J. Mater. Sci. Technol. ›› 2022, Vol. 130: 136-156.DOI: 10.1016/j.jmst.2022.05.010
• Review Article • Previous Articles Next Articles
Long Xiaa,*(
), Yuming Fenga, Biao Zhaob,*()
Received:2022-04-15
Revised:2022-05-06
Accepted:2022-05-06
Published:2022-12-10
Online:2022-12-07
Contact:
Long Xia,Biao Zhao
About author:E-mail addresses: zhao_biao@fudan.edu.cn (B. Zhao)Long Xia, Yuming Feng, Biao Zhao. Intrinsic mechanism and multiphysics analysis of electromagnetic wave absorbing materials: New horizons and breakthrough[J]. J. Mater. Sci. Technol., 2022, 130: 136-156.
Fig. 1. Electromagnetic protection, absorbing structure, and mechanism.
Fig. 2. Numerical analysis and simulation optimization module for wave absorbing materials.
Fig. 3. (a) 3D plot of the relationship between p, ε', and ε''. (b) Relationship between ε' and ε''; (c) relationship between ε' and tanε; (d) relation between ε' and p and Δp [40]. Copyright 2022, Elsevier.
Fig. 4. (a) Cole-Cole model, (b) experimental setup, (c) circuit model from [41]. Copyright 2020, Wiley-VCH. (d) Nyquist plots for different types of impedance [50]. Copyright 2021, Wiley. (e) τ, (f) β factors, (g) RL curves, and (h) 2D images of RL value from [51]. Copyright 2019, Elsevier.
Fig. 5. (a) Multilayer impedance matching model. (b) Dielectric constant curve. (c) 3D view of the conical structure. (d) Electric field distribution in the designed structure from Ref. [70]. Copyright 2021, Elsevier. (e) Multi-segment ladder impedance honeycomb structure model [71]. Copyright 2020, IOP. (f) Impedance matching map for a dielectric absorber [73]. Copyright 2012, the Japan Society of Applied Physics.
Fig. 6. (a) Microwave absorption mechanism of c-CMF. (b) Electric field distribution of the CMF cross-section at 12 GHz. (c) RL curves at different Δε, (d) comparison of theoretical and experimental RL curves from Ref. [83]. Copyright 2020, Elsevier. (e) Time-averaged power flow of MCS6, (f) time-averaged power flow of MCS8 from Ref. [51]. Copyright 2019, Elsevier.
Fig. 7. (a, d) TEM images; (b, c, e, f) electron holograms of Ni@MXene hybrids. (g) Electromagnetic wave absorption mechanisms from Ref. [86]. Copyright 2019, American Chemical Society. (h) MnO model, (j) MnO@N-doped carbon model, (i) simulated electric field distribution, and (k) magnetic field distribution of MnO and MnO@N-doped carbon composites from Ref. [87]. Copyright 2020, Elsevier. (l) Experimental scheme of Bragg coherent diffraction imaging. Evolution of the spontaneous polarization distribution (m, n, o) at field E [88]. Copyright 2017, the Author(s). (p) SEM image of PM-rGO/ACMs/rGO. (q) Simulation model and (r) electric field distribution. (s) Complex permittivity and (t) RL curves from Ref. [82]. Copyright 2016, WILEY-VCH.
Fig. 8. (a) Schematic of stretchable and microwave-invisible pangolin-inspired meta scale (PIMS). Finite element analysis results in the absorbing performance of PIMS: (b) Electric intensity and PLD; (c) electric field along the x-axis and the intensity of the in-plane component of the PLD. (d) Normalized power loss; (e) simulation and experimental results [90]. Copyright 2021, Wiley-VCH.
Fig. 9. (a) Flexible multifunctional microsensor beyond electrical and optical energy. (b) Fitted temperature-response curve with r2 = 0.9992 and (c) r2 = 0.9996. (d) Frequency-dependence EMI shielding of the microsensor at different temperatures. (e-j) Characterization for polarization relaxation in nonperfect graphene. (k-p) Temperature-driven plasma resonance of nonperfect graphene patterns [97]. Copyright 2020, WILEY-VCH.
Fig. 10. First-principles calculations. (a) SnO and SnO2 crystal plane models used to calculate work functions and (b-e) work functions obtained by calculating typical crystal planes between samples’ interfaces from Ref. [103]. Copyright 2021, Elsevier. (f) Reduction of the energy barrier via a lattice-confined strategy [104]. Copyright 2020, American Chemical Society. The molecular dynamics simulations of IGPC at 20 and 50 °C. (g) Cluster analysis of hydrogen bond pairs within 0.35 nm; (h) radius of gyrate that indicates the structural deformation degree; (i) distance between C219 and C318 in an IGPC molecular; (j) conformation change of IGPC. (k) Wave absorption mechanisms of IGPC from Ref. [105]. Copyright 2021, Elsevier.
Fig. 11. (a) Simulated reflectivity spectra of designed arrays with different geometric parameters; (b) assumed relationship between tip configuration and input impedance matching/internal losses; (c) 3D power loss distribution of periodic modes from [110]. Copyright 2020, Springer Nature. (d, e) Digital photographs and (f) SEM images of GS with different shapes. (g-n) Complex electric field intensity time-averaged amplitude distribution and power loss distribution. (o) EM loss mechanisms from [115]. Copyright 2021, Wiley-VCH.
Fig. 12. (a-d) Far-field response based on the plane wave theory of Co@C/CGs. (e) EM field intensity distribution from Ref. [110]. Copyright 2021, Wiley-VCH. HFSS simulation results of the samples: (f) PEC, (g) PEC substrates covered with samples S-40, (i) S-50, and (j) S-60. (h) RCS simulated graphs; (k) RCS reduction compare with PEC from Ref. [117]. Copyright 2020, Elsevier. (l, m, o, p) Perfect conductive layer covered with G700, G800, and G900. (n) RCS simulated curves of PEC and all products under different scanning angles. (q) Comparison of RCS reduction values of G700/G800/G900. (r) MA mechanisms for 3D shaddock peel-derived carbon aerogel from Ref. [118]. Copyright 2021, the Author(s). Simulation of RCS of PEC substrate and PEC substrate with Fe@RC coating (s) at 6.00 GHz for 3.0 mm coating thickness; (t) at 10.00 GHz for 2.0 mm coating thickness; (u) at 14.08 GHz for 1.5 mm coating thickness from Ref. [119]. Copyright 2021, Elsevier. (v) HFSS simulation results of the MF composite coatings at different testing angles. (w) RCS reduction was obtained by subtracting the MF coating with PEC at representative scanning angles from Ref. [120]. Copyright 2021, American Chemical Society.
| Materials | Main mechanism | RLmin (dB) | Thickness (mm) | Bandwidth (GHz) | Refs. |
|---|---|---|---|---|---|
| Ni/graphene | Magnetic loss | -45.5 | 2.5 | 5.6 | [ |
| Fe doping LaCoO3 | Dielectric-magnetic loss | -41 | 1.95 | 5.61 | [ |
| CoSn/NC carbon | Multiple polarization | -48.2 | 2.2 | 5.84 | [ |
| MWCNT@TiO2-C | Polarization loss | -53.2 | 2.5 | 3.1 | [ |
| NiCo2O4/C | Interface polarization | -64 | 3.62 | 8.08 | [ |
| C-SnO2-MWCNT | Conduction loss | -53.5 | 2.65 | 3.16 | [ |
| NiCo/CeO2/Ti3C2Tx | Conduction loss | -42.28 | 1.9 | 6.32 | [ |
| GCraphene foam | Multiple reflection | -61.29 | 4.75 | 5.51 | [ |
| MnxOy@C | Multiple dielectric loss | -76.0 | 2.0 | 5.2 | [ |
| Spinel ferrites | Magnetic loss | -30.10 | 3.5 | 7.48 | [ |
| Ni2P/CF | Conductivity loss | -56.9 | 2.32 | 7.2 | [ |
| SnO2@MWCNT | Multiple reflections | -56.9 | 2.6 | 3.1 | [ |
| Carbon nanocoils /Fe3O4 or Ni | Dielectric-magnetic Multiple loss | -40.3 | 3.1 | - | [ |
| rGO/glass | Multi-polarization | -69.2 | 2.8 | 4.56 | [ |
| Transition metal carbides | Magnetic loss | -41.7 | 2.11 | 3.5 | [ |
| SCF/glass | Interface polarization | -40.5 | 6 | - | [ |
| CNT/CF | Conductivity loss | -44.46 | 3 | 7.44 | [ |
| C@magnetic metal | Dielectric-magnetic loss | -54.1 | 3.4 | 5.5 | [ |
| CoNi/C | Multiple reflections | -64 | - | 4.8 | [ |
Table 1. Comparison of MA properties and mechanisms based on MA materials in recent years
| Materials | Main mechanism | RLmin (dB) | Thickness (mm) | Bandwidth (GHz) | Refs. |
|---|---|---|---|---|---|
| Ni/graphene | Magnetic loss | -45.5 | 2.5 | 5.6 | [ |
| Fe doping LaCoO3 | Dielectric-magnetic loss | -41 | 1.95 | 5.61 | [ |
| CoSn/NC carbon | Multiple polarization | -48.2 | 2.2 | 5.84 | [ |
| MWCNT@TiO2-C | Polarization loss | -53.2 | 2.5 | 3.1 | [ |
| NiCo2O4/C | Interface polarization | -64 | 3.62 | 8.08 | [ |
| C-SnO2-MWCNT | Conduction loss | -53.5 | 2.65 | 3.16 | [ |
| NiCo/CeO2/Ti3C2Tx | Conduction loss | -42.28 | 1.9 | 6.32 | [ |
| GCraphene foam | Multiple reflection | -61.29 | 4.75 | 5.51 | [ |
| MnxOy@C | Multiple dielectric loss | -76.0 | 2.0 | 5.2 | [ |
| Spinel ferrites | Magnetic loss | -30.10 | 3.5 | 7.48 | [ |
| Ni2P/CF | Conductivity loss | -56.9 | 2.32 | 7.2 | [ |
| SnO2@MWCNT | Multiple reflections | -56.9 | 2.6 | 3.1 | [ |
| Carbon nanocoils /Fe3O4 or Ni | Dielectric-magnetic Multiple loss | -40.3 | 3.1 | - | [ |
| rGO/glass | Multi-polarization | -69.2 | 2.8 | 4.56 | [ |
| Transition metal carbides | Magnetic loss | -41.7 | 2.11 | 3.5 | [ |
| SCF/glass | Interface polarization | -40.5 | 6 | - | [ |
| CNT/CF | Conductivity loss | -44.46 | 3 | 7.44 | [ |
| C@magnetic metal | Dielectric-magnetic loss | -54.1 | 3.4 | 5.5 | [ |
| CoNi/C | Multiple reflections | -64 | - | 4.8 | [ |
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