flux of 2.71 × 10^-7 mol cm^-2 s^-1 with 50 mol% He/CO₂ as the sweep gas at 925 °C, and this value was much higher than that of perovskite-type membranes. The rate-limiting step in the oxygen permeation process changed from the bulk diffusion to the surface oxygen exchange when the CGO-PBC_0.5F_1.5O membrane thickness decreased to 0.8 mm or less. Due to the high oxygen permeation fluxes and the excellent structural stability under CO₂ atmosphere, the CGO-PBC_0.5F_1.5O membrane is a great potential candidate material for separating oxygen from air in the oxy-fuel combustion techniques.

Key words: Dual-phase membrane, Phase stability, Oxygen permeation, CO2-tolerance

Bo Jiang, Hongwei Cheng, Longfei Luo, Xionggang Lu, Zhongfu Zhou. Oxygen Permeation and Stability of Ce_0.8Gd_0.2O_2-δ-PrBaCo_2-xFexO₅₊δ Dual-phase Composite Membranes[J]. J. Mater. Sci. Technol., 2014, 30(12): 1174-1180.

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Oxygen Permeation and Stability of Ce_0.8Gd_0.2O_2-δ-PrBaCo_2-xFexO₅₊δ Dual-phase Composite Membranes

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