J. Mater. Sci. Technol. ›› 2026, Vol. 241: 35-51.DOI: 10.1016/j.jmst.2025.02.087

• Research Article • Previous Articles     Next Articles

Unusual deformation substructure and strain hardening in an additively manufactured CoCrFeMnNi high entropy alloy under high-velocity impact loading

Hongyu Chena, Xiaofeng Yangb, Dongdong Gua, Yang Liuc,*, Shengze Yangc, Xiyu Chenb, Konrad Kosibad, Yufei Chenb, Junhang Dub, Konda Gokuldoss Prashanthe,f, Yonggang Wangc, Tiwen Lub,*   

  1. aJiangsu Provincial Engineering Research Center for Laser Additive Manufacturing of High-Performance Components, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China;
    bKey Laboratory of Pressure Systems and Safety, Ministry of Education, State Key Laboratory of Chemical Safety, East China University of Science and Technology, Shanghai 200237, China;
    cKey Laboratory of Impact and Safety Engineering of Ministry of Education of China, Ningbo University, Ningbo 315211, China;
    dLeibniz Institute for Solid State and Materials Research Dresden, Institute Material Chemistry, 12 Helmholtzstr. 20, 01069 Dresden, Germany;
    eDepartment of Mechanical and Industrial Engineering, Tallinn University of Technology, 19086 Tallinn, Estonia;
    fCBCMT, Vellore Institute of Technology, Vellore 632014, Tamil Nadu, India
  • Received:2024-11-13 Revised:2025-02-21 Accepted:2025-02-25 Online:2026-01-14
  • Contact: *E-mail addresses: liuyang1@nbu.edu.cn (Y. Liu), tiwenlu@ecust.edu.cn (T. Lu)

Abstract: The superior dynamic mechanical properties of high-entropy alloys (HEAs) have attracted great interest, while there have been limited studies on the adiabatic temperature change as well as the deformation mechanism in the additively manufactured HEAs under impact loading. In this work, the deformation mechanism of laser powder bed fusion (LPBF)-fabricated CoCrFeMnNi HEAs under high-velocity impact loading was elucidated through multiple microstructural characterization in conjunction with molecular dynamics simulation. Different from CoCrFeMnNi alloys made by thermomechanical processing, both yield strength (YS) and strain hardening behavior of LPBF-fabricated HEA samples are more sensitive to the strain rate in the range of 0.001/s to 5000/s. The YS of the LPBF-fabricated HEAs shows an increasing trend from ∼452 MPa at 0.001/s to ∼685 MPa at 5000/s. The strain hardening capacity also increases with the increase of strain rate from 0.001/s to 3000/s. When the strain rates are over 3000/s, high strain hardening capacity is derived from strong dislocation multiplication induced by a high density of deformation twin boundaries. An intriguing mechanical response of the LPBF-fabricated HEAs emerges during loading: the strain hardening rate slightly decreases when the strain rate values increase from 3000/s to 5000/s, which is ascribed to the potential temperature rise-induced dislocation dynamic recovery. Further, in comparison to as-cast HEAs, LPBF-fabricated HEAs show significantly enhanced twinning behavior at high strain rates. The difference is related to unique as-printed microstructure of LPBF-fabricated HEAs: high-density dislocation increasing flow stress, cellular boundaries inducing dislocation dissociation and subsequent nano-twins at high strain rates. These substructures bring enhanced twinning behavior and strain rate-dependent high-velocity impact behavior in LPBF-fabricated HEAs. Our work provides a new insight into the dynamic impact behavior of additively manufactured HEA materials.

Key words: Laser powder bed fusion, High entropy alloy, Dynamic loading, Cellular structure, Twinning behavior