J. Mater. Sci. Technol. ›› 2025, Vol. 213: 80-89.DOI: 10.1016/j.jmst.2024.06.046

• Research Article • Previous Articles     Next Articles

Unified mixed conductivity model

X.T. Lia, Z.J. Zhanga,b,*, R.J. Daia, R. Liua, Z. Qua,b, S.G. Wanga, H.T. Lic, W.J. Hua,b, Q.Z. Wanga,b, Z.Y. Maa,b, Z.F. Zhanga,b,*   

  1. aShenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China;
    bSchool of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China;
    cNational Laboratory for Rail Transit, Southwest Jiaotong University, Chengdu 610031, China
  • Received:2024-06-08 Accepted:2024-06-16 Published:2025-04-01 Online:2025-04-01
  • Contact: *E-mail address: zjzhang@imr.ac.cn (Z.J. Zhang), zhfzhang@imr.ac.cn (Z.F. Zhang)

Abstract: Matter conductivities are crucial physical properties that directly determine the engineering application value of materials. In reality, the majority of materials are multiphase composites. However, there is currently a lack of theoretical models to accurately predict the conductivities of composite materials. In this study, we develop a unified mixed conductivity (UMC) model, achieving unity in three aspects: (1) a unified description and prediction for different conductivities, including elastic modulus, thermal conductivity, electrical conductivity, magnetic permeability, liquid permeability coefficient, and gas diffusion coefficient; (2) a unified-form governing equation for mixed conductivities of various composite structures, conforming to the Riccati equation; (3) a unified-form composite structure, i.e., a three-dimensional multiphase interpenetrating cuboid structure, encompassing over a dozen of typical composite structures as its specific cases. The UMC model is applicable for predicting the conductivity across six different types of physical fields and over a dozen different composite structures, providing a broad range of applications. Therefore, the current study deepens our understanding of the conduction phenomena and offers a powerful theoretical tool for predicting the conductivities of composite materials and optimizing their structures, which holds significant scientific and engineering implications.

Key words: Composite materials, Conductivity, Elastic modulus, Permeability coefficient, Diffusion coefficient, Multiphase interpenetrating structure