J. Mater. Sci. Technol. ›› 2024, Vol. 172: 71-82.DOI: 10.1016/j.jmst.2023.06.038

• Research Article • Previous Articles     Next Articles

Precipitating thermally reinforcement phase in aluminum alloys for enhanced strength at 400 °C

Xiang Sua,b,1, Yuan Leia,1, Yang Chena,*, Hongjie Qua, Zhixiang Qia, Gong Zhenga, Xu Liua, Henggao Xianga, Guang Chena,*   

  1. aNational Key Laboratory of Advanced Casting Technologies, MIIT Key Laboratory of Advanced Metallic and Intermetallic Materials Technology, Engineering Research Center of Materials Behavior and Design, Ministry of Education, Nanjing University of Science and Technology, Nanjing 210094, China;
    bSchool of Aviation and Mechanical Engineering, Changzhou Institute of Technology, Changzhou 213032, China
  • Received:2023-02-08 Revised:2023-06-16 Accepted:2023-06-18 Published:2024-02-10 Online:2023-08-07
  • Contact: *E-mail addresses: yang.chen@njust.edu.cn (Y. Chen), gchen@njust.edu.cn (G. Chen)
  • About author:1 These authors contributed equally to this work.

Abstract: Heat-resistant aluminum alloys are widely used in aerospace and automotive fields for manufacturing hot components due to their advantages in lightweight design and energy conservation. However, the high-temperature strength of existing cast aluminum alloys is always limited to about 100 MPa at 350 °C due to coarsening and transformation of strengthening phases. Here, we reveal that the yield strength and ultimate tensile strength of the T6 state Al-8.4Cu-2.3Ce-1.0Mn-0.5Ni-0.2Zr alloy at 400 ℃ increase by 34% and 44% after re-aging at 300 °C for 100 h, and its thermal strength exhibits distinguished advantage over traditional heat-resistant aluminum alloys. The enhanced elevated-temperature strength is attributed to the reprecipitation of the Ni-bearing T-Al20Cu2Mn3 phase, whose number density increases over one time. The significant segregation of Ni, Ce, and Zr elements at the interfaces helps improve the thermal stability of the T phase. The thermostable T phase effectively strengthens the matrix by inhibiting dislocation motion. Meanwhile, a highly interconnected 3D intermetallic network along the grain boundaries can still remain after long-term re-aging at 300 °C, which is conducive to imposing a drag on the grain boundaries at high temperatures. This finding offers a viable route for enhancing the elevated-temperature strength of heat-resistant aluminum alloys, which could provide expanded opportunities for higher-temperature applications.

Key words: Aluminum alloys, Precipitation, Thermally reinforcement phase, Re-aging treatment, High-temperature strength