Understanding oxidation state of Cu-based catalysts for electrocatalytic CO2 reduction

doi:10.1016/j.jmst.2024.08.029

Abstract

Abstract: Electrocatalytic CO₂ reduction (ECR) is a promising approach for achieving carbon neutrality due to its ability to convert CO₂ to valuable chemicals. Recent advances have significantly enhanced the ECR performance of various catalysts by tuning their oxidation states, particularly for Cu-based catalysts that can reduce CO₂ to multiple products. However, the oxidation state of copper (OS_Cu), especially Cu⁺, changes during the reaction process, posing significant challenges for both catalyst characterization and performance. In this review, the current understanding of the effect of oxidation states on product selectivity was first discussed. A comprehensive overview of in situ/operando characterization techniques, used to monitor the dynamic evolution of oxidation states during ECR, was then provided. Various strategies for stabilizing oxidation states through modification of catalysts and manipulation of external conditions were discussed. This review aimed to deepen the understanding of oxidation states in ECR and enlighten the development of more efficient electrocatalysts.

Key words: Electrocatalytic CO₂ reduction, Cu-based catalysts, Oxidation state, In situ/operando characterization techniques, Stabilization strategies

Ping Zhu, Yuan-Chu Qin, Xin-Hao Cai, Wen-Min Wang, Ying Zhou, Lin-Lin Zhou, Peng-Hui Liu, Lu Peng, Wen-Long Wang, Qian-Yuan Wu. Understanding oxidation state of Cu-based catalysts for electrocatalytic CO₂ reduction[J]. J. Mater. Sci. Technol., 2025, 218: 1-24.

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Understanding oxidation state of Cu-based catalysts for electrocatalytic CO₂ reduction

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