J. Mater. Sci. Technol. ›› 2023, Vol. 163: 45-58.DOI: 10.1016/j.jmst.2023.01.061

• Research Article • Previous Articles     Next Articles

Superelastic metastable Ti-Mo-Sn alloys with high elastic admissible strain for potential bio-implant applications

Shuanglei Lia, Jae H. Kima, Seung Won Kanga, Jae Ho Kima, Tae-Hyun Namb, Jong-Taek Yeoma,*   

  1. aTitanium Alloys Department, Metal Materials Division, Korea Institute of Materials Science (KIMS), Changwon 51508, Republic of Korea;
    bDepartment of Materials Engineering and Convergence Technology & Research Institute for Green Energy Convergence Technology (RIGET), Gyeongsang National University, 900 Gazwadong, Jinju, Gyeongnam 52828, Republic of Korea
  • Received:2022-11-08 Revised:2023-01-02 Accepted:2023-01-02 Published:2023-11-10 Online:2023-03-19
  • Contact: * E-mail address: yjt96@kims.re.kr (J.-T. Yeom).

Abstract: The demand for titanium alloys simultaneously having high elastic admissible strain and large recovery strain for bio-implant applications is increasing. Ni-free Ti-based shape memory alloys are promising candidates for obtaining the required multifunctional properties. In this study, a wide content range of (0-15)wt% of low-cost, toxicity-free, and high-biocompatible Sn element was added to the Ti-8Mo (wt%) alloy to study its effect on the superelastic recovery and mechanical properties of biomedical Ti-Mo-Sn alloys. By tailoring Sn content, desired multifunctional properties of high elastic admissible strain and room temperature superelasticity were achieved in the studied Ti-Mo-Sn alloys. It was found that the increase in Sn content stabilized the β phase and a single β phase was obtained at room temperature in Ti-8Mo-(13, 15)Sn alloys. The addition of Sn modified the lattice parameters of the α″ martensite and β phase and affected the lattice deformation stain of βα″. The lattice deformation strain along the [011]β direction was found to be decreased by -0.26%/wt% Sn. The room temperature superelasticity with a recovery strain of 3.1% and an elastic admissible strain of 1% was obtained in the Ti-8Mo-13Sn alloy. As Sn content increased to 15 wt%, a high elastic admissible strain of 1.56% and a recovery strain of 2.0% were obtained. These Ti-Mo-Sn alloys with excellent multifunctional properties are promising candidates for bio-implant applications.

Key words: Ti-Mo-Sn alloy, Shape memory alloy, Elastic admissible strain, Elastic modulus, Superelasticity