High temperature oxidation behavior at 1250 °C: A new multilayer modified silicide coating design strategy on niobium alloys

doi:10.1016/j.jmst.2024.04.084

J. Mater. Sci. Technol. ›› 2025, Vol. 210: 159-169.DOI: 10.1016/j.jmst.2024.04.084

• Research Article • Previous Articles Next Articles

High temperature oxidation behavior at 1250 °C: A new multilayer modified silicide coating design strategy on niobium alloys

Shuqi Wang^a,b,1,*, Zhiyun Ye^a,b,1, Yulin Ge^a,b, Yongchun Zou^a,b, Tianlong Zhang^c, Xinrui Zhao^a,b, Mengjie Wang^d, Ci Song^e, Yaming Wang^a,b,*, Yu Zhou^a,b

^aInstitute for Advanced Ceramics, Harbin Institute of Technology, Harbin 150001, PR China;
^bKey Laboratory of Advanced Structure-Function Integrated Materials and Green Manufacturing Technology, Harbin Institute of Technology, Harbin 150001, PR China;
^cDepartment of Mechanical and Aerospace Engineering, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, PR China;
^dInstitute of Materials Mechanics, Helmholtz-Zentrum Hereon, Max-Planck-Strasse 121502 Geesthacht, Germany;
^eFaculty of Engineering, Kiel University, Kiel 24143, Germany

Received:2023-12-28 Revised:2024-02-12 Accepted:2024-04-15 Online:2024-06-13
Contact: ^*E-mail addresses: wang-shuqi@hit.edu.cn (S. Wang), wangyaming@hit.edu.cn (Y. Wang).
About author:¹These authors contributed equally to this work.

Abstract

Abstract: Silicide coatings have proven to be promising for improving the high-temperature oxidation resistance of niobium alloy. However, the long-term protective property of single silicide coating remains a long-time endeavor due to the deficiency of oxygen-consuming phases, as well as the self-healing ability of the protective layer. Herein, a silicide-based composite coating is constructed on niobium alloy by incorporation of nano-SiC particles for enhancing the high-temperature oxidation resistance. Isothermal oxidation results at 1250 °C for 50 h indicate that NbSi₂/Nb₂O₅-SiO₂/SiC multilayer coated sample with a low mass gain of 2.49 mg/cm² shows an improved oxidation resistance compared with NbSi₂ coating (6.49 mg/cm²). The enhanced high-temperature antioxidant performance of NbSi₂/Nb₂O₅-SiO₂/SiC multilayer coating is mainly attributed to the formation of the protective SiO₂ self-healing film and the high-temperature diffusion behavior of NbSi₂/substrate.

Key words: Niobium alloys, Silicide-based coating, High-temperature oxidation resistance nano-SiC, Liquid-plasma-assisted particle deposition and sintering

Shuqi Wang, Zhiyun Ye, Yulin Ge, Yongchun Zou, Tianlong Zhang, Xinrui Zhao, Mengjie Wang, Ci Song, Yaming Wang, Yu Zhou. High temperature oxidation behavior at 1250 °C: A new multilayer modified silicide coating design strategy on niobium alloys[J]. J. Mater. Sci. Technol., 2025, 210: 159-169.

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High temperature oxidation behavior at 1250 °C: A new multilayer modified silicide coating design strategy on niobium alloys

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