Dynamic mechanical relaxation behavior of Zr35Hf17.5Ti5.5Al12.5Co7.5Ni12Cu10 high entropy bulk metallic glass

doi:10.1016/j.jmst.2020.11.074

Abstract

Abstract:

Non-equiatomic high entropy bulk metallic glasses were reported recently and show unique mechanical and physical properties. Dynamic mechanical relaxation behavior of Zr₃₅Hf_17.5Ti_5.5Al_12.5Co_7.5Ni₁₂Cu₁₀ high entropy bulk metallic glass was investigated by dynamic mechanical analysis (DMA) and the mechanical spectra could be well described by the quasi-point defects (QPD) theory. Compared to typical metallic glasses, the intensity of the β relaxation of Zr₃₅Hf_17.5Ti_5.5Al_12.5Co_7.5Ni₁₂Cu₁₀ high entropy bulk metallic glass is lower due to the sluggish diffusion. At the same time, the correlation factor χ is higher than that of conventional metallic glasses and this is ascribed to the high configuration entropy. In parallel, physical aging below the glass transition temperature leads to a decrease of atomic mobility, caused by a decrease of the concentration of defects.

Key words: High entropy bulk metallic glass, Mechanical relaxation, Quasi-point defects, Physical aging

L.T. Zhang, Y.J. Duan, T. Wada, H. Kato, J.M. Pelletier, D. Crespo, E. Pineda, J.C. Qiao. Dynamic mechanical relaxation behavior of Zr₃₅Hf_17.5Ti_5.5Al_12.5Co_7.5Ni₁₂Cu₁₀ high entropy bulk metallic glass[J]. J. Mater. Sci. Technol., 2021, 83: 248-255.

Figures/Tables 11

Fig. 1. DSC curve of Zr35Hf17.5Ti5.5Al12.5Co7.5Ni12Cu10 high entropy bulk metallic glass (heating rate is 3 K/min). Inset is the XRD pattern of Zr35Hf17.5Ti5.5Al12.5Co7.5Ni12Cu10 high entropy bulk metallic glass.

Fig. 2. (a)Temperature dependence of the normalized storage modulus and the loss modulus of Zr35Hf17.5Ti5.5Al12.5Co7.5Ni12Cu10 high entropy bulk metallic glass. (b)The normalized loss mudulus E”/E”max in typical MGs as a function of the normalized temperature T/Tα. E”max is the maximum of the loss modulus. Tα is the peak temperature of the main α relaxation.

Fig. 3. Temperature dependence of the normalized loss modulus of Zr35Hf17.5Ti5.5Al12.5Co7.5Ni12Cu10 high entropy bulk metallic glass with different driving frequencies (0.05, 0.1, 0.3 and 0.5 Hz). The heating rate is 3 K/min. Inset shows lnf as a function of 1000/Tα.

Table 1 Activation energy of the main α relaxation in typical MGs obtained by DMA technique.

Metallic glasses	T_g (K)	E_α (eV)	Refs.
Ce₇₀Al₁₀Cu₂₀	366	2.03	[59]
Zn₃₈Mg₁₂Ca₃₂Yb₁₈	395	2.71	[60]
La₆₅Al₁₄(Cu_5/6Ag_1/6)₁₁(Cu_1/2Ni_1/2)₁₀	414	3.24	[61]
Mg₆₅Cu₂₅Y₁₀	425	2.97	[59]
La₃₀Ce₃₀Al₁₅Co₂₅	430	3.61	[58]
La₅₅Al₂₅Ni₂₀	479	3.77	[59]
Pd₄₀Ni₄₀P₂₀	597	5.95	[59]
Zr_41.2Ti_13.8Cu_12.5Ni₁₀Be_22.5	613	5.13	[59]
Zr₆₅Cu₁₅Al₁₀Ni₁₀	652	3.9	[59]
Zr₅₅Cu₃₀Al₁₀Ni₅	678	4.73	[59]
(Zr₅₅Cu₃₀Ni₅Al₁₀)₉₉Fe₁	684	4.97	[62]
Zr₄₉Cu₄₆Al₅	694	6.22	[59]
Zr₃₅Hf_17.5Ti_5.5Al_12.5Co_7.5Ni₁₂Cu₁₀	695	6.1	The current work
Cu₄₆Zr₄₅Al₇Y₂	698	5.56	[59]
Zr_47.5Cu _47.5Al₅	702	6.3	[59]
Cu₄₉Hf₄₂Al₉	765	7.08	The current work

Fig. 4. The activation energy of the main α relaxation Eα versus the glass transition temperature Tg in typical MGs.

Fig. 5. Dependence of the normalized storage E'/Eu (a) and the loss modulus E”/Eu (b) on frequency at different temperatures of Zr35Hf17.5Ti5.5Al12.5Co7.5Ni12Cu10 high entropy bulk metallic glass. (c) Master curve of the normalized storage modulus E'/Eu and the loss modulus E”/Eu with the frequency. The reference temperature is 700 K.

Fig. 6. (a) The loss factor tanδ varies with the driving frequency at various temperature of Zr35Hf17.5Ti5.5Al12.5Co7.5Ni12Cu10 high entropy bulk metallic glass. Solid lines are the best fits by the Eq. (3). (b) Evolution of the correlation factor χ and loss factor tanδ with temperature of Zr35Hf17.5Ti5.5Al12.5Co7.5Ni12Cu10 high entropy bulk metallic glass. (c) Evolution of the correlation factor χ with the normalized temperature in typical MGs.

Fig. 7. Evolution of the storage modulus E'/Eu (a) and loss factor tanδ (b) with the aging time at different aging temperatures of Zr35Hf17.5Ti5.5Al12.5Co7.5Ni12Cu10 high entropy bulk metallic glass. The aging temperatures are 623, 638, 653 and 668 K, respectively. The solid lines are fitted by the Eq. (4).

Fig. 8. Double logarithm of the loss factor tanδ versus the logarithm of the aging time at different aging temperatures for Zr35Hf17.5Ti5.5Al12.5Co7.5Ni12Cu10 high entropy bulk metallic glass.

Fig. 9. Temperature dependence of normalized activation energy spectra P(Eapp) of Zr35Hf17.5Ti5.5Al12.5Co7.5Ni12Cu10 high entropy bulk metallic glass.

Fig. 10. Evolution of the loss factor tanδ with temperature of Zr35Hf17.5Ti5.5Al12.5Co7.5Ni12Cu10 high entropy bulk metallic glass at different states: as-cast state and the samples were annealed at different temperatures, i.e., 623, 638, 653 and 668 K, for 12 h.

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Dynamic mechanical relaxation behavior of Zr₃₅Hf_17.5Ti_5.5Al_12.5Co_7.5Ni₁₂Cu₁₀ high entropy bulk metallic glass

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