J. Mater. Sci. Technol. ›› 2025, Vol. 234: 292-306.DOI: 10.1016/j.jmst.2025.01.060

• Research Article • Previous Articles     Next Articles

Synergistic dual-scale laser beams for fabricating high-temperature eutectic ceramic coatings with nano microstructures via LPBF

Zhonglin Shena,b, Haijun Sua,c,*, Minghui Yua, Peixin Yanga, Yinuo Guoa,b, Yang Caod, Hao Jianga, Xiang Lia, Dong Donga, Zhuo Zhanga, Min Guoa   

  1. aState Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an 710072, China;
    bDepartment of Mechanical Engineering, National University of Singapore, Singapore 117575, Singapore;
    cResearch & Development Institute of Northwestern Polytechnical University in Shen Zhen, Shenzhen 518057, China;
    dSchool of Microelectronics, Fudan University, Shanghai 200433, China
  • Received:2024-09-12 Revised:2024-12-30 Accepted:2025-01-13 Published:2025-11-01 Online:2025-03-26
  • Contact: *E-mail address: shjnpu@nwpu.edu.cn (H. Su).

Abstract: This study introduces a novel integrated laser powder bed fusion (LPBF) approach for fabricating high-quality, ultra-high-temperature oxide eutectic ceramic coatings on superalloys to meet the critical demand for improved thermal barrier coatings in high-temperature applications. To resolve the interface bonding challenges between brittle ceramic coatings and ductile superalloys, this method employs two different laser sources: a short-wavelength fiber laser for fabricating the IN718 superalloy substrate and NiCoCrAlY bonding layer, and a long-wavelength CO2 laser for depositing oxide eutectic ceramic coatings. Additionally, the finite element modeling (FEM) is utilized to optimize the preparation of superalloy-ceramic coating composites using LPBF technology, revealing the temperature and stress field distributions during the fabrication process. The resulting in-situ eutectic composite ceramic coatings exhibit a bonding strength of about 29.3 N and a nanoscale microstructure with a eutectic spacing of 97 nm. In high-temperature water-oxygen corrosion tests at 1000 ℃, the coatings showed no signs of delamination. After 100 h of heat treatment at 500 ℃, the microstructure experienced only a slight coarsening, maintaining its nanoscale structures. This LPBF fabrication method provides an effective approach for the rapid integrated manufacturing of oxide eutectic ceramic coatings on superalloy substrates, demonstrating significant potential for high temperature applications.

Key words: Laser powder bed fusion, Ceramic coating, FEM simulation, Bonding strength