Ion diffusion, and hysteresis of magnesium hydride conversion electrode materials

doi:10.1016/j.jmst.2023.01.028

Abstract

Abstract: MgH₂, owing to a high theoretical capacity of 2038 mAh g^-1, is regarded as a promising anode material for lithium-ion batteries (LIBs). However, the application of MgH₂ is still far from satisfactory due to its poor cycling stability. Herein, nano-crystallization of MgH₂ as an anode is applied for all-solid-state lithium-ion batteries (ASSLIBs) using LiBH₄ as a solid-state electrolyte. The self-assembly designed MgH₂ electrode on graphene could effectively alleviate the volume expansion, prevent the agglomeration of active substances, improve the electron transfer, and enhance the electrochemical performance of the anode material. As a result, a reversible capacity of 1214 mAh g^-1 after 50 cycles is obtained. Significantly enhanced cycle life with a notable capacity of 597 mAh g^-1 at a current density of 400 mA g^-1 is delivered after 200 cycles. Further investigation on full cells also exhibits great application potential on ASSLIBs.

Key words: Magnesium hydride, Lithium borohydrides, Graphene, Nano-crystallization, All-solid-state lithium-ion battery

Yingtong Lv, Xiang Zhang, Wei Chen, Shunlong Ju, Zhenhua Liu, Guanglin Xia, Takayuki Ichikawa, Tengfei Zhang, Xuebin Yu. Ion diffusion, and hysteresis of magnesium hydride conversion electrode materials[J]. J. Mater. Sci. Technol., 2023, 155: 47-53.

References

[1] A. Manthiram, X.W. Yu, S.F. Wang, Nat. Rev. Mater. 2(2017) 16103.
[2] P.G. Bruce, B. Scrosati, J.-.M. Tarascon, Angew.Chem., Int. Ed. 47(2008) 2930-2946.
[3] T.F. Zhang, W.J. He, W. Zhang, T. Wang, P. Li, Z.M. Sun, X.B. Yu, Chem. Sci. 11(2020) 8686-8707.
[4] A. Manthiram, ACS Cent. Sci. 3(2017) 1063-1069.
[5] F.Q. Lu, Y.P. Pang, M.F. Zhu, F.D. Han, J.H. Yang, F. Fang, D.L. Sun, S.Y. Zheng, C. S. Wang, Adv. Funct. Mater. 29(2019) 1809219.
[6] Q. Li, L.S. Han, Q. Luo, X.Y. Liu, J. Yi, Batter. Supercaps 5 (2022) e202100417.
[7] R.T. Li, Y.X. Du, Y.H. Li, Z.X. He, L. Dai, L. Wang, X.W. Wu, J.J. Zhang, J. Yi, ACS Energy Lett. 8(2022) 457-476.
[8] K. Wu, F.H. Ning, J. Yi, X.Y. Liu, J.Q. Qin, Y.Y. Liu, J.J. Zhang, J. Energy Chem. 69(2022) 237-243.
[9] X.Y. Liu, Y.Z. Fang, P.C. Liang, J.H. Xu, B. Xing, K. Zhu, Y.Y. Liu, J.J. Zhang, J. Yi, Chin. Chem. Lett. 32(2021) 2899-2903.
[10] B. Anasori, M.R. Lukatskaya, Y. Gogotsi, Nat. Rev. Mater. 2(2017) 16098.
[11] I.H. Son, J. Hwan Park, S. Kwon, S. Park, M.H. Rümmeli, A. Bachmatiuk, H.J. Song, J. Ku, J.W. Choi, J. Choi, S.-.G. Doo, H.Chang, Nat. Commun. 6(2015) 7393.
[12] M. Naguib, J. Halim, J. Lu, K.M. Cook, L. Hultman, Y. Gogotsi, M.W. Barsoum, J. Am. Chem.Soc. 135(2013) 15966-15969.
[13] J.M. Jiang, J.R. Yuan, P. Nie, Q. Zhu, C.L. Chen, W.J. He, T.F. Zhang, H. Dou, X. G. Zhang, J. Mater. Chem. A 8 (2020) 3956-3966.
[14] Y. Sun, J.J. Xue, S.Y. Dong, Y.D. Zhang, Y.F. An, B. Ding, T.F. Zhang, H. Dou, X. G. Zhang, J. Mater. Sci. 55(2020) 5166-5176.
[15] H.-.W. Li, M. Zhu, C. Buckley, T.R. Jensen, Inorganics 6 (2018) 91.
[16] Y. Oumellal, A. Rougier, G.A. Nazri, J.-.M. Tarascon, L.Aymard, Nat. Mater. 7(2008) 916-921.
[17] G.L. Xia, Y.B. Tan, X.W. Chen, D.L. Sun, Z.P. Guo, H.K. Liu, L.Z. Ouyang, M. Zhu, X. B. Yu, Adv. Mater. 27(2015) 5981-5988.
[18] S. Sartori, F. Cuevas, M. Latroche, Appl. Phys. A-Mater.Sci. Process. 122(2016) 1-7.
[19] S.L. Zhong, S.L. Ju, Y.F. Shao, W. Chen, T.F. Zhang, Y.Q. Huang, H.Y. Zhang, G. L. Xia, X.B. Yu, J. Energy Chem. 62(2021) 431-439.
[20] M. Guo, S.L. Zhong, T. Xu, Y.Q. Huang, G.L. Xia, T.F. Zhang, X.B. Yu, J. Mater. Chem. A 9 (2021) 23841-23849.
[21] Y. Jin, B. Zhu, Z.D. Lu, N. Liu, J. Zhu, Adv. Energy Mater. 7(2017) 1700715.
[22] Q. Xu, J.-.Y. Li, J.-.K. Sun, Y.-.X. Yin, L.-.J. Wan, Y.-.G. Guo, Adv. Energy Mater. 7(2017) 1601481.
[23] J. Liu, Q. Zhang, T. Zhang, J.-.T. Li, L.Huang, S.-.G. Sun, Adv. Funct. Mater. 25(2015) 3599-3605.
[24] W.J. He, T.F. Zhang, Z.W. Li, J.M. Jiang, C.L. Chen, N. Liu, H. Dou, X.G. Zhang, J. Mater. 7(2021) 802-809.
[25] W.J. He, T.F. Zhang, J.M. Jiang, C.L. Chen, Y.D. Zhang, N. Liu, H. Dou, X.G. Zhang, ACS Appl. Energy Mater. 3(2020) 4394-4402.
[26] S.Y. Bai, X.Z. Liu, K. Zhu, S.C. Wu, H.S. Zhou, Nat. Energy 1 (2016) 16094.
[27] Q. Pang, X. Liang, C.Y. Kwok, L.F. Nazar, Nat. Energy 1 (2016) 16132.
[28] Z.W. Seh, Y.M. Sun, Q.F. Zhang, Y. Cui, Chem. Soc. Rev. 45(2016) 5605-5634.
[29] Y. Lu, L. Yu, X.W. (David) Lou, Chem 4 (2018) 972-996.
[30] Q.B. Xia, W.J. Li, Z.C. Miao, S.L. Chou, H.K. Liu, Nano Res. 10(2017) 4055-4081.
[31] W. Liu, P. Oh, X. Liu, M.-.J. Lee, W.Cho, S. Chae, Y. Kim, J. Cho, Angew. Chem., Int. Ed. 54(2015) 4440-4457.
[32] Y. Zhao, X.F. Li, B. Yan, D.B. Xiong, D.J. Li, S. Lawes, X.L. Sun, Adv. Energy Mater. 6(2016) 1502175.
[33] M.B. Zheng, H. Tang, L.L. Li, Q. Hu, L. Zhang, H.G. Xue, H. Pang, Adv. Sci. 5(2018) 1700592.
[34] W.Z. Wang, Q. Zhang, T. Jiang, S.J. Li, J.Z. Gao, X.H. Liu, C.F. Lin, Adv. Energy Mater. 12(2022) 2200656.
[35] R.J. Li, G.S. Liang, X.Z. Zhu, Q.F. Fu, Y.J. Chen, L.J. Luo, C.F. Lin, Energy Environ. Mater. 4(2021) 65-71.
[36] S.Y. Ma, T. Jiang, J.B. Deng, Q. Zhang, Y.J. Ou, X.H. Liu, C.F. Lin, K.K. Wang, X. S. Zhao, Energy Storage Mater. 46(2022) 366-373.
[37] Q. Zhang, S.Y. Ma, W.Z. Wang, S.F. Gao, Y.J. Ou, S.J. Li, X.H. Liu, C.F. Lin, Energy Storage Mater. 52(2022) 637-645.
[38] Y.Y. Zhu, L.Z. Ouyang, H. Zhong, J.W. Liu, H. Wang, H.Y. Shao, Z.G. Huang, M. Zhu, Angew. Chem., Int. Ed. 59(2020) 8623-8629.
[39] L.Z. Ouyang, W. Chen, J.W. Liu, M. Felderhoff, H. Wang, M. Zhu, Adv. Energy Mater. 7(2017) 1700299.
[40] Q. Luo, Y.L. Guo, B. Liu, Y.J. Feng, J.Y. Zhang, Q. Li, K.C. Chou, J. Mater. Sci.Tech- nol. 44(2020) 171-190.
[41] Q. Li, Q. Lin, K.C. Chou, L.J. Jiang, J. Mater. Sci. 39(2004) 61-65.
[42] Y.O. Ma, T.F. Zhang, W.J. He, Q. Luo, Z.W. Li, W. Zhang, J.P. He, Q. Li, Int. J. Hydrogen Energy 45 (2020) 12048-12070.
[43] L.Z. Ouyang, Z.J. Cao, H. Wang, J.W. Liu, D.L. Sun, Q.A. Zhang, M. Zhu, Int. J. Hydrogen Energy 38 (2013) 8881-8887.
[44] Q.H. Cheng, D.L. Sun, X.B. Yu, J. Alloy. Compd. 769(2018) 167-185.
[45] B.P. Zhang, Y.S. Si, Q.F. Gu, M. Chen, X.B. Yu, ACS Appl. Mater. Interfaces 11 (2019) 28987-28995.
[46] J. Cuan, Y. Zhou, T.F. Zhou, S.G. Ling, K. Rui, Z.P. Guo, H.K. Liu, X.B. Yu, Adv. Mater. 31(2019) 1803533.
[47] A. Inoishi, H. Sato, Y.X. Chen, H. Saito, R. Sakamoto, H. Sakaebe, S. Okada, RSC Adv. 12(2022) 10749-10754.
[48] F. Cano-Banda, A. Gallardo-Gutierrez, L. Luviano-Ortiz, A. Hernandez-Guerrero, A. Jain, T. Ichikawa, Int. J. Hydrogen Energy 46 (2020) 1030-1037.
[49] Q. Li, Y.F. Lu, Q. Luo, X.H. Yang, Y. Yang, J. Tan, Z.H. Dong, J. Dang, J.B. Li, Y. Chen, B. Jiang, S.H. Sun, F.S. Pan, J. Magn. Alloy. 9(2021) 1922-1941.
[50] H.W. Song, J. Su, C.X. Wang, Adv. Energy Mater. 9(2019) 1900426.
[51] J. Su, H.W. Song, C.X. Wang, Adv. Funct. Mater. 29(2019) 1907154.
[52] H.W. Song, J. Su, C.X. Wang, ACS Appl. Mater. Interfaces 11 (2019) 37867-37874.
[53] R. Hu, Y.Z. Fang, X.Y. Liu, K. Zhu, D.X. Cao, J. Yi, G.L. Wang, Chem. Res. Chin. Univ. 37(2021) 311-317.
[54] H. Wang, H.J. Lin, W.T. Cai, L.Z. Ouyang, M. Zhu, J. Alloy. Compd. 658(2016) 280-300.
[55] Y. Oumellal, C. Zlotea, S. Bastide, C. Cachet-Vivier, E. Léonel, S. Seng- many, E. Leroy, L. Aymard, J.-.P. Bonnet, M. Latroche, Nanoscale 6 (2014) 14459-14466.
[56] B.P. Zhang, G.L. Xia, D.L. Sun, F. Fang, X.B. Yu, ACS Nano 12 (2018) 3816-3824.
[57] G.L. Xia, B.P. Zhang, X.W. Chen, D.L. Sun, Z.P. Guo, F.X. Liang, W.D. Zou, Z.Z. Yang, X.B. Yu, ACS Nano 12 (2018) 8177-8186.
[58] B.Y. Liu, Y.H. Gong, K. Fu, X.G. Han, Y.G. Yao, G. Pastel, C.P. Yang, H. Xie, E. D. Wachsman, L.B. Hu, ACS Appl. Mater. Interfaces 9 (2017) 18809-18815.
[59] T.F. Zhang, Y.M. Wang, T. Song, H. Miyaoka, K. Shinzato, H. Miyaoka, T. Ichikawa, S.Q. Shi, X.G. Zhang, S. Isobe, N. Hashimoto, Y. Kojima, Joule 2 (2018) 1522-1533.
[60] A. Unemoto, T. Ikeshoji, S. Yasaku, M. Matsuo, V. Stavila, T.J. Udovic, S. Orimo, Chem. Mater. 27(2015) 5407-5416.
[61] S. Kim, N. Toyama, H. Oguchi, T. Sato, S. Takagi, T. Ikeshoji, S.I. Orimo, Chem. Mater. 30(2018) 386-391.
[62] K. Wu, J. Yi, X.Y. Liu, Y. Sun, J. Cui, Y.H. Xie, Y.Y. Liu, Y.Y. Xia, J.J. Zhang, Nano-Micro Lett. 13(2021) 1-11.
[63] M. Matsuo, Y. Nakamori, S.I. Orimo, H. Maekawa, H. Takamura, Appl. Phys. Lett. 91(2007) 224103.
[64] S. Kim, H. Oguchi, N. Toyama, T. Sato, S. Takagi, T. Otomo, D. Arunkumar, N. Kuwata, J. Kawamura, S. Orimo, Nat. Commun. 10(2019) 1081.
[65] L. Zeng, H. Miyaoka, T. Ichikawa, Y. Kojima, J. Phys. Chem. C 114 (2010) 13132-13135.
[66] G. Kresse, J. Furthmüller, Phys. Rev. B 54 (1996) 11169-11186.
[67] G. Kresse, J. Hafner, Phys. Rev. B 47 (1993) 558-561.
[68] P.E. Blöchl, Phys. Rev. B 50 (1994) 17953-17979.
[69] J.P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett. 77(1996) 3865-3868.
[70] H.T. Larijani, M. Jahanshahi, M.D. Ganji, M.H. Kiani, Phys. Chem. Chem. Phys. 19(2017) 1896-1908.
[71] D. Meggiolaro, G. Gigli, A. Paolone, P. Reale, M.L. Doublet, S. Brutti, J. Phys. Chem. C 119 (2015) 17044-17052.
[72] N.D. Lepley, N.A.W. Holzwarth, Y.A. Du, Phys. Rev. B 88 (2013) 104103.
[73] J.K. Ko, K.M. Wiaderek, N. Pereira, T.L. Kinnibrugh, J.R. Kim, P.J. Chu- pas, K.W. Chapman, G.G. Amatucci, ACS Appl. Mater. Interfaces 6 (2014) 10858-10869.
[74] M.D. Levi, E. Markevich, D. Aurbach, Electrochim. Acta 51 (2005) 98-110.
[75] J.Y. Hwang, S. Shin, C.S. Yoon, Y.K. Sun, ACS Energy Lett. 4(2019) 2787-2795.
[76] G.Q. Tan, R. Xu, Z.Y. Xing, Y.F. Yuan, J. Lu, J.G. Wen, C. Liu, L. Ma, C. Zhan, Q. Liu, T.P. Wu, Z.L. Jian, R. Shahbazian-Yassar, Y. Ren, D.J. Miller, L.A. Curtiss, X.L. Ji, K. Amine, Nat. Energy 2 (2017) 1-10.
[77] S.Y. Zheng, Y. Chen, Y.H. Xu, F. Yi, Y.J. Zhu, Y.H. Liu, J.H. Yang, C.S. Wang, ACS Nano 7 (2013) 10995-11003.
[78] S.Q. Li, D. Leng, W.Y. Li, L. Qie, Z.H. Dong, Z.Q. Cheng, Z.Y. Fan, Energy Storage Mater. 27(2020) 279-296.
[79] M.L. Yu, S. Zhou, Z.Y. Wang, W. Pei, X.J. Liu, C. Liu, C.L. Yan, X.Y. Meng, S. Wang, J.J. Zhao, J.S. Qiu, Adv. Funct. Mater. 29(2019) 1-11.
[80] Y.Z. Liu, X.Y. Meng, Z.Y. Wang, J.S. Qiu, Sci. Adv. 8(2022) 8390.
[81] Z.H. Liu, T.F. Zhang, S.L. Ju, Y.D. Ji, Z.T. Hu, Y.T. Lv, G.L. Xia, X.B. Yu, ACS Appl. Energy Mater. 5(2022) 14301-14310.
[82] F.X. Wu, A. Magasinski, G. Yushin, J. Mater. Chem. A 2 (2014) 6064-6070.
[83] J.R. He, Y.F. Chen, W.Q. Lv, K.C. Wen, C. Xu, W.L. Zhang, Y.R. Li, W. Qin, W.D. He, ACS Nano 10 (2016) 10981-10987.