Magnesium borohydride Mg(BH4)2 for energy applications: A review

doi:10.1016/j.jmst.2023.03.040

Abstract

Abstract: Mg(BH₄)₂ with several polymorphs, known as a high capacity (14.9 wt.%) hydrogen storage material, has become more intriguing due to the recently found new functions of gas physisorption and ionic conductivity. Here we review the state-of-the-art on the energy related functions of Mg(BH₄)₂. Mg(BH₄)₂ tends to form the stable intermediate [B₁₂H₁₂]^2- when the dehydrogenation temperature is above 400 °C, the strong B-B bonding of which makes the rehydrogenation condition very harsh. In contrast, lower borane intermediate [B₃H₈]^2- facilitates the rehydrogenation even at a mild condition of 100 °C, suggesting the possibility of reversible hydrogen storage in Mg(BH₄)₂. The porous polymorph γ-Mg(BH₄)₂ shows attractive gas adsorption properties in view of its unique hydridic surface and pore shape, and potentially can be applied in hydrogen adsorption and Kr/Xe selectivity. A new diffraction-based adsorption methodology was developed to characterize adsorption thermodynamics and kinetics of γ-Mg(BH₄)₂, providing a novel idea for the characterization of crystalline porous materials. Moreover, the potential of Mg(BH₄)₂ as an electrolyte is discussed in the last part. Mg(BH₄)₂·THF/DME acts as a liquid electrolyte in Mg-batteries, while anion substituted or neutral molecule derivatives of Mg(BH₄)₂ can act as solid-state electrolyte.

Key words: Hydride, Hydrogen storage, Gas adsorption, Hydrogen adsorption, Electrolyte

Xiao Li, Yigang Yan, Torben R. Jensen, Yaroslav Filinchuk, Iurii Dovgaliuk, Dmitry Chernyshov, Liqing He, Yongtao Li, Hai-Wen Li. Magnesium borohydride Mg(BH₄)₂ for energy applications: A review[J]. J. Mater. Sci. Technol., 2023, 161: 170-179.

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Magnesium borohydride Mg(BH₄)₂ for energy applications: A review

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