Hollow engineering in CoNi@Air@C@MoS2 multicomponent composites derived from bimetallic CoNi Prussian blue analogs for ultra-wide bandwidth and strong electromagnetic wave absorption

doi:10.1016/j.jmst.2024.06.018

Abstract

Abstract: In recent years, two-dimensional layered transition metal dichalcogenides-based multicomponent com-posites (MCCs) acting as electromagnetic wave (EMW) materials have received intensive investiga-tions. However, the vulcanication of metal greatly hindered their enhancement of EMW absorption per-formances (EMWAPs). Herein, a combined metal-organic frameworks-derived and hydrothermal strat-egy was presented to produce yolk-shell structure (YSS) CoNi@Air@C@MoS₂ MCCs. The results showed that the thermal and hydrothermal treatments resulted in the generation of YSS and two-dimensional MoS₂ nanosheets, which maintained the original morphology of CoNi Prussian blue analogues. The pro-tection of thick C layer well inhibited the vulcanization of inner CoNi alloy. The formed sheet-like MoS₂ further optimized impedance matching characteristics, which led to the satisfactory EMWAPs of CoNi@Air@C@MoS₂ MCCs. Furthermore, the EMWAPs could be further improved by optimizing the Ni:Co atom ratios CoNi@Air@C@MoS₂ MCCs, which stemmed from their boosted impedance matching perfor-mances, EMW attention and polarization loss abilities. The absorption bandwidth and reflection loss val-ues for YSS CoNi@Air@C@MoS₂ MCCs are 8 GHz and-60.83 dB, which covered almost all C-Ku bands. In general, our research work provided a valid strategy to produce YSS magnetic CoNi@Air@C@MoS₂ MCCs with high efficiency, which well avoided the vulcanization of metal nanoparticles, made best of hollow engineering and atomic ratio optimization strategy to boost the comprehensive EMWAPs.

Key words: Hollow engineering, CoNi@Air@C@MoS₂, Polarization loss, Ultra-wide bandwidth, Microwave absorption

Ziqing Yang, Qiqin Liang, Xiaosi Qi, Beibei Zhan, Xiu Gong, Yunpeng Qu, Junfei Ding, Jing-Liang Yang, Yanli Chen, Qiong Peng, Wei Zhong. Hollow engineering in CoNi@Air@C@MoS₂ multicomponent composites derived from bimetallic CoNi Prussian blue analogs for ultra-wide bandwidth and strong electromagnetic wave absorption[J]. J. Mater. Sci. Technol., 2025, 212: 35-43.

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Hollow engineering in CoNi@Air@C@MoS₂ multicomponent composites derived from bimetallic CoNi Prussian blue analogs for ultra-wide bandwidth and strong electromagnetic wave absorption

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