Designing sandwich-structured IBP nanosheets with superior antioxidant property to enhance corrosion resistance, flame retardancy, and wear resistance for polymeric coatings

doi:10.1016/j.jmst.2024.07.023

Abstract

Abstract: The rapid development of industrialization requires the advancement of multifunctional coatings. In this study, successful self-assembly of iron porphyrin on BP nanosheets resulted in the synthesis of IBP nanosheets with a sandwich structure. Characterization tests including SEM, XPS, SPM, and XRD confirmed the successful preparation of IBP nanosheets with robust structural stability and antioxidation. Subsequently, a water-based epoxy resin (WEP) coating containing IBP nanosheets was prepared. Test results revealed that the composite coating containing 0.4 wt.% IBP nanosheets exhibited outstanding anti-corrosion, wear-resistant, and flame-retardant properties. After 42 days of immersion in a 3.5 wt.% NaCl solution, the R_ct value of the 4-IBP/WEP coating was 1.79 × 10⁹ Ω cm², surpassing the Pure WEP coating by more than 3 orders of magnitude. Additionally, the peak heat release rate (PHRR) and wear rate of the 4-IBP/WEP coating decreased by 19.29 % and 90.97 % compared to the Pure WEP coating. This research presents a novel idea for the utilization of BP nanosheets in multifunctional coatings.

Key words: Black phosphorus, Corrosion resistance, Wear-resistant, Flame-retardant

Qihan Weng, Li Zhang, Xinxin Sheng, Delong Xie. Designing sandwich-structured IBP nanosheets with superior antioxidant property to enhance corrosion resistance, flame retardancy, and wear resistance for polymeric coatings[J]. J. Mater. Sci. Technol., 2025, 215: 22-35.

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